Time evolution of spin state of radical ion pair in microwave field: An analytical solution

The paper reports an exact solution for the problem of spin evolution of radical ion pair in static magnetic and resonant microwave field taking into account Zeeman and hyperfine interactions and spin relaxation. The values of parameters that provide one of the four possible types of solution are analysed. It is demonstrated that in the absence of spin relaxation, besides the zero field invariant an invariant at large amplitudes of the resonant microwave field can be found. The two invariants open the possibility for simple calculation of microwave pulses to control quantum state of the radical pair. The effect of relaxation on the invariants is analysed and it is shown that changes in the high field invariant are induced by phase relaxation.Comment: 18 pages, 7 figure

Methodological approaches to evaluation of efficiency of new biotechnologies for remediation of soils contaminated with oil and oilfield liquids

© 2018 Neftyanoe Khozyaistvo. All rights reserved. Currently available is a wide range of biotechnologies for remediation of oil-polluted areas. These are based on application of hydrocarbon oxidizing microorganisms, humic compounds, and sorbents, which have various efficiency depending on the nature of pollution, climatic conditions, grain size distribution, and soil type. The purpose of the present research effort is to summarize the lessons learned in evaluation of the performance of new biotechnologies for remediation of soils contaminated with oil or oilfield liquid. Integrated performance assessment of biotechnologies for soil remediation should include the following diagnostic blocks: determination of oil product content, agrochemical and microbiological parameters, toxicological characteristics, mutagenicity of soil samples and phytoproductivity. Infrared spectrometry is recommended for determination of petroleum product content. This method provides for extraction of petroleum products from soil using tetrachloride carbon, chromatographic separation from associated organic compounds of other classes and quantitative analysis based on intensity of infrared absorption. Determination of agroecological parameters in soil samples involves рН of aqueous and salt extracts, chlorides, sulfates, dissolved solids of aqueous extract, humic matter, alkali hydrolyzable nitrogen, labile phosphorous compounds and exchange potassium. Microbiological monitoring includes determination of the amount of hydrocarbon oxidizing, heterotrophic microorganisms, micromycetes, total microbial biomass and basal respiration. Analysis of soil mutagenic activity is a part of soil assessment process. Of the several technologies available for identification of mutagenes, the most common are tests on microorganisms, fruit fly, in vitro tests using mammal cell cultures, mammalian in vivo micronucleus tests

Simulation of Coherent Diffraction Radiation Generation by Pico-Second Electron Bunches in an Open Resonator

In this report we present new approach for calculation of processes of diffraction radiation generation, storage and decay in an open resonator based on generalized surface current method. The radiation characteristics calculated using the developed approach were compared with those calculated using Gaussian-Laguerre modes method. The comparison shows reasonable coincidence of the results that allows to use developed method for investigation of more complicated resonators

Assessment of oil treatment facilities impact on radiation environment in adjacent areas

Upstream and downstream activities result in large environmental emissions of natural radionuclides. Specific activity of radionuclides in soil samples from Tatneft assets was analyzed to evaluate oil treatment facilities impact on radiation pollution of the environment. Reliable identification of radio-geochemical anomalies was achieved through landscape-geochemical zoning and detailed analysis using R statistical software

Cluster analysis and classification of process data by use of principal curves

Thesis (M.Ing.) -- University of Stellenbosch, 1999.ENGLISH SUMMARY: In this thesis a new method of clustering as wen as a new method of classification is proposed. Cluster analysis is a statistical method used to search for natural groups in an unstructured multivariate data set. Clusters are obtained in such. a way that the observations belonging to the same group are more alike than observations across groups. For instance, long data records are found in mineral processing plants, where the data can be reduced to clusters according to different ore types. Most of the existing clustering methods do not give reliable results when applied to engineering data, since these methods were mainly developed in the domains of psychology and biology. Classification analysis can be regarded as the natural continuation of cluster analysis. In order to classify objects, two types of observations are needed. The first are those observations whose group memberships are known a priori, which can be acquired through cluster analysis. The second kind of observations are those whose group memberships are unidentified. By means of classification these observations are allocated to one of the existing groups. Both of the proposed techniques are based on the use of a smooth one-dimensional curve, passing through the middle of the data set. To formalise such an idea, principal curves were developed by Hastie and Stuetzle (1989). A principal curve summarises the data in a non-linear fashion. For clustering, the principal curve of the entire unstructured data set is extracted. This one-dimensional representation of the data set is then used to search for different clusters. For classification, a principal curve is fitted to every known group in the data set. The observations to be assigned to one of the known groups are allocated to the group closest to the new point. Clustering with principal curves grouped engineering data better than most of the well-known clustering algorithms. Some shortcomings of this method were also established. Classification with principal curves gave similar, optimal results as compared to some existing classification methods. This classification method can be applied to data of any distribution, unlike statistical classification techniques.AFRIKAANSE OPSOMMING: In hierdie tesis word 'n nuwe metode elk vir trosanalise en klassifikasie analise voorgestel. Trosanalise is 'n statistiese tegniek waarrnee natuurlike groepe in 'n ongestruktureerde meerveranderlike datastel gevind word. Groepe word op so 'n wyse verkry dat die waamemings in dieselfde groep meer eenders is as waarnemings tussen groepe. Byvoorbeeld, in mineraalaanlegte is lang datarekords algemeen, wat deur middel van trosanalise gereduseer kan word na verskillende groepe, ooreenkomstig verskillende ertstipes. Die meerderheid bestaande groeperingsmetodes lewer nie betroubare resultate in hul toepassing op ingenieursdata nie, aangesien hierdie tegnieke meestal hul oorsprong in die sielkundige en biologiese velde het. Klassifikasie analise kan gesien word as die natuurlike opvolging van trosanalise. Om objekte te klassifiseer, word gebruik gemaak van twee soorte waarnemings. Die eerste tipe is daardie waamemings met a priori bekende groepsidentiteite, wat deur trosanalise gevind kan word. Die tweede soort is die waarnemings met onbekende groepsidentiteite. Elkeen van hierdie waarnemings kan deur middel van klassifikasie toegewys word aan een van die bestaande groepe. Beide hierdie voorgestelde tegnieke is gebaseer op die gebruik van 'n gladde, eendimensionele kromme wat deur die middel van die datastel beweeg. Om hierdie idee te formaliseer, is hoojkrommes ontwikkel deur Hastie en Stuetzle (1989). 'n Hoofkromme gee 'n nie-lineere opsomming van die data. Vir groeperingsdoeleindes word 'n hoofkromme uit die algehele ongestruktureerde datastel onttrek. Met klassifikasie word'n hootkurwe aan elke bekende groep in die datastel gepas. Die waameming wat aan een van die bestaande groepe toegewys moet word, word in die groep naaste aan die betrokke punt geplaas. Groepering met behulp van hoofkrommes, het met ingenieursdata beter resultate gelewer as meeste van die bestaande tegnieke. Deur middel van praktiese voorbeelde is sekere tekortkominge van hierdie groeperingsmetode vasgestel. Klassifikasie met behulp van hoofkrornmes lewer soortgelyke, optimale resultate as die van bekende vergelykende tegnieke. Die voorgestelde klassifikasie tegniek kan toegepas word op datastelle van enige verde ling, in teenstelling met die statistiese klassifikasietegnieke.Maste

One-step synthesis of 2,5-bis(chloromethyl)-1,4-dioxane from epichlorohydrin using ZIF-8, taking advantage of structural defects

We demonstrate herein the ZIF-8-only-mediated catalysis of the cyclodimerization of epichlorohydrin to 2,5-bis(chloromethyl)-1,4-dioxane in the absence of co-catalyst and solvent. The easy handling and economic aspects of ZIF-8, in addition to the one-step reaction to produce the cyclodimer, make this catalyst attractive even for industry. It has been clearly illustrated that the nature of the method used to synthesize ZIF-8 affected the yields of the cyclodimers. Specifically, the method employed to produce ZIF-8 directly influences the amount of crystal structural defects, which in turn impacts their performance as catalysts. To emphasize the role of defects, other physical properties, such as surface area and particle size, were controlled during the synthesis of the ZIF-8 catalysts. Remarkably, the amount of structural defects was quantified by temperature program desorption analysis

Status of the Novosibirsk terahertz FEL

The first stage of Novosibirsk high-power free-electron laser (FEL) was commissioned in 2003. It is based on a normal conducting CW energy recovery linac. Now the FEL provides electromagnetic radiation in the wavelength range of 120…180 micrometers. An average power is 400 W. The minimum measured line width is 0.3%, which is close to the Fourier-transform limit. A user-beamline assembly is in progress, parts of the full-scale machine are manufactured. The latter will operate in the near IR region and provide higher average powerВ 2003 году в Новосибирске заработала первая очередь мощного лазера на свободных электронах (ЛСЭ). Машина построена на базе линака-рекуператора непрерывного действия. В настоящее время ЛСЭ работает в диапазоне длин волн 120…180 мкм, его средняя мощность достигает 400 Вт. Минимальная измеренная ши- рина полосы излучения составляет 0.3%, что близко к теоретическому минимуму. В настоящее время монтируются каналы разводки излучения для пользователей, части полномасштабной машины запущены в производство. Полномасштабная машина будет работать в ближнем ИК-диапазоне и обладать большей мощностью.В 2003 році в Новосибірську заробила перша черга потужного лазера на вільних електронах (ЛВЕ). Машина побудована на базі лінака-рекуператора безперервної дії. Зараз ЛВЕ працює в діапазоні довжин хвиль 120...180 мкм, його середня потужність досягає 400 Вт. Мінімальна виміряна ширина смуги випромінювання становить 0.3%, що близько до теоретичного мінімуму. Зараз монтуються канали розведення випромінювання для користувачів, частини повномасштабної машини запущені у виробництво. Повномасштабна машина буде працювати в ближньому ІЧ-діапазоні і мати більшу потужність

First experimental results obtained using the highpower free electron laser at the siberian center for photochemical research

The first lasing near the wavelength of 140 µm was achieved in April 2003 using a high-power free electron laser (FEL) constructed at the Siberian Center for Photochemical Research. In this paper we briefly describe the design of the FEL driven by an accelerator–recuperator. Characteristics of the electron beam and terahertz laser radiation, obtained in the first experiments, are also presented in the paper.У Сибірському центрі фотохімічних досліджень навесні 2003 року отримана генерація випромінювання з довжиною хвилі 140 мкм на потужному лазері на вільних електронах (ЛВЕ). У роботі коротко описана конструкція ЛВЕ на базі прискорювача рекуператора і представлені результати вимірювання деяких параметрів електронного пучка і терагерцового випромінювання.В Сибирском центре фотохимических исследований весной 2003 года получена генерация излучения с длиной волны 140 мкм на мощном лазере на свободных электронах (ЛСЭ). В работе кратко описана конструкция ЛСЭ на базе ускорителя рекуператора и представлены результаты измерения некоторых параметров электронного пучка и терагерцового излучения