234 research outputs found

    Listening to the Snake; or, On Having a Spine

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    The western prohibition of reflection on what we call today religion begins not with a banned scholarly monograph or a taunted academic, but with a myth about a transgressive desire for mature moral knowledge and a subsequent sexual emotion, namely, Adam and Even\u27s shameful sense of being naked after accepting the serpent\u27s gift of the knowledge of good and evil. Elsewhere, I have explored some of the ways that western religions thought has sexualized this foundational myth in order to take up this gnosis as my own and explore the problems and promises of sexual desire, gender difference, sexual orientation, love, mortality, and -- above all -- the inescapably transgressive nature of radical thinking about religion in the contemporary academy

    Supportive Periodontal Therapy for Dental Implant Patients

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    Some of the early indicators of future implant failure are increased plaque accumulation, bleeding upon probing, increased probing pocket depth, abscess formation, bone loss seen under radiographic, retrograde tooth wear and broken restoration. A periodic supportive periodontal treatment visit allows for early detection and intervention to provide an opportunity to salvage an ailing implant. Presence of biofilm/plaque on the implant may progress to peri-implantitis with bone resorption. Microbial challenge in the oral environment may result in pathological reactions in peri-implant tissues and thereby compromising tissue integration. The long-term success of implants depends on adequate supportive periodontal treatment visits. Prevention of disease is a key factor in the aim of preserving the supporting tissues around implants. Thus, sufficient supportive therapy during maintenance is inevitable in order to achieve optimal results in implant dentistry

    Electron Paramagnetic Resonance of Mn2+-Doped Cadmium Formate Dihydrate Single Crystals

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    An electron paramagnetic resonance (EPR) study on Mn2+ doped Cadmium formate dihydrate single crystals is carried out. The EPR spectrum at room temperature exhibits only one out of five fine structural transitions which split into six hyperfine lines in all directions. The spectrum is simulated using the EasySpin program and evaluated spin Hamiltonian parameters. The simulated EPR spectrum is in good agreement with the experiment. By comparing direction cosines of spectroscopic splitting factor g and the direction cosines of different bonds determined by the crystal structure data it is found that Mn2+ enters the lattice substitutionally and only one Mn2+ site is identified. The obtained g and the hyperfine interaction constant A achieved are g = 2.006 ± 0.002, A = (98 ± 2) × 10−4 cm−1 and the second-order axial zero-field splitting parameter D = (60 ± 2) × 10−4 cm−1

    ESR and optical study of Cu2+-doped bis-(5,5′-diethylbarbiturato)bis picoline Zn(II)

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    ESR studies were conducted on Cu2+-doped bis-(5,5′-diethylbarbiturato)bis picoline Zn(II). Two Cu2+ lattice sites, Cu2+(I) and Cu2+(II), were identified. These sites exhibit two sets of four hyperfine lines in all directions. The g factor and hyperfine splitting were calculated from ESR absorption spectra: gx = 2.0201 ± 0.002, gy = 2.0900 ± 0.002, gz = 2.1634 ± 0.002, Ax = (30 ± 2) × 10−4 cm−1, Ay = (40 ± 2) × 10−4 cm−1 and Az = (154 ± 2) × 10−4 cm−1. It was found that Cu2+ enters the lattice substitutionally. The ground-state wavefunction of the Cu2+ ion in this lattice was determined from the spin Hamiltonian constants obtained from the ESR studies. With the help of an optical absorption study, the nature of the bonding in the complex is also discussed

    Crystalline Field Effect on bonding Parameters of VO2+ Ion

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    The interpretation of g factor of the VO2+ ion doped in defferent single crystals is made using the Stevens model where the symmetry of the crystalline field is tetragonal. The bonding parameters K|| and K┴, choosing the different parametric angle β, are determined. The value of K┴ should be less than 0.048 in order to have a better fit to the experimental g values

    A crowdsourced global data set for validating built-up surface layers

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    Several global high-resolution built-up surface products have emerged over the last five years, taking full advantage of open sources of satellite data such as Landsat and Sentinel. However, these data sets require validation that is independent of the producers of these products. To fill this gap, we designed a validation sample set of 50 K locations using a stratified sampling approach independent of any existing global built-up surface products. We launched a crowdsourcing campaign using Geo-Wiki (https://www.geo-wiki.org/) to visually interpret this sample set for built-up surfaces using very high-resolution satellite images as a source of reference data for labelling the samples, with a minimum of five validations per sample location. Data were collected for 10 m sub-pixels in an 80 × 80 m grid to allow for geo-registration errors as well as the application of different validation modes including exact pixel matching to majority or percentage agreement. The data set presented in this paper is suitable for the validation and inter-comparison of multiple products of built-up areas

    Ion conducting and paramagnetic d-PCL(530)/siloxane-based biohybrids doped with Mn 2+ ions

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    Amorphous α,ω-hidroxylpoly(ε-caprolactone) (PCL(530))/siloxane ormolytes doped with manganese perchlorate (Mn(ClO4)2) (d-PCL(530)/siloxanenMn(ClO4)2) with n = 20, 50, and 100), thermally stable up to at least 200 ºC, were synthesized by the sol-gel method. Ionic conductivity values up to 4.8×10−8 and 2.0×10−6 S cm−1 at about 25 and 100 ºC, respectively, where obtained for n = 20. FT-IR data demonstrated that the hydrogen bonding interactions present in the non-doped d-PCL(530)/siloxane host hybrid matrix were significantly influenced by the inclusion of Mn(ClO4)2 which promoted the formation of more oxyethylene/urethane and urethane/urethane aggregates. In addition, the Mn2+ ions bonded to all the “free” C=O groups of the urethane cross-links and to some of the “free” ester groups of the amorphous PCL(530) chains. In the electrolytes, the ClO4 − ions were found “free” and bonded to the Mn2+ ions along a bidentate configuration. The magnitude of the electron paramagnetic resonance (EPR) hyperfine constant of the analyzed samples (A ≈ 90×10-4 cm−1 ) suggested that the bonding between Mn2+ ions and the surrounding ligands is moderately ionic. The synthetized d-PCL(530)/siloxanenMn(ClO4)2 biohybrids have potential application in paramagnetic, photoelectrochemical and electrochromic devices.This work was supported by Fundacao para a Ciencia e a Tecnologia (FCT) and Feder (contracts PTDC/CTM-BPC/112774/2009, PEst-OE/QUI/UI0616/2014 and PEst-C/QUI/UI0686/2013) and COST Action MP1202 "Rational design of hybrid organic-inorganic interfaces". R.F.P.P. acknowledges FCT for a grant (SFRH/BPD/87759/2012). M.M.S. acknowledges CNPq (PVE grant 406617/2013-9), for a mobility grant. The financial support of the Brazilian agencies Capes and CNPq are gratefully acknowledged. Research was partially financed by the CeRTEV, Center for Research, Technology and Education in Vitreous Materials, FAPESP 2013/07793-6.info:eu-repo/semantics/publishedVersio
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