Magnetic Control of Valley Pseudospin in Monolayer WSe2

Local energy extrema of the bands in momentum space, or valleys, can endow electrons in solids with pseudo-spin in addition to real spin. In transition metal dichalcogenides this valley pseudo-spin, like real spin, is associated with a magnetic moment which underlies the valley-dependent circular dichroism that allows optical generation of valley polarization, intervalley quantum coherence, and the valley Hall effect. However, magnetic manipulation of valley pseudospin via this magnetic moment, analogous to what is possible with real spin, has not been shown before. Here we report observation of the valley Zeeman splitting and magnetic tuning of polarization and coherence of the excitonic valley pseudospin, by performing polarization-resolved magneto-photoluminescence on monolayer WSe2. Our measurements reveal both the atomic orbital and lattice contributions to the valley orbital magnetic moment; demonstrate the deviation of the band edges in the valleys from an exact massive Dirac fermion model; and reveal a striking difference between the magnetic responses of neutral and charged valley excitons which is explained by renormalization of the excitonic spectrum due to strong exchange interactions

Intervalley scattering by acoustic phonons in two-dimensional MoS2 revealed by double-resonance Raman spectroscopy

Double-resonance Raman scattering is a sensitive probe to study the electron-phonon scattering pathways in crystals. For semiconducting two-dimensional transition-metal dichalcogenides, the double-resonance Raman process involves different valleys and phonons in the Brillouin zone, and it has not yet been fully understood. Here we present a multiple energy excitation Raman study in conjunction with density functional theory calculations that unveil the double-resonance Raman scattering process in monolayer and bulk MoS2. Results show that the frequency of some Raman features shifts when changing the excitation energy, and first-principle simulations confirm that such bands arise from distinct acoustic phonons, connecting different valley states. The double-resonance Raman process is affected by the indirect-to-direct bandgap transition, and a comparison of results in monolayer and bulk allows the assignment of each Raman feature near the M or K points of the Brillouin zone. Our work highlights the underlying physics of intervalley scattering of electrons by acoustic phonons, which is essential for valley depolarization in MoS2

The valley Zeeman effect in inter- and intra-valley trions in monolayer WSe2

Monolayer transition metal dichalcogenides (TMDs) hold great promise for future information processing applications utilizing a combination of electron spin and valley pseudospin. This unique spin system has led to observation of the valley Zeeman effect in neutral and charged excitonic resonances under applied magnetic fields. However, reported values of the trion valley Zeeman splitting remain highly inconsistent across studies. Here, we utilize high quality hBN encapsulated monolayer WSe2 to enable simultaneous measurement of both intervalley and intravalley trion photoluminescence. We find the valley Zeeman splitting of each trion state to be describable only by a combination of three distinct g-factors, one arising from the exciton-like valley Zeeman effect, the other two, trion specific, g-factors associated with recoil of the excess electron. This complex picture goes significantly beyond the valley Zeeman effect reported for neutral excitons, and eliminates the ambiguity surrounding the magneto-optical response of trions in tungsten based TMD monolayers

Logarithmic contribution to the density of states of rectangular Andreev billiards.

We demonstrate that the exact quantum mechanical calculations are in good agreement with the semiclassical predictions for rectangular Andreev billiards, and therefore for a large number of open channels it is sufficient to investigate the Bohr-Sommerfeld approximation of the density of states . We present exact calculations of the classical path length distribution P(s), which is a nondifferentiable function of s, but whose integral is a smooth function with logarithmically dependent asymptotic behavior. Consequently, the density of states of rectangular Andreev billiards has two contributions on the scale of the Thouless energy: one which is well-known and is proportional to the energy, and the other which shows a logarithmic energy dependence. It is shown that the prefactors of both contributions depend on the geometry of the billiards but have universal limiting values when the width of the superconductor tends to zero

Effective description of the gap fluctuation for chaotic Andreev billiards.

We present a numerical study of the universal gap fluctuations and the ensemble averaged density of states (DOS) of chaotic two-dimensional Andreev billiards for finite Ehrenfest time τE . We show that the distribution function of the gap fluctuation for small enough Ehrenfest time can be related to that derived earlier for zero Ehrenfest time. An effective description based on the random matrix theory is proposed giving a good agreement with the numerical results. A systematic linear decrease of the mean field gap with increasing Ehrenfest time τE is observed but its derivative with respect to τE is in between two competing theoretical predictions and close to that of the recent numerical calculations for Andreev map. The exponential tail of the density of states is interpreted semiclassically

Magic Number Theory of Superconducting Proximity Effects and Wigner Delay Times in Graphene-Like Molecules

When a single molecule is connected to external electrodes by linker groups, the connectivity of the linkers to the molecular core can be controlled to atomic precision by appropriate chemical synthesis. Recently, the connectivity dependence of the electrical conductance and Seebeck coefficient of single molecules has been investigated both theoretically and experimentally. Here, we study the connectivity dependence of the Wigner delay time of single-molecule junctions and connectivity dependence of superconducting proximity effects, which occur when the external electrodes are replaced by superconductors. Although absolute values of transport properties depend on complex and often uncontrolled details of the coupling between the molecule and electrodes, we demonstrate that ratios of transport properties can be predicted using tables of "magic numbers," which capture the connectivity dependence of superconducting proximity effects and Wigner delay times within molecules. These numbers are calculated easily, without the need for large-scale computations. For normal-molecule-superconducting junctions, we find that the electrical conductance is proportional to the fourth power of their magic numbers, whereas for superconducting-molecule-superconducting junctions, the critical current is proportional to the square of their magic numbers. For more conventional normal-molecule-normal junctions, we demonstrate that delay time ratios can be obtained from products of magic number tables

Quantized invariant tori in Andreev billiards of mixed phase Space.

Comparing the results of exact quantum calculations and those obtained from the Einstein-Brillouin-Keller–like quantization scheme of Silvestrov et al. [Phys. Rev. Lett. 90, 116801 (2003)] we show that the spectrum of Andreev billiards of mixed phase space can basically be decomposed into a regular and an irregular part, similarly to normal billiards. We provide a numerical confirmation of the validity of this quantization scheme for individual eigenstates and discuss its accuracy

Proximity-Induced Subgaps in Andreev Billiard.

We examine the density of states of an Andreev billiard and show that any billiard with a finite upper cutoff in the path length distribution P(s) will possess an energy gap on the scale of the Thouless energy. An exact quantum mechanical calculation for different Andreev billiards gives good agreement with the semiclassical predictions when the energy dependent phase shift for Andreev reflections is properly taken into account. Based on this new semiclassical Bohr-Sommerfeld approximation of the density of states, we derive a simple formula for the energy gap. We show that the energy gap, in units of Thouless energy, may exceed the value predicted earlier from random matrix theory for chaotic billiards