33 research outputs found
Continuous and correlated nucleation during nonstandard island growth at Ag/Si(111)-7x7 heteroepitaxy
We present a combined experimental and theoretical study of submonolayer
heteroepitaxial growth of Ag on Si(111)-7x7 at temperatures from 420 K to 550 K
when Ag atoms can easily diffuse on the surface and the reconstruction 7x7
remains stable. STM measurements for coverages from 0.05 ML to 0.6 ML show that
there is an excess of smallest islands (each of them fills up just one
half-unit cell - HUC) in all stages of growth. Formation of 2D wetting layer
proceeds by continuous nucleation of the smallest islands in the proximity of
larger 2D islands (extended over several HUCs) and following coalescence with
them. Such a growth scenario is verified by kinetic Monte Carlo simulation
which uses a coarse-grained model based on a limited capacity of HUC and a
mechanism which increases nucleation probability in a neighbourhood of already
saturated HUCs (correlated nucleation). The model provides a good fit for
experimental dependences of the relative number of Ag-occupied HUCs and the
preference in occupation of faulted HUCs on temperature and amount of deposited
Ag. Parameters obtained for the hopping of Ag adatoms between HUCs agree with
those reported earlier for initial stages of growth. The model provides two new
parameters - maximum number of Ag atoms inside HUC, and on HUC boundary.Comment: LaTeX2e, BibTeX, 9 pages, 7 images, accepted to Phys. Rev.
Scanning tunneling microscopy at multiple voltage biases of stable "ring-like" Ag clusters on Si(111)-(77)
Since more than twenty years it is known that deposition of Ag onto
Si(111)-(7\times7) leads under certain conditions to the formation of so-called
"ring-like" clusters, that are particularly stable among small clusters. In
order to resolve their still unknown atomic structure, we performed voltage
dependent scanning tunneling microscopy (STM) measurements providing
interesting information about the electronic properties of clusters which are
linked with their atomic structure. Based on a structural model of Au cluster
on Si(111)-(7\times7) and our STM images, we propose an atomic arrangement for
the two most stable Ag "ring-like" clusters.Comment: 9 pages and 5 figure
Significant tax changes of the last 6 years in Hungary. The effect of tax changes on the management and liquidity of Kristály-99 Ltd. between 2008 and 2010.
Adóváltozások összefoglalása.BscPénzügy és Számvite