Field Drawing of South Wall Profile of Unit D from Penny (8BR158)

This document is a field map drawing of the south wall profile of Unit D. It is a scan of original paper documents generated in the field

Field Drawing of Profile of Feature D4 From Unit D From Penny (8BR158)

This document is a field map drawing of the feature profile of D4 from Unit D. It is a scan of original paper documents generated in the field

Field Drawing of Profile of Features D6, D8, D9 From Unit D From Penny (8BR158)

This document is a field map drawing of the profiles of features D6, D8, and D9 from Unit D. It is a scan of original paper documents generated in the field

Field Drawing of Plan View of Unit D From Penny (8BR158)

This document is a field map drawing of the plan view of Unit D. It is a scan of original paper documents generated in the field

Field Drawing of West Wall Profile of Unit D From Penny (8BR158)

This document is a field map drawing of the west wall profile of Unit D. It is a scan of original paper documents generated in the field

Field Drawing of Profile of Feature D5 From Unit D From Penny (8BR158)

This document is a field map drawing of the profile of feature D5 from Unit D. It is a scan of original paper documents generated in the field

Field Drawing of East Wall Profile of Unit D From Penny (8Br158)

This document is a field map drawing of the east wall profile of Unit D. It is a scan of original paper documents generated in the field

Redox-active ligand uranium complexes for approaches to multi-electron chemistry

While transition metal complexes are known to participate in multi-electron redox chemistry to facilitate important organometallic transformations, actinides, due to their low redox potentials, have a propensity to perform single electron chemistry. Because of its highly reducing nature, the ability to control the electronics of low-valent uranium is highly sought after as this may lead to unprecedented reactivity. Our lab has specifically been interested in mediating multi-electron transformations at uranium by employing redox-active ligands. Redox-active ligands can be used to facilitate multi-electron processes such as oxidative addition and reductive elimination at single metal centers. Using primarily 2,6-((Mes)N=CMe)2C5H3N) ( MesPDIMe) as a redox-active ligand, highly reduced uranium species bearing bulky cyclopentadienyl-based ancillary ligands, CpxU (MesPDIMe)(L) (x = P (1-(7,7-dimethylbenzyl)), * (1,2,3,4,5-pentamethyl); L = THF, HMPA), have been synthesized. These species have the ability to perform one, two, and four electron reduction of a variety of substrates. For examples, uranium mediated pinacol coupling of carbonylated substrates as well as oxidative addition toward two (X2, PhE-EPh, PhE-X) and four electron (Ar-N=N-Ar’, oxygen-atom transfer reagents) organic oxidants have been studied. with both radical and concerted addition pathways operable. Synthesis of a trans-dioxo species, Cp*UO2(MesPDIMe), has allowed for the study of the activation of the robust U=O double bonds—providing key insights into the necessary components for U=O bond scission. The lessons learned from the reductive silylation of this complex redox-active ligand species has allowed for application of these principles to simple UO 22+ systems

EFFECTS OF IMAGE CONGRUENCY ON PERSUASIVENESS AND RECALL IN DIRECT-TO-CONSUMER PRESCRIPTION DRUG ADVERTISING

Although direct-to-consumer (DTC) prescription drug advertising is regulated by the U.S. Food and Drug Administration, content analyses (Baird-Harris, 2009; Frosch, Krueger, Hornik, Cronbolm, & Berg, 2007; Kaphingst, DeJong, Rudd, & Daltroy, 2004; Wilkes, Bell, & Kravitz, 2000) and other studies (Davis, 2000, 2007) have suggested that advertisers may not disclose drug risks to the same extent that they describe drug benefits. This study builds on previous studies by Baird-Harris and Smith and Shaffer (2000) and aims to test the relationship between image congruency in televised DTC advertisements, recall of risks and benefits, and perceived ad persuasiveness. Advertisements for Nexium, Advair, and Lunesta were shown to college students in either their original (i.e., image incongruent) or modified (i.e., image neutral) form. In general, risks were easier to recall with image neutral advertisements (which were considered to be less persuasive), although results were not statistically significant. Gender had a significant interaction effect, suggesting that males and females process risks differently depending on images in a DTC advertisement. Despite its lack of significant findings, this study explores an underdeveloped area of research and provides a model for future studies

Shovel Test Pit Paperwork of Transect 5 from Quarterman (8BR223)

This document contains the field notes taken during phase 1 survey for transect 4