Phthalocyanine-based dumbbell-shaped molecule: synthesis, structure and charge transport studies

International audienceWe describe the synthesis of a fully conjugated donor-acceptor-donor triad (ZnPc-BTD-ZnPc) made of zinc phthalocyanine donor fragments (ZnPc) at both ends of a benzothiadiazole-based central dye (BTD). The molecule exhibits a broad absorption in the whole visible range. The introduction of sterically demanding alkoxy chains to the ZnPc fragments is found to limit the molecular organization to a short-range columnar order and the charge-carrier mobility to moderate values, but provides outstanding solubilities in organic solvents

Constraint Programming for Multi-criteria Conceptual Clustering

International audienceA conceptual clustering is a set of formal concepts (i.e., closed itemsets) that defines a partition of a set of transactions. Finding a conceptual clustering is an N P-complete problem for which Constraint Programming (CP) and Integer Linear Programming (ILP) approaches have been recently proposed. We introduce new CP models to solve this problem: a pure CP model that uses set constraints, and an hybrid model that uses a data mining tool to extract formal concepts in a preprocessing step and then uses CP to select a subset of formal concepts that defines a partition. We compare our new models with recent CP and ILP approaches on classical machine learning instances. We also introduce a new set of instances coming from a real application case, which aims at extracting setting concepts from an Enterprise Resource Planning (ERP) software. We consider two classic criteria to optimize, i.e., the frequency and the size. We show that these criteria lead to extreme solutions with either very few small formal concepts or many large formal concepts, and that compromise clusterings may be obtained by computing the Pareto front of non dominated clusterings

RF Induced Depolarizing Resonanaces, Spin Flip, and Partial Siberian Snakes

This research was sponsored by the National Science Foundation Grant NSF PHY-931478

Atelier ORIXAS: Projeto Tripartite África/Brasil/França: luta contra a desertificação: promoção da segurança alimentar e redução da pobreza.

No âmbito do Programa de Cooperação Científica Tripartite entre a Agence Inter-établissements de Recherche pourle Développement (AIRD), Agence Panafricaine de la Grande Muraille Verte (APGMV) e o Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq), o projeto ORIXAS "Observatórios Regionais Integrados de Regiões Árida, Semiáridas e Sub-úmidas secas" concebido em uma visão transversal, foca principalmente em metodologias e ferramentas para apoiar dispositivos de monitoramento ambiental para ser aplicado nos países inseridos na iniciativa africana Grande Muralha Verde - GMV (Burkina-Faso, Djibouti, Érythrée, Éthiopie, Mali, Mauritanie, Niger, Nigeria, Sénégal, Soudan, Tchad) e tem como objetivo desenvolver abordagens metodológicas e produtos compartilhados para melhorar a avaliação e monitoramento da desertificação e os impactos diretos ou indiretos de iniciativas para lutar contra o desmatamento e desertificação no âmbito da GMV. Esta publicação contempla aspectos metodológicos utilizados pelo projeto "ORIXAS" durante a primeira oficina de trabalho coletivo África-Brasil-França - Atelier (MAISON DE LA TÉLÉDÉTECTION), realizada de 10 a 19 de junho de 2014, em Montpellier França, objetivando informar a forma de execução dos estudos que vêm sendo realizados no escopo do projeto, visando principalmente a luta contra a desertificação, promoção da segurança alimentar e redução da pobreza nos países inseridos na iniciativa africana Grande Muralha Verde - GMV.bitstream/item/123193/1/DOC-174-Atelier-Orixas.pd

A review on development and application of plant-based bioflocculants and grafted bioflocculants

Flocculation is extensively employed for clarification through sedimentation. Application of eco-friendly plant-based bioflocculants in wastewater treatment has attracted significant attention lately with high removal capability in terms of solids, turbidity, color, and dye. However, moderate flocculating property and short shelf life restrict their development. To enhance the flocculating ability, natural polysaccharides derived from plants are chemically modified by inclusion of synthetic, nonbiodegradable monomers (e.g., acrylamide) onto their backbone to produce grafted bioflocculants. This review is aimed to provide an overview of the development and flocculating efficiencies of plant-based bioflocculants and grafted bioflocculants for the first time. Furthermore, the processing methods, flocculation mechanism, and the current challenges are discussed. All the reported studies about plant-derived bioflocculants are conducted under lab-scale conditions in wastewater treatment. Hence, the possibility to apply natural bioflocculants in food and beverage, mineral, paper and pulp, and oleo-chemical and biodiesel industries is discussed and evaluated

Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes

P. 32603-32614The coupling of biological and thermal technologies allows for the complete conversion of wastes into energy and biochar eliminating the problem of sludge disposal. The valorisation of fatty residues as co-substrate in a mesophilic digester of a wastewater treatment plant was studied considering an integrated approach of co-digestion and pyrolysis. Four digested samples obtained from co-digestion of sewage sludge and butcher’s fat waste were studied by thermogravimetric analysis. The activation energy corresponding to the sludge pyrolysis was calculated by a non-isothermal kinetic. Arrhenius activation energy was lower for the pyrolysis of a digested grease sample (92 kJ mol−1 obtained by OFW and 86 kJ mol−1 obtained by Vyazovkin) than for the pyrolysis of sewage sludge and its blends (164–190 kJ mol−1 obtained by OFW and 162–190 kJ mol−1 obtained by Vyazovkin). The analysis of the integrated approach of anaerobic co-digestion and pyrolysis of digestates demonstrated that the addition of 3% (w/v) of fat to the feeding sludge results in a 25% increase in the electricity obtained from biogas (if a combined heat and power unit is considered for biogas valorisation) and increasing the fat content to 15% allows for covering all thermal needs for drying of digestate and more than doubles (2.4 times) the electricity production when the scenario of digestion and pyrolysis is contemplated.S

Use of a transient model to simulate fluidized bed incineration of sewage sludge

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Role of inorganics on the biomass char gasification reactivity: A review involving reaction mechanisms and kinetics models

International audienceThis review article presents the effects of the inorganic elements and compounds on gasification and their mechanisms of action. The influence of inorganics on the gasification reaction have been described in the literature. However, the specific phenomena involved and the mechanisms of action are not stated with consensus. Therefore, the present review gathers the various mechanisms proposed by authors. Some have been demonstrated to be unlikely such as the mechanisms involving intercalation compounds or mechanical actions. In order to give more practical applications of this work, the review also gathers the gasification kinetic models that take these inorganic effects into account