267 research outputs found
Gas permeation through a polymer network
We study the diffusion of gas molecules through a two-dimensional network of
polymers with the help of Monte Carlo simulations. The polymers are modeled as
non-interacting random walks on the bonds of a two-dimensional square lattice,
while the gas particles occupy the lattice cells. When a particle attempts to
jump to a nearest-neighbor empty cell, it has to overcome an energy barrier
which is determined by the number of polymer segments on the bond separating
the two cells. We investigate the gas current as a function of the mean
segment density , the polymer length and the probability
for hopping across segments. Whereas decreases monotonically with
for fixed , its behavior for fixed and increasing
depends strongly on . For small, non-zero , appears to increase
slowly with . In contrast, for , it is dominated by the underlying
percolation problem and can be non-monotonic. We provide heuristic arguments to
put these interesting phenomena into context.Comment: Dedicated to Lothar Schaefer on the occasion of his 60th birthday. 11
pages, 3 figure
Autonomous detection and anticipation of jam fronts from messages propagated by inter-vehicle communication
In this paper, a minimalist, completely distributed freeway traffic
information system is introduced. It involves an autonomous, vehicle-based jam
front detection, the information transmission via inter-vehicle communication,
and the forecast of the spatial position of jam fronts by reconstructing the
spatiotemporal traffic situation based on the transmitted information. The
whole system is simulated with an integrated traffic simulator, that is based
on a realistic microscopic traffic model for longitudinal movements and lane
changes. The function of its communication module has been explicitly validated
by comparing the simulation results with analytical calculations. By means of
simulations, we show that the algorithms for a congestion-front recognition,
message transmission, and processing predict reliably the existence and
position of jam fronts for vehicle equipment rates as low as 3%. A reliable
mode of operation already for small market penetrations is crucial for the
successful introduction of inter-vehicle communication. The short-term
prediction of jam fronts is not only useful for the driver, but is essential
for enhancing road safety and road capacity by intelligent adaptive cruise
control systems.Comment: Published in the Proceedings of the Annual Meeting of the
Transportation Research Board 200
Reducing congestion in obstructed highways with traffic data dissemination using adhoc vehicular networks
Vehicle-to-vehicle communications can be used effectively for intelligent transport systems (ITSs) and location-aware services. The ability to disseminate information in an ad hoc fashion allows pertinent information to propagate faster through a network. In the realm of ITS, the ability to spread warning information faster and further is of great advantage to receivers. In this paper we propose and present a message-dissemination procedure that uses vehicular wireless protocols to influence vehicular flow, reducing congestion in road networks. The computational experiments we present show how a car-following model and lane-change algorithm can be adapted to “react” to the reception of information. This model also illustrates the advantages of coupling together with vehicular flow modelling tools and network simulation tools
Simple and selective spectrophotometric assay of diethylcarbamazine citrate using 2,3-dichloro-5,6-dicyano-p-benzoquinone and 2,4-dinitro phenol
Two simple, rapid and inexpensive spectrophotometric methods are described for the determination of diethylcarbamazine citrate (DEC) in bulk drug and formulations. The methods are based on the charge-transfer (CT) complexation reaction involving DEC as the n- donor and 2,3-dichloro-5,6-dicyano-p-benzoquinone DDQ] (method A) and 2,4-dinitro phenol DNP] (method B) as pi-acceptors in chloroform. The absorbance of CT complexes was measured at 480 nm for method A, and 420 nm for method B. Under optimum conditions, Beer's law was obeyed over the concentration ranges 4-90 and 4-100 mu g mL(-1) for methods A and B, respectively
Calibrating Car-Following Models using Trajectory Data: Methodological Study
The car-following behavior of individual drivers in real city traffic is
studied on the basis of (publicly available) trajectory datasets recorded by a
vehicle equipped with an radar sensor. By means of a nonlinear optimization
procedure based on a genetic algorithm, we calibrate the Intelligent Driver
Model and the Velocity Difference Model by minimizing the deviations between
the observed driving dynamics and the simulated trajectory when following the
same leading vehicle. The reliability and robustness of the nonlinear fits are
assessed by applying different optimization criteria, i.e., different measures
for the deviations between two trajectories. The obtained errors are in the
range between~11% and~29% which is consistent with typical error ranges
obtained in previous studies. In addition, we found that the calibrated
parameter values of the Velocity Difference Model strongly depend on the
optimization criterion, while the Intelligent Driver Model is more robust in
this respect. By applying an explicit delay to the model input, we investigated
the influence of a reaction time. Remarkably, we found a negligible influence
of the reaction time indicating that drivers compensate for their reaction time
by anticipation. Furthermore, the parameter sets calibrated to a certain
trajectory are applied to the other trajectories allowing for model validation.
The results indicate that ``intra-driver variability'' rather than
``inter-driver variability'' accounts for a large part of the calibration
errors. The results are used to suggest some criteria towards a benchmarking of
car-following models
Idiopathic Adolescent Scoliosis and self-concept
Introducción y objetivos. Esta investigación trata sobre adolescentes que presentan escoliosis idiopática. Queremos estudiar si la manifestación de tal patología tiene efectos psicológicos en el adolescente que la presenta y sobre todo en la imagen que percibe de sí mismo como de su entorno.
El objetivo del presente estudio se concreta en conocer la influencia de la escoliosis idiopática en el autoconcepto o imagen de si mismo en el adolescente.
Material y métodos. Estudio observacional. Muestra formada por 17 adolescentes de 10-18 años de edad. En primer lugar, al tratarse de menores de edad y con el fin de informar de las características del estudio, como de la participación en el mismo, se le pasó un consentimiento informado a los padres o tutores. Asimismo, se extrajeron una serie de datos biográficos para identificar aspectos como el perfil clínico y personal, diagnóstico, antecedentes familiares, datos personal y de ocio del paciente, a través de un cuestionario de datos biográficos. Finalmente se le pasó el cuestionario de Pierre-Harris que consta de 80 ítems que abarcan las siguientes dimensiones del concepto de si mismo: comportamiento, estatus general y académico, popularidad, felicidad y satisfacción, apariencia física, ansiedad.
Tras la recogida de los datos, se realizó un análisis de distribución de frecuencias, mediante el método estadístico SPSS v. 15.0 para Windows, con el cálculo de la media y la desviación típica, de los mismos.
Resultados.
Las puntuaciones del cuestionario de Pierre-Harris por cada sujeto, están por encima de la media establecida en cada dimensión. Solamente, en la dimensión de ansiedad, hay 5 sujetos por debajo de la media.
Conclusiones.
No se observó una imagen de sí mismo negativa o por debajo de la media en la muestra estudiada en ninguna dimensión del cuestionario. Solamente una de las dimensiones presentaba algunos individuos por debajo, por lo tanto, en la muestra estudiada con escoliosis idiopática del adolescente, la imagen de sí mismo es buena, por los valores encontrados.Terapia y Rehabilitació
PREPARATION AND PERFORMANCE STUDIES ON POLYETHERSULFONE ULTRAFILTRATION MEMBRANES MODIFIED WITH GELATIN FOR TREATMENT OF TANNERY AND DISTILLERY WASTEWATER
A novel human skin chamber model to study wound infection ex vivo
Wound infections with multi-drug resistant bacteria increase morbidity and mortality and have considerable socioeconomic impact. They can lead to impaired wound healing, resulting in rising treatment costs. The aim of this study was to investigate an ex vivo human wound infection model. Human full-thickness skin from the operating room (OR) was placed into the Bo-Drum® and cultivated for 7 days in an air–liquid interphase. On day 8, the skin was inoculated with either (1) Pseudomonas aeruginosa, (2) Staphylococcus aureus (105 CFU, n = 3) or (3) carrier control. 1, 3 and 7 days after inoculation colony forming units in the tissue/media were determined and cytokine expression was quantified. A reliable and reproducible wound infection could be established for 7 days. At this timepoint, 1.8 × 108 CFU/g tissue of P. aeruginosa and 2 × 107 CFU/g tissue of S. aureus were detected. Immunohistochemical analysis demonstrated bacterial infection and epidermolysis in infected skin. RT-PCR analysis exhibited a significant induction of proinflammatory cytokines after infection. The BO-drum® is a robust, easy-to-use, sterilizable and reusable ex vivo full-skin culture system. For investigation of wound infection, treatment and healing, the BO-drum® presents a convenient model and may help to standardize wound research
Formação de membranas planas celulósicas por espalhamento duplo para os processos de nanofiltração e osmose inversa
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