Identification by Raman spectroscopy of Mg–Fe content of olivine samples after impact at 6kms?1 onto aluminium foil and aerogel: In the laboratory and in Wild-2 cometary samples

AbstractOlivine, (Mg, Fe)2[SiO4], is a common mineral in extraterrestrial materials, whose Mg–Fe content varies from the end-members Forsterite (Mg2SiO4: denoted ‘Fo’) to Fayalite (Fe2SiO4: denoted ‘Fa’), together with minor quantities of Ca, Cr, Mn and Ni. Olivine is readily identified by Raman spectroscopy, and the Mg–Fe content can be obtained by precise measurements of the position of the two strongest Raman peaks. Here we show that this is not only true for pristine and highly crystalline olivine, but also for grains which have undergone high pressure shock processing during hypervelocity impact. We demonstrate that there are subtle changes to the Raman spectra in grains impacted at 6.1kms−1 onto aluminium foil and into low density aerogel. We quantify these changes, and also show that if no correction is made for the impact effects, the Fe:Mg molar ratio of the olivine can be significantly misinterpreted. This study was stimulated by NASA’s Stardust mission to comet 81P/Wild-2, since freshly ejected cometary dust particles were collected (via impact) onto aluminium foil and into aerogel cells at 6.1kms−1 and these samples are being investigated with Raman spectroscopy. We identify the residue in one Stardust impact crater on aluminium foil as arising from an olivine with a composition of Fo97–100

Heterogeneity in lunar anorthosite meteorites: Implications for the lunar magma ocean model

The lunar magma ocean model is a well-established theory of the early evolution of the Moon. By this model, the Moon was initially largely molten and the anorthositic crust that now covers much of the lunar surface directly crystallized from this enormous magma source. We are undertaking a study of the geochemical characteristics of anorthosites from lunar meteorites to test this model. Rare earth and other element abundances have been measured in situ in relict anorthosite clasts from two feldspathic lunar meteorites: Dhofar 908 and Dhofar 081. The rare earth elements were present in abundances of approximately 0.1 to approximately 10× chondritic (CI) abundance. Every plagioclase exhibited a positive Eu-anomaly, with Eu abundances of up to approximately 20×CI. Calculations of the melt in equilibrium with anorthite show that it apparently crystallized from a magma that was unfractionated with respect to rare earth elements and ranged in abundance from 8 to 80×CI. Comparisons of our data with other lunar meteorites and Apollo samples suggest that there is notable heterogeneity in the trace element abundances of lunar anorthosites, suggesting these samples did not all crystallize from a common magma source. Compositional and isotopic data from other authors also suggest that lunar anorthosites are chemically heterogeneous and have a wide range of ages. These observations may support other models of crust formation on the Moon or suggest that there are complexities in the lunar magma ocean scenario to allow for multiple generations of anorthosite formation

Stardust in STARDUST - the C, N, and O Isotopic Compositions of Wild 2 Cometary Matter in Al foil Impacts

In January 2006, the STARDUST mission successfully returned dust samples from the tail of comet 81P/Wild 2 in two principal collection media, low density silica aerogel and Al foil. While hypervelocity impacts at 6.1 km/s, the encounter velocity of STARDUST, into Al foils are generally highly disruptive for natural, silicate-dominated impactors, previous studies have shown that many craters retain sufficient residue to allow a determination of the elemental and isotopic compositions of the original projectile. We have used the NanoSIMS to perform C, N, and O isotope imaging measurements on four large (59-370 microns diameter) and on 47 small (0.32-1.9 microns diameter) Al foil impact craters as part of the STARDUST Preliminary Examination. Most analyzed residues in and around these craters are isotopically normal (solar) in their C, N, and O isotopic compositions. However, the debris in one large crater shows an average 15N enrichment of approx. 450 %, which is similar to the bulk composition of some isotopically primitive interplanetary dust particles. A 250 nm grain in another large crater has an O-17 enrichment with approx. 2.65 times the solar O-17/O-16 ratio. Such an O isotopic composition is typical for circumstellar oxide or silicate grains from red giant or asymptotic giant branch stars. The discovery of this circumstellar grain clearly establishes that there is authentic stardust in the cometary samples returned by the STARDUST mission. However, the low apparent abundance of circumstellar grains in Wild 2 samples and the preponderance of isotopically normal material indicates that the cometary matter is a diverse assemblage of presolar and solar system materials

“Dogged” Search of Fresh Nakhla Surfaces Reveals New Alteration Textures

Special Issue: 74th Annual Meeting of the Meteoritical Society, August 8-12, 2011, London, U.K.International audienceCarbonaceous chondrites are considered as amongst the most primitive Solar System samples available. One of their primitive characteristics is their enrichment in volatile elements.This includes hydrogen, which is present in hydrated and hydroxylated minerals. More precisely, the mineralogy is expected to be dominated by phyllosilicates in the case of CM chondrites, and by Montmorillonite type clays in the case of CI. Here, in order to characterize and quantify the abundance of lowtemperature minerals in carbonaceous chondrites, we performed thermogravimetric analysis of matrix fragments of Tagish Lake, Murchison and Orgueil

Palladium-coated kapton for use on dust detectors in low earth orbit: Performance under hypervelocity impact and atomic oxygen exposure

Observation of dust and debris in the near Earth environment is a field of great commercial and scientific interest, vital to maximising the operational and commercial life-cycle of satellites and reducing risk to increasing numbers of astronauts in Low Earth Orbit (LEO). To this end, monitoring and assessment of the flux of particles is of paramount importance to the space industry and wider socio-economic interests that depend upon data products/services from orbital infrastructure. We have designed a passive space dust detector to investigate the dust environment in LEO—the Orbital Dust Impact Experiment (ODIE). ODIE is designed for deployment in LEO for ~1 year, whereupon it would be returned to Earth for analysis of impact features generated by dust particles. The design emphasises the ability to distinguish between the orbital debris (OD) relating to human space activity and the naturally occurring micrometeoroid (MM) population at millimetre to submillimetre scales. ODIE is comprised of multiple Kapton foils, which have shown great potential to effectively preserve details of the impacting particles’ size and chemistry, with residue chemistry being used to interpret an origin (OD vs. MM). LEO is a harsh environment—the highly erosive effects of atomic oxygen damage Kapton foil—requiring the use of a protective coating. Common coatings available for Kapton (e.g., Al, SiO2, etc.) are problematic for subsequent analysis and interpretation of OD vs. MM origin, being a common elemental component of MM or OD, or having X-ray emission peaks overlapping with those of elements used to distinguish MM from OD. We thus propose palladium coatings as an alternative for this application. Here we report on the performance of palladium as a protective coating for a Kapton-based passive dust detector when exposed to atomic oxygen and impact. When subjected to impact, we observe that thicker coatings suffer delamination such that a coating of <50 nm is recommended. Analysis of atomic oxygen exposed samples shows a thin 10 nm coating of palladium significantly reduces the mass loss of Kapton, while coatings of 25 nm and over perform as well as or better than other commonly used coating

Sample return of interstellar matter (SARIM)

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Final Reports of the Stardust ISPE: Seven Probable Interstellar Dust Particles

The Stardust spacecraft carried the first spaceborne collector specifically designed to capture and return a sample of contemporary interstellar dust to terrestrial laboratories for analysis [1]. The collector was exposed to the interstellar dust stream in two periods in 2000 and 2002 with a total exposure of approximately 1.8 10(exp 6) square meters sec. Approximately 85% of the collector consisted of aerogel, and the remainder consisted of Al foils. The Stardust Interstellar Preliminary Examination (ISPE) was a consortiumbased effort to characterize the collection in sufficient detail to enable future investigators to make informed sample requests. Among the questions to be answered were these: How many impacts are consistent in their characteristics with interstellar dust, with interplanetary dust, and with secondary ejecta from impacts on the spacecraft? Are the materials amorphous or crystalline? Are organics detectable? An additional goal of the ISPE was to develop or refine the techniques for preparation, analysis, and curation of these tiny samples, expected to be approximately 1 picogram or smaller, roughly three orders of magnitude smaller in mass than the samples in other small particle collections in NASA's collections - the cometary samples returned by Stardust, and the collection of Interplanetary Dust Particles collected in the stratosphere

A cosmic dust detection suite for the deep space Gateway

The decade of the 2020s promises to be when humanity returns to space beyond Earth orbit, with several nations trying to place astronauts on the Moon, before going further into deep space. As part of such a programme, NASA and partner organisations, propose to build a Deep Space Gateway in lunar orbit by the mid-2020s. This would be visited regularly and offer a platform for science as well as for human activity. Payloads that can be mounted externally on the Gateway offer the chance to, amongst other scientific goals, monitor and observe the dust flux in the vicinity of the Moon. This paper looks at relevant technologies to measure dust which will impact the exposed surface at high speed. Flux estimates and a model payload of detectors are described. It is predicted that the flux is sufficient to permit studies of cometary vs. asteroidal dust and their composition, and to sample interstellar dust streams. This may also be the last opportunity to measure the natural dust flux near the Moon before the current, relatively pristine environment, is contaminated by debris, as humanity’s interest in the Moon generates increased activity in that vicinity in coming decades

Mineralogy and petrology of comet 81P/wild 2 nucleus samples

The bulk of the comet 81P/Wild 2 (hereafter Wild 2) samples returned to Earth by the Stardust spacecraft appear to be weakly constructed mixtures of nanometer-scale grains, with occasional much larger (over 1 micrometer) ferromagnesian silicates, Fe-Ni sulfides, Fe-Ni metal, and accessory phases. The very wide range of olivine and low-Ca pyroxene compositions in comet Wild 2 requires a wide range of formation conditions, probably reflecting very different formation locations in the protoplanetary disk. The restricted compositional ranges of Fe-Ni sulfides, the wide range for silicates, and the absence of hydrous phases indicate that comet Wild 2 experienced little or no aqueous alteration. Less abundant Wild 2 materials include a refractory particle, whose presence appears to require radial transport in the early protoplanetary disk