Three-terminal devices to examine single molecule conductance switching

We report electronic transport measurements of single-molecule transistor devices incorporating bipyridyl-dinitro oligophenylene-ethynylene dithiol (BPDN-DT), a molecule known to exhibit conductance switching in other measurement configurations. We observe hysteretic conductance switching in 8% of devices with measurable currents, and find that dependence of the switching properties on gate voltage is rare when compared to other single-molecule transistor devices. This suggests that polaron formation is unlikely to be responsible for switching in these devices. We discuss this and alternative switching mechanisms.Comment: 5 pages, 4 figures. Supporting material available upon reques

Kondo resonances and anomalous gate dependence of electronic conduction in single-molecule transistors

We report Kondo resonances in the conduction of single-molecule transistors based on transition metal coordination complexes. We find Kondo temperatures in excess of 50 K, comparable to those in purely metallic systems. The observed gate dependence of the Kondo temperature is inconsistent with observations in semiconductor quantum dots and a simple single-dot-level model. We discuss possible explanations of this effect, in light of electronic structure calculations.Comment: 5 pages, four figures. Supplementary material at http://www.ruf.rice.edu/~natelson/publications.htm

Inelastic electron tunneling via molecular vibrations in single-molecule transistors

In single-molecule transistors, we observe inelastic cotunneling features that correspond energetically to vibrational excitations of the molecule, as determined by Raman and infrared spectroscopy. This is a form of inelastic electron tunneling spectroscopy of single molecules, with the transistor geometry allowing in-situ tuning of the electronic states via a gate electrode. The vibrational features shift and change shape as the electronic levels are tuned near resonance, indicating significant modification of the vibrational states. When the molecule contains an unpaired electron, we also observe vibrational satellite features around the Kondo resonance.Comment: 5 pages, 4 figures. Supplementary information available upon reques

Single-Molecule Transistors: Electron Transfer in the Solid State

Single-molecule transistors (SMTs) incorporating individual small molecules are unique tools for examining the fundamental physics and chemistry of electronic transport in molecular systems at the single nanometer scale. We describe the fabrication and characterization of such devices, and the synthesis and surface attachment chemistry of novel transition metal complexes that have been incorporated into such SMTs. We present gate-modulated inelastic electron tunneling vibrational spectroscopy of single molecules, strong Kondo physics (TK ∼ 75 K) as evidence of excellent molecule/electrode electronic coupling, and a demonstration that covalent attachment chemistry can produce SMTs that survive repeated thermal cycling to room temperature. We conclude with a look ahead at the prospects for these nanoscale systems

Universal Scaling of Nonequilibrium Transport in the Kondo Regime of Single Molecule Devices

Scaling laws and universality are often associated with systems exhibiting emergent phenomena possessing a characteristic energy scale. We report nonequilibrium transport measurements on two different types of single-molecule transistor (SMT) devices in the Kondo regime. The conductance at low bias and temperature adheres to a scaling function characterized by two parameters. This result, analogous to that reported recently in semiconductor dots with Kondo temperatures two orders of magnitude lower, demonstrates the universality of this scaling form. We compare the extracted values of the scaling coefficients to previous experimental and theoretical results.Comment: 4.5 pages, 3 figure

Ices in Star-Forming Regions: First Results from VLT-ISAAC

The first results from a VLT-ISAAC program on L- and M-band infrared spectroscopy of deeply-embedded young stellar objects are presented. The advent of 8-m class telescopes allows high S/N spectra of low-luminosity sources to be obtained. In our first observing run, low- and medium-resolution spectra have been measured toward a dozen objects, mostly in the Vela and Chamaeleon molecular clouds. The spectra show strong absorption of H2O and CO ice, as well as weak features at `3.47' and 4.62 mu. No significant solid CH3OH feature at 3.54 mu is found, indicating that the CH3OH/H2O ice abundance is lower than toward some massive protostars. Various evolutionary diagnostics are investigated for a set of sources in Vela.Comment: 8 pages, 4 figures, to appear in The Origins of Stars and Planets: the VLT View, eds. J. Alves, M. McCaughrean (Springer Verlag

A hybrid heuristic approach for attribute-oriented mining

We present a hybrid heuristic algorithm, clusterAOI, that generates a more interesting generalised table than obtained via attribute-oriented induction (AOI). AOI tends to overgeneralise as it uses a fixed global static threshold to cluster and generalise attributes irrespective of their features, and does not evaluate intermediate interestingness. In contrast, clusterAOI uses attribute features to dynamically recalculate new attribute thresholds and applies heuristics to evaluate cluster quality and intermediate interestingness. Experimental results show improved interestingness, better output pattern distribution and expressiveness, and improved runtime. © 2013 Elsevier B.V

Electronic and optical properties of electromigrated molecular junctions

Electromigrated nanoscale junctions have proven very useful for studying electronic transport at the single-molecule scale. However, confirming that conduction is through precisely the molecule of interest and not some contaminant or metal nanoparticle has remained a persistent challenge, typically requiring a statistical analysis of many devices. We review how transport mechanisms in both purely electronic and optical measurements can be used to infer information about the nanoscale junction configuration. The electronic response to optical excitation is particularly revealing. We briefly discuss surface-enhanced Raman spectroscopy on such junctions, and present new results showing that currents due to optical rectification can provide a means of estimating the local electric field at the junction due to illumination.Comment: 19 pages, 8 figures, invited paper for forthcoming special issue of Journal of Physics: Condensed Matter. For other related papers, see http://www.ruf.rice.edu/~natelson/publications.htm

Golden gaskets: variations on the Sierpi\'nski sieve

We consider the iterated function systems (IFSs) that consist of three general similitudes in the plane with centres at three non-collinear points, and with a common contraction factor \la\in(0,1). As is well known, for \la=1/2 the invariant set, \S_\la, is a fractal called the Sierpi\'nski sieve, and for \la<1/2 it is also a fractal. Our goal is to study \S_\la for this IFS for 1/2<\la<2/3, i.e., when there are "overlaps" in \S_\la as well as "holes". In this introductory paper we show that despite the overlaps (i.e., the Open Set Condition breaking down completely), the attractor can still be a totally self-similar fractal, although this happens only for a very special family of algebraic \la's (so-called "multinacci numbers"). We evaluate \dim_H(\S_\la) for these special values by showing that \S_\la is essentially the attractor for an infinite IFS which does satisfy the Open Set Condition. We also show that the set of points in the attractor with a unique ``address'' is self-similar, and compute its dimension. For ``non-multinacci'' values of \la we show that if \la is close to 2/3, then \S_\la has a nonempty interior and that if \la<1/\sqrt{3} then \S_\la$ has zero Lebesgue measure. Finally we discuss higher-dimensional analogues of the model in question.Comment: 27 pages, 10 figure

The UTMOST Survey for Magnetars, Intermittent pulsars, RRATs and FRBs I: System description and overview

We describe the ongoing `Survey for Magnetars, Intermittent pulsars, Rotating radio transients and Fast radio bursts' (SMIRF), performed using the newly refurbished UTMOST telescope. SMIRF repeatedly sweeps the southern Galactic plane performing real-time periodicity and single-pulse searches, and is the first survey of its kind carried out with an interferometer. SMIRF is facilitated by a robotic scheduler which is capable of fully autonomous commensal operations. We report on the SMIRF observational parameters, the data analysis methods, the survey's sensitivities to pulsars, techniques to mitigate radio frequency interference and present some early survey results. UTMOST's wide field of view permits a full sweep of the Galactic plane to be performed every fortnight, two orders of magnitude faster than previous surveys. In the six months of operations from January to June 2018, we have performed $\sim 10$ sweeps of the Galactic plane with SMIRF. Notable blind re-detections include the magnetar PSR J1622$-$4950, the RRAT PSR J0941$-$3942 and the eclipsing pulsar PSR J1748$-$2446A. We also report the discovery of a new pulsar, PSR J1705$-$54. Our follow-up of this pulsar with the UTMOST and Parkes telescopes at an average flux limit of $\leq 20$ mJy and $\leq 0.16$ mJy respectively, categorizes this as an intermittent pulsar with a high nulling fraction of $< 0.002$Comment: Submitted to MNRAS, comments welcom