Pacific climate variability and the possible impact on global surface CO2 flux

<p>Abstract</p> <p>Background</p> <p>Climate variability modifies both oceanic and terrestrial surface CO2 flux. Using observed/assimilated data sets, earlier studies have shown that tropical oceanic climate variability has strong impacts on the land surface temperature and soil moisture, and that there is a negative correlation between the oceanic and terrestrial CO2 fluxes. However, these data sets only cover less than the most recent 20 years and are insufficient for identifying decadal and longer periodic variabilities. To investigate possible impacts of interannual to interdecadal climate variability on CO2 flux exchange, the last 125 years of an earth system model (ESM) control run are examined.</p> <p>Results</p> <p>Global integration of the terrestrial CO2 flux anomaly shows variation much greater in amplitude and longer in periodic timescale than the oceanic flux. The terrestrial CO2 flux anomaly correlates negatively with the oceanic flux in some periods, but positively in others, as the periodic timescale is different between the two variables. To determine the spatial pattern of the variability, a series of composite analyses are performed. The results show that the oceanic CO2 flux variability peaks when the eastern tropical Pacific has a large sea surface temperature anomaly (SSTA). By contrast, the terrestrial CO2 flux variability peaks when the SSTA appears in the central tropical Pacific. The former pattern of variability resembles the ENSO-mode and the latter the ENSO-modoki¹.</p> <p>Conclusions</p> <p>Our results imply that the oceanic and terrestrial CO2 flux anomalies may correlate either positively or negatively depending on the relative phase of these two modes in the tropical Pacific.</p

Excitonic Correlations in the Intermetallic Fe2VAl

The intermetallic compound Fe2VAl looks non-metallic in transport and strongly metallic in thermodynamic and photoemission data. It has in its band structure a highly differentiated set of valence and conduction bands leading to a semimetallic system with a very low density of carriers. The pseudogap itself is due to interaction of Al states with the d orbitals of Fe and V, but the resulting carriers have little Al character. The effects of generalized gradient corrections to the local density band structure as well spin-orbit coupling are shown to be significant, reducing the carrier density by a factor of three. Doping of this nonmagnetic compound by 0.5 electrons per cell in a virtual crystal fashion results in a moment of 0.5 bohr magnetons and destroys the pseudogap. We assess the tendencies toward formation of an excitonic condensate and toward an excitonic Wigner crystal, and find both to be unlikely. We propose a model is which the observed properties result from excitonic correlations arising from two interpenetrating lattices of distinctive electrons (e_g on V) and holes (t_2g on Fe) of low density (one carrier of each sign per 350 formula units).Comment: 8 2-column pages, 8 postscript figure

Twenty-first-century compatible co2 emissions and airborne fraction simulated by cmip5 earth system models under four representative concentration pathways

PublishedJournal ArticleThe carbon cycle is a crucial Earth system component affecting climate and atmospheric composition. The response of natural carbon uptake to CO2 and climate change will determine anthropogenic emissions compatible with a target CO2 pathway. For phase 5 of the Coupled Model Intercomparison Project (CMIP5), four future representative concentration pathways (RCPs) have been generated by integrated assessment models (IAMs) and used as scenarios by state-of-the-art climate models, enabling quantification of compatible carbon emissions for the four scenarios by complex, process-based models. Here, the authors present results from 15 such Earth system GCMs for future changes in land and ocean carbon storage and the implications for anthropogenic emissions. The results are consistent with the underlying scenarios but show substantial model spread. Uncertainty in land carbon uptake due to differences among models is comparable with the spread across scenarios. Model estimates of historical fossil-fuel emissions agree well with reconstructions, and future projections for representative concentration pathway 2.6 (RCP2.6) and RCP4.5 are consistent with the IAMs. For high-end scenarios (RCP6.0 and RCP8.5), GCMs simulate smaller compatible emissions than the IAMs, indicating a larger climate-carbon cycle feedback in the GCMs in these scenarios. For the RCP2.6 mitigation scenario, an average reduction of 50% in emissions by 2050 from 1990 levels is required but with very large model spread (14%-96%). The models also disagree on both the requirement for sustained negative emissions to achieve the RCP2.6 CO2 concentration and the success of this scenario to restrict global warming below 28C. All models agree that the future airborne fraction depends strongly on the emissions profile with higher airborne fraction for higher emissions scenarios. ©2013 American Meteorological Society.MOHC authors were supported by the JointDECC/Defra MetOffice Hadley Centre Climate Programme (GA01101), and work to performHadGEM2- ES and MPI-ESM CMIP5 simulations was supported by the EU-FP7 COMBINE project (Grant 226520). JS was supported by the EU-FP7 CARBOCHANGE project (Grant 284679). We acknowledge the World Climate Research Programme’s Working Group on Coupled Modelling, which is responsible for CMIP, and we thank the climate modeling groups (listed in Table 1 of this paper) for producing and making available their model output. For CMIP, the U.S. Department of Energy’s Program for Climate Model Diagnosis and Intercomparison provides coordinating support and led development of software infrastructure in partnership with the Global Organization for Earth System Science Portals. JT and CR were supported by the Research Council of Norway through the EarthClim (207711/E10) project

Effect of high dust amount on surface temperature during the Last Glacial Maximum: a modelling study using MIROC-ESM

The effect of aerosols is one of many uncertain factors in projections of future climate. However, the behaviour of mineral dust aerosols (dust) can be investigated within the context of past climate change. The Last Glacial Maximum (LGM) is known to have had enhanced dust deposition in comparison with the present, especially over polar regions. Using the Model for Interdisciplinary Research on Climate Earth System Model (MIROC-ESM), we conducted a standard LGM experiment following the protocol of the Paleoclimate Modelling Intercomparison Project phase 3 and sensitivity experiments. We imposed glaciogenic dust on the standard LGM experiment and investigated the impacts of glaciogenic dust and non-glaciogenic dust on the LGM climate. Global mean radiative perturbations by glaciogenic and non-glaciogenic dust were both negative, consistent with previous studies. However, glaciogenic dust behaved differently in specific regions; e.g. it resulted in less cooling over the polar regions. One of the major reasons for reduced cooling is the ageing of snow or ice, which results in albedo reduction via high dust deposition, especially near sources of high glaciogenic dust emission. Although the net radiative perturbations in the lee of high glaciogenic dust provenances are negative, warming by the ageing of snow overcomes this radiative perturbation in the Northern Hemisphere. In contrast, the radiative perturbation due to high dust loading in the troposphere acts to warm the surface in areas surrounding Antarctica, primarily via the longwave aerosol–cloud interaction of dust, and it is likely the result of the greenhouse effect attributable to the enhanced cloud fraction in the upper troposphere. Although our analysis focused mainly on the results of experiments using the atmospheric part of the MIROC-ESM, we also conducted full MIROC-ESM experiments for an initial examination of the effect of glaciogenic dust on the oceanic general circulation module. A long-term trend of enhanced warming was observed in the Northern Hemisphere with increased glaciogenic dust; however, the level of warming around Antarctica remained almost unchanged, even after extended coupling with the ocean.</p

Long-Term climate change commitment and reversibility: An EMIC intercomparison

This is the final version of the article. Available from the American Meteorological Society via the DOI in this record.This paper summarizes the results of an intercomparison project with Earth System Models of Intermediate Complexity (EMICs) undertaken in support of the Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report (AR5). The focus is on long-term climate projections designed to 1) quantify the climate change commitment of different radiative forcing trajectories and 2) explore the extent to which climate change is reversible on human time scales. All commitment simulations follow the four representative concentration pathways (RCPs) and their extensions to year 2300. MostEMICs simulate substantial surface air temperature and thermosteric sea level rise commitment following stabilization of the atmospheric composition at year-2300 levels. The meridional overturning circulation (MOC) is weakened temporarily and recovers to near-preindustrial values in most models for RCPs 2.6-6.0. The MOC weakening is more persistent for RCP8.5. Elimination of anthropogenic CO2 emissions after 2300 results in slowly decreasing atmospheric CO2 concentrations. At year 3000 atmospheric CO2 is still at more than half its year-2300 level in all EMICs forRCPs 4.5-8.5. Surface air temperature remains constant or decreases slightly and thermosteric sea level rise continues for centuries after elimination ofCO2 emissions in allEMICs.Restoration of atmosphericCO2 fromRCPto preindustrial levels over 100-1000 years requires large artificial removal of CO2 from the atmosphere and does not result in the simultaneous return to preindustrial climate conditions, as surface air temperature and sea level response exhibit a substantial time lag relative to atmospheric CO2. © 2013 American Meteorological Society.KZ and AJW acknowledge support from the National Science and Engineering Research Council (NSERC) Discovery Grant Program. AJW acknowledges support from NSERC's G8 Research Councils Initiative on Multilateral Research Funding Program. AVE and IIM were supported by the President of Russia Grant 5467.2012.5, by the Russian Foundation for Basic Research, and by the programs of the Russian Academy of Sciences. EC, TF, HG, and GPB acknowledge support from the Belgian Federal Science Policy Office. FJ, RS, and MS acknowledge support by the Swiss National Science Foundation and by the European Project CARBOCHANGE (Grant 264879), which received funding from the European Commission's Seventh Framework Programme (FP7/2007–2013). PBH and NRE acknowledge support from EU FP7 Grant ERMITAGE 265170

NMR and Mossbauer study of spin dynamics and electronic structure of Fe{2+x}V{1-x}Al and Fe2VGa

In order to assess the magnetic ordering process in Fe2VAl and the related material Fe2VGa, we have carried out nuclear magnetic resonance (NMR) and Mossbauer studies. 27Al NMR relaxation measurements covered the temperature range 4 -- 500 K in Fe(2+x)V(1-x)Al samples. We found a peak in the NMR spin-lattice relaxation rate, 27T1^-1, corresponding to the magnetic transitions in each of these samples. These peaks appear at 125 K, 17 K, and 165 K for x = 0.10, 0, and - 0.05 respectively, and we connect these features with critical slowing down of the localized antisite defects. Mossbauer measurements for Fe2VAl and Fe2VGa showed lines with no hyperfine splitting, and isomer shifts nearly identical to those of the corresponding sites in Fe3Al and Fe3Ga, respectively. We show that a model in which local band filling leads to magnetic regions in the samples, in addition to the localized antisite defects, can account for the observed magnetic ordering behavior.Comment: 5 pages, 3 figure

Carbon-concentration and carbon-climate feedbacks in CMIP6 models, and their comparison to CMIP5 models

Abstract. Results from the fully-, biogeochemically-, and radiatively-coupled simulations in which CO2 increases at a rate of 1 % per year (1pctCO2) from its pre-industrial value are analyzed to quantify the magnitude of two feedback parameters which characterize the coupled carbon-climate system. These feedback parameters quantify the response of ocean and terrestrial carbon pools to changes in atmospheric CO2 concentration and the resulting change in global climate. The results are based on eight comprehensive Earth system models from the fifth Coupled Model Intercomparison Project (CMIP5) and eleven models from the sixth CMIP (CMIP6). The comparison of model results from two CMIP phases shows that, for both land and ocean, the model mean values of the feedback parameters and their multi-model spread has not changed significantly across the two CMIP phases. The absolute values of feedback parameters are lower for land with models that include a representation of nitrogen cycle. The sensitivity of feedback parameters to the three different ways in which they may be calculated is shown and, consistent with existing studies, the most relevant definition is that calculated using results from the fully- and biogeochemically-coupled configurations. Based on these two simulations simplified expressions for the feedback parameters are obtained when the small temperature change in the biogeochemically-coupled simulation is ignored. Decomposition of the terms of these simplified expressions for the feedback parameters allows identification of the reasons for differing responses among ocean and land carbon cycle models. </jats:p

Long-term climate change commitment and reversibility: an EMIC intercomparison

This paper summarizes the results of an intercomparison project with Earth System Models of Intermediate Complexity (EMICs) undertaken in support of the Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report (AR5). The focus is on long-term climate projections designed to: (i) quantify the climate change commitment of different radiative forcing trajectories, and (ii) explore the extent to which climate change is reversible on human timescales. All commitment simulations follow the four Representative Concentration Pathways (RCPs) and their extensions to 2300. Most EMICs simulate substantial surface air temperature and thermosteric sea level rise commitment following stabilization of the atmospheric composition at year-2300 levels. The meridional overturning circulation (MOC) is weakened temporarily and recovers to near pre-industrial values in most models for RCPs 2.6–6.0. The MOC weakening is more persistent for RCP 8.5. Elimination of anthropogenic CO2 emissions after 2300 results in slowly decreasing atmospheric CO2 concentrations. At year 3000 atmospheric CO2 is still at more than half its year-2300 level in all EMICs for RCPs 4.5–8.5. Surface air temperature remains constant or decreases slightly and thermosteric sea level rise continues for centuries after elimination of CO2 emissions in all EMICs. Restoration of atmospheric CO2 from RCP to pre-industrial levels over 100–1000 years requires large artificial removal of CO2 from the atmosphere and does not result in the simultaneous return to pre-industrial climate conditions, as surface air temperature and sea level response exhibit a substantial time lag relative to atmospheric CO2