Resonance energy transfer from a fluorescent dye molecule to plasmon and electron-hole excitations of a metal nanoparticle

We study the distance dependence of the rate of electronic excitation energy transfer from a dye molecule to a metal nanoparticle. Using the spherical jellium model, we evaluate the rates corresponding to the excitation of l = 1, 2, and 3 modes of the nanoparticle. Our calculation takes into account both the electron-hole pair and the plasmon excitations of the nanoparticle. The rate follows conventional R^-6 dependence at large distances while small deviations from this behavior are observed at shorter distances. Within the framework of the jellium model, it is not possible to attribute the experimentally observed d^-4 dependence of the rate to energy transfer to plasmons or e-h pair excitations.Comment: 4 figure

Legacy data and cosmological constraints from the angular-size/redshift relation for ultra-compact radio sources

We have re-examined an ancient VLBI survey of ultra-comact radio sources at 2.29 GHz, which gave fringe amplitudes for 917 such objects with total flux density >0.5 Jy approximately. A number of cosmological investigations based upon this survey have been published in recent years. We have updated the sample with respect to both redshift and radio information, and now have full data for 613 objects, significantly larger than the number (337) used in earlier investigations. The corresponding angular-size/redshift diagram gives Omega_m=0.25+0.04/-0.03, Omega_\Lambda=0.97+0.09/-0.13 and K=0.22+0.07/-0.10. In combination with supernova data, and a simple-minded approach to CMB data based upon the angular size of the acoustic horizon, our best figures are Omega_m=0.298+0.025/-0.024, Omega_\Lambda=0.702+0.035/-0.036 and K= 0.000+0.021/-0.019. We have examined simple models of dynamical vacuum energy; the first, based upon a scalar potential V(phi)=omega_C^2 phi^2/2, gives w(0)=-1.00+0.06/-0.00, (dw/dz)_0=+0.00/-0.08; in this case conditions at z=0 require particular attention, to preclude behaviour in which phi becomes singular as z -->infinity. For fixed w limits are w=-1.20+0.15/-0.14. The above error bars are 68% confidence limits.Comment: 24 pages, 9 figure

Operator identities in q-deformed Clifford analysis

In this paper, we define a q-deformation of the Dirac operator as a generalization of the one dimensional q-derivative. This is done in the abstract setting of radial algebra. This leads to a q-Dirac operator in Clifford analysis. The q-integration on R(m), for which the q-Dirac operator satisfies Stokes' formula, is defined. The orthogonal q-Clifford-Hermite polynomials for this integration are briefly studied

Electron tunneling time measured by photoluminescence excitation correlation spectroscopy

The tunneling time for electrons to escape from the lowest quasibound state in the quantum wells of GaAs/AlAs/GaAs/AlAs/GaAs double-barrier heterostructures with barriers between 16 and 62 Å has been measured at 80 K using photoluminescence excitation correlation spectroscopy. The decay time for samples with barrier thicknesses from 16 Å (≈12 ps) to 34 Å(≈800 ps) depends exponentially on barrier thickness, in good agreement with calculations of electron tunneling time derived from the energy width of the resonance. Electron and heavy hole carrier densities are observed to decay at the same rate, indicating a coupling between the two decay processes

Making Sense of the Legendre Transform

The Legendre transform is an important tool in theoretical physics, playing a critical role in classical mechanics, statistical mechanics, and thermodynamics. Yet, in typical undergraduate or graduate courses, the power of motivation and elegance of the method are often missing, unlike the treatments frequently enjoyed by Fourier transforms. We review and modify the presentation of Legendre transforms in a way that explicates the formal mathematics, resulting in manifestly symmetric equations, thereby clarifying the structure of the transform algebraically and geometrically. Then we bring in the physics to motivate the transform as a way of choosing independent variables that are more easily controlled. We demonstrate how the Legendre transform arises naturally from statistical mechanics and show how the use of dimensionless thermodynamic potentials leads to more natural and symmetric relations.Comment: 11 pages, 3 figure

Generalized virial theorem in Palatini f(R)f(R) gravity

We use the collision-free Boltzmann equation in Palatini $f({\mathcal{R}})$ gravity to derive the virial theorem within the context of the Palatini approach. It is shown that the virial mass is proportional to certain geometrical terms appearing in the Einstein field equations which contribute to gravitational energy and that such geometric mass can be attributed to the virial mass discrepancy in cluster of galaxies. We then derive the velocity dispersion relation for clusters followed by the metric tensor components inside the cluster as well as the $f({\mathcal{R}})$ lagrangian in terms of the observational parameters. Since these quantities may also be obtained experimentally, the $f({\mathcal{R}})$ virial theorem is a convenient tool to test the viability of $f({\mathcal{R}})$ theories in different models. Finally, we discuss the limitations of our approach in the light of the cosmological averaging used and questions that have been raised in the literature against such averaging procedures in the context of the present work.Comment: 16 pages, to appear in PR

Deep ocean disposal of sewage sludge off Orange County, California: a research plan

Even though the discharge of sludge into the ocean via an outfall is not now permitted, this research plan has been prepared to show what could be learned with a full scale experimental sludge discharge of 150 dry tons/day by the County Sanitation Districts of Orange County into deep water (over 1000 feet). To provide a wide range of inputs and evaluation, a broad-based Research Planning Committee was established to advise the Environmental Quality Laboratory on the overall content and details of the research plan. Two meetings were held at EQL on: March 4-5, 1982: The entire Committee July 19-20, 1982: A working subgroup of the Committee The entire Committee is listed in Appendix B, with footnotes to indicate meeting attendance. Those unable to come to a meeting were asked to comment on the drafts by mail or telephone. We gratefully acknowledge the members of the Research Planning Committee for their generous help in formulating the research tasks and reviewing report drafts

Kramers-Kronig, Bode, and the meaning of zero

The implications of causality, as captured by the Kramers-Kronig relations between the real and imaginary parts of a linear response function, are familiar parts of the physics curriculum. In 1937, Bode derived a similar relation between the magnitude (response gain) and phase. Although the Kramers-Kronig relations are an equality, Bode's relation is effectively an inequality. This perhaps-surprising difference is explained using elementary examples and ultimately traces back to delays in the flow of information within the system formed by the physical object and measurement apparatus.Comment: 8 pages; American Journal of Physics, to appea

On the applicability of Backus' mantle filter theory

Geomagnetic jerks are sudden changes of trend in the geomagnetic secular variation. The Earth's mantle behaves as a filter for the jerks, causing a delayed and a smoothed signal at the Earth's surface. Backus' mantle filter theory relies on approximating the impulse response function (IRF) of the mantle by a Gaussian. The advantage of this theory is the linear relation between jerks' delay times and the mantle electrical conductivity, as expressed by kernels. However, the limitations of this theory arise when negative delay and/or smoothing times occur. The applicability of the mantle filter theory is examined by analysing the validity of the Gaussian as an approximation for the composite IRF (CIRF) at a given location. We show that the electrical conductivity of the lower mantle is mostly responsible for the jerk delay time. Alternating sign CIRFs might cause negative delay and/or smoothing times which prevents the use of the mantle filter theory. Adequate/inadequate Gaussian approximations to the CIRFs give small/large differences in the convolved jerk occurrence times. Most observatories yield positive time constants, but in most cases the difference in the jerk occurrence times exceeds 0.5y