Tabulator Redux: writing Into the Semantic Web

A first category of Semantic Web browsers were designed to present a given dataset (an RDF graph) for perusal, in various forms. These include mSpace, Exhibit, and to a certain extent Haystack. A second category tackled mechanisms and display issues around linked data gathered on the fly. These include Tabulator, Oink, Disco, Open Link Software's Data Browser, and Object Browser. The challenge of once that data is gathered, how might it be edited, extended and annotated has so far been left largely unaddressed. This is not surprising: there are a number of steep challenges for determining how to support editing information in the open web of linked data. These include the representation of both the web of documents and the web of things, and the relationships between them; ensuring the user is aware of and has control over the social context such as licensing and privacy of data being entered, and, on a web in which anyone can say anything about anything, helping the user intuitively select the things which they actually wish to see in a given situation. There is also the view update problem: the difficulty of reflecting user edits back through functions used to map web data to a screen presentation. In the latest version of the Tabulator project, described in this paper we have focused on providing the write side of the readable/writable web. Our approach has been to allow modification and addition of information naturally within the browsing interface, and to relay changes to the server triple by triple for least possible brittleness (there is no explicit 'save' operation). Challenges which remain include the propagation of changes by collaborators back to the interface to create a shared editing system. To support writing across (semantic) Web resources, our work has contributed several technologies, including a HTTP/SPARQL/Update-based protocol between an editor (or other system) and incrementally editable resources stored in an open source, world-writable 'data wiki'. This begins enabling the writable Semantic Web

Line Emission from Gas in Optically Thick Dust Disks around Young Stars

We present self-consistent models of gas in optically-thick dusty disks and calculate its thermal, density and chemical structure. The models focus on an accurate treatment of the upper layers where line emission originates, and at radii $\gtrsim 0.7$ AU. We present results of disks around $\sim 1{\rm M}_{\odot}$ stars where we have varied dust properties, X-ray luminosities and UV luminosities. We separately treat gas and dust thermal balance, and calculate line luminosities at infrared and sub-millimeter wavelengths from all transitions originating in the predominantly neutral gas that lies below the ionized surface of the disk. We find that the [ArII] 7$\mu$m, [NeII] 12.8$\mu$m, [FeI] 24$\mu$m, [SI] 25$\mu$m, [FeII] 26$\mu$m, [SiII] 35 $\mu$m, [OI] 63$\mu$m and pure rotational lines of H$_2$, H$_2$O and CO can be quite strong and are good indicators of the presence and distribution of gas in disks. We apply our models to the disk around the nearby young star, TW Hya, and find good agreement between our model calculations and observations. We also predict strong emission lines from the TW Hya disk that are likely to be detected by future facilities. A comparison of CO observations with our models suggests that the gas disk around TW Hya may be truncated to $\sim 120$ AU, compared to its dust disk of 174 AU. We speculate that photoevaporation due to the strong stellar FUV field from TW Hya is responsible for the gas disk truncation.Comment: Accepted to Astrophysical Journa

Low EUV Luminosities Impinging on Protoplanetary Disks

The amount of high-energy stellar radiation reaching the surface of protoplanetary disks is essential to determine their chemistry and physical evolution. Here, we use millimetric and centimetric radio data to constrain the EUV luminosity impinging on 14 disks around young (~2-10Myr) sun-like stars. For each object we identify the long-wavelength emission in excess to the dust thermal emission, attribute that to free-free disk emission, and thereby compute an upper limit to the EUV reaching the disk. We find upper limits lower than 10$^{42}$ photons/s for all sources without jets and lower than $5 \times 10^{40}$ photons/s for the three older sources in our sample. These latter values are low for EUV-driven photoevaporation alone to clear out protoplanetary material in the timescale inferred by observations. In addition, our EUV upper limits are too low to reproduce the [NeII] 12.81 micron luminosities from three disks with slow [NeII]-detected winds. This indicates that the [NeII] line in these sources primarily traces a mostly neutral wind where Ne is ionized by 1 keV X-ray photons, implying higher photoevaporative mass loss rates than those predicted by EUV-driven models alone. In summary, our results suggest that high-energy stellar photons other than EUV may dominate the dispersal of protoplanetary disks around sun-like stars.Comment: Accepted for publication to The Astrophysical Journa

Effective grain surface area in the formation of molecular hydrogen in interstellar clouds

In the interstellar clouds, molecular hydrogens are formed from atomic hydrogen on grain surfaces. An atomic hydrogen hops around till it finds another one with which it combines. This necessarily implies that the average recombination time, or equivalently, the effective grain surface area depends on the relative numbers of atomic hydrogen influx rate and the number of sites on the grain. Our aim is to discover this dependency. We perform a numerical simulation to study the recombination of hydrogen on grain surfaces in a variety of cloud conditions. We use a square lattice (with a periodic boundary condition) of various sizes on two types of grains, namely, amorphous carbon and olivine. We find that the steady state results of our simulation match very well with those obtained from a simpler analytical consideration provided the `effective' grain surface area is written as $\sim S^{\alpha}$, where, $S$ is the actual physical grain area and $\alpha$ is a function of the flux of atomic hydrogen which is determined from our simulation. We carry out the simulation for various astrophysically relevant accretion rates. For high accretion rates, small grains tend to become partly saturated with $H$ and $H_2$ and the subsequent accretion will be partly inhibited. For very low accretion rates, the number of sites to be swept before a molecular hydrogen can form is too large compared to the actual number of sites on the grain, implying that $\alpha$ is greater than unity.Comment: 8 pages, 5 figures in eps forma

Detection of shocked atomic gas in the Kleinmann-Low nebula

The 63 micrometer (3)p(1)-(3)P(2) fine structure line emission of neutral atomic oxygen at the center of the Orion nebula with a resolution of 30" is presented. There are three main emission peaks. One is associated with the region of strongest thermal radio continuum radiation close to the Trapezium cluster, and probably arises at the interface between the HII region and the dense Orion molecular cloud. The other two line emission peaks, associated with the Kleinmann Low nebula, are similar in both distribution and velocity to those of the 2 micrometer S(1) line of molecular hydrogen and of the high velocity wings of rotational CO emission. The OI emission from the KL nebula can be produced in the shocked gas associated with the mass outflows in this region and is an important coolant of the shocked gas

SWAS and Arecibo observations of H2O and OH in a diffuse cloud along the line-of-sight to W51

Observations of W51 with the Submillimeter Wave Astronomy Satellite (SWAS) have yielded the first detection of water vapor in a diffuse molecular cloud. The water vapor lies in a foreground cloud that gives rise to an absorption feature at an LSR velocity of 6 km/s. The inferred H2O column density is 2.5E+13 cm-2. Observations with the Arecibo radio telescope of hydroxyl molecules at ten positions in W51 imply an OH column density of 8E+13 cm-2 in the same diffuse cloud. The observed H2O/OH ratio of ~ 0.3 is significantly larger than an upper limit derived previously from ultraviolet observations of the similar diffuse molecular cloud lying in front of HD 154368. The observed variation in H2O/OH likely points to the presence in one or both of these clouds of a warm (T > 400) gas component in which neutral-neutral reactions are important sources of OH and/or H2O.Comment: 15 pages (AASTeX) including 4 (eps) figures. To appear in the Astrophysical Journa

A multi-wavelength study of a double intermediate-mass protostar - from large-scale structure to collimated jets

(abridged) We study a previously discovered protostellar source that is deeply embedded and drives an energetic molecular outflow. The source, UYSO1, is located close to IRAS 07029-1215 at a distance of ~1 kpc. The multi-wavelength observations resulted in the detection of a double intermediate-mass protostar at the location of UYSO1. In addition to the associated molecular outflow, with a projected size of 0.25 pc, two intersecting near-infrared jets with projected sizes of 0.4 pc and 0.2 pc were found. However, no infrared counterparts to the driving sources could be detected in sensitive near- to far-infrared observations. In interferometric millimeter observations, UYSO1 was resolved into two continuum sources with high column densities and gas masses of 3.5 Mo and 1.2 Mo, with a linear separation of 4200 AU. We report the discovery of a H2O maser toward one of the two sources. The total luminosity is roughly estimated to be ~50 Lo, shared by the two components, one of which is driving the molecular outflow that has a dynamical timescale of less than a few thousand years. The jets of the two individual components are not aligned. Submillimeter observations show that the region lacks typical hot-core chemistry. We thus find two protostellar objects, whose associated circumstellar and parent core masses are high enough to suggest that they may evolve into intermediate-mass stars. This is corroborated by their association with a very massive and energetic CO outflow, suggesting high protostellar accretion rates. The short dynamical timescale of the outflow, the pristine chemical composition of the cloud core and absence of hot core tracers, the absence of detectable radio continuum emission, and the very low protostellar luminosity argue for an extremely early evolutionary stage.Comment: 10 pages, 10 figures, accepted for publication in A&A; minor changes: typos corrected, revised argument in Section

Optimization of glycolipid synthesis in hydrophilic deep eutectic solvents

Glycolipids are considered an alternative to petrochemically based surfactants because they are non-toxic, biodegradable, and less harmful to the environment while having comparable surface-active properties. They can be produced chemically or enzymatically in organic solvents or in deep eutectic solvents (DES) from renewable resources. DES are non-flammable, non-volatile, biodegradable, and almost non-toxic. Unlike organic solvents, sugars are easily soluble in hydrophilic DES. However, DES are highly viscous systems and restricted mass transfer is likely to be a major limiting factor for their application. Limiting factors for glycolipid synthesis in DES are not generally well understood. Therefore, the influence of external mass transfer, fatty acid concentration, and distribution on initial reaction velocity in two hydrophilic DES (choline:urea and choline:glucose) was investigated. At agitation speeds of and higher than 60 rpm, the viscosity of both DES did not limit external mass transfer. Fatty acid concentration of 0.5 M resulted in highest initial reaction velocity while higher concentrations had negative effects. Fatty acid accessibility was identified as a limiting factor for glycolipid synthesis in hydrophilic DES. Mean droplet sizes of fatty acid-DES emulsions can be significantly decreased by ultrasonic pretreatment resulting in significantly increased initial reaction velocity and yield (from 0.15 ± 0.03 μmol glucose monodecanoate/g DES to 0.57 ± 0.03 μmol/g) in the choline: urea DES. The study clearly indicates that fatty acid accessibility is a limiting factor in enzymatic glycolipid synthesis in DES. Furthermore, it was shown that physical pretreatment of fatty acid-DES emulsions is mandatory to improve the availability of fatty acids

c2d Spitzer IRS spectra of embedded low-mass young stars: gas-phase emission lines

A survey of mid-IR gas-phase emission lines of H2, H2O and various atoms toward a sample of 43 embedded low-mass young stars in nearby star-forming regions is presented. The sources are selected from the Spitzer "Cores to Disks" (c2d) legacy program. The environment of embedded protostars is complex both in its physical structure (envelopes, outflows, jets, protostellar disks) and the physical processes (accretion, irradiation by UV and/or X-rays, excitation through slow and fast shocks) which take place. A key point is to spatially resolve the emission in the Spitzer-IRS spectra. An optimal extraction method is used to separate both spatially unresolved (compact, up to a few 100 AU) and spatially resolved (extended, 1000 AU or more) emission from the IRS spectra. The results are compared with the c2d disk sample and literature PDR and shock models to address the physical nature of the sources. Both compact and extended emission features are observed. Warm (Tex few 100 K) H2, observed through the pure rotational H2 S(0), S(1) and S(2) lines, and [S I] 25 mu emission is observed primarily in the extended component. [S I] is observed uniquely toward truly embedded sources and not toward disks. On the other hand hot (Tex>700 K) H2, observed primarily through the S(4) line, and [Ne II] emission is seen mostly in the compact component. [Fe II] and [Si II] lines are observed in both spatial components. Hot H2O emission is found in the compact component of some sources. The observed emission on >=1000 AU scales is characteristic of PDR emission and likely originates in the outflow cavities in the remnant envelope created by the stellar wind and jets from the embedded young stars. Weak shocks along the outflow wall can also contribute. The compact emission is likely of mixed origin, comprised of optically thick circumstellar disk and/or jet/outflow emission from the protostellar object.Comment: 22 pages, 11 figures, accepted for publication in A&