On Silicon Carbide Grains as the Carrier of the 21 Micron Emission Feature in Post-Asymptotic Giant Branch Stars

The mysterious 21mu emission feature seen in 12 proto-planetary nebulae (PPNe) remains unidentified since its first detection in 1989. Over a dozen of candidate materials have been proposed within the past decade, but none of them has received general acceptance. Very recently, silicon carbide (SiC) grains with impurities were suggested to be the carrier of this enigmatic feature, based on recent laboratory data that doped SiC grains exhibit a resonance at \~21mu. This proposal gains strength from the fact that SiC is a common dust species in carbon-rich circumstellar envelopes. However, SiC dust has a strong vibrational band at ~11.3mu. We show in this Letter that in order to be consistent with the observed flux ratios of the 11.3mu feature to the 21mu feature, the band strength of the 21mu resonance has to be very strong, too strong to be consistent with current laboratory measurements. But this does not yet readily rule out the SiC hypothesis since recent experimental results have demonstrated that the 21mu resonance of doped SiC becomes stronger as the C impurity increases. Further laboratory measurements of SiC dust with high fractions of C impurity are urgently needed to test the hypothesis of SiC as the carrier of the 21mu feature.Comment: 14 pages, 3 figures, accepted for publication in ApJ

On the Unusual Depletions toward Sk 155, or What Are the Small Magellanic Cloud Dust Grains Made of?

The dust in the Small Magellanic Cloud (SMC), an ideal analog of primordial galaxies at high redshifts, differs markedly from that in the Milky Way by exhibiting a steeply rising far-ultraviolet extinction curve, an absence of the 2175 Angstrom extinction feature, and a local minimum at ~12 micron in its infrared emission spectrum, suggesting the lack of ultrasmall carbonaceous grains (i.e. polycyclic aromatic hydrocarbon molecules) which are ubiquitously seen in the Milky Way. While current models for the SMC dust all rely heavily on silicates, recent observations of the SMC sightline toward Sk 155 indicated that Si and Mg are essentially undepleted and the depletions of Fe range from mild to severe, suggesting that metallic grains and/or iron oxides, instead of silicates, may dominate the SMC dust. However, in this Letter we apply the Kramers-Kronig relation to demonstrate that neither metallic grains nor iron oxides are capable of accounting for the observed extinction; silicates remain as an important contributor to the extinction, consistent with current models for the SMC dust.Comment: 12 pages, 3 figures; The Astrophysical Journal Letters, in pres

Determining the Dust Extinction of Gamma-ray Burst Host Galaxies: A Direct Method Based on Optical and X-ray Photometry

The dust extinction of gamma-ray bursts (GRBs) host galaxies, containing important clues to the nature of GRB progenitors and crucial for dereddening, is still poorly known. Here we propose a straightforward method to determine the extinction of GRB host galaxies by comparing the observed optical spectra to the intrinsic ones extrapolated from the X-ray spectra. The rationale for this method is from the standard fireball model: if the optical flux decay index equals to that of the X-ray flux, then there is no break frequency between the optical and X-ray bands, therefore we can derive the intrinsic optical flux from the X-ray spectra. We apply this method to three GRBs of which the optical and X-ray fluxes have the same decay indices and another one with inferred cooling break frequency, and obtain the rest-frame extinction curves of their host galaxies. The derived extinction curves are gray and do not resemble any extinction curves of local galaxies (e.g. the Milk Way, the Small/Large Magellanic Clouds, or nearby starburst galaxies). The amount of extinction is rather large (with visual extinction $A_V$ $\sim$ 1.6--3.4\magni). We model the derived extinction curves in terms of the silicate-graphite interstellar grain model. As expected from the ``gray'' nature of the derived extinction curve, the dust size distribution is skewed to large grains. We determine, for the first time, the local dust-to-gas ratios of GRB host galaxies using the model-derived dust parameters and the hydrogen column densities determined from X-ray absorptions.Comment: 14 pages, 2 figures, accepted for publication in Ap

The Spectral Energy Distribution of Dust Emission in the Edge-on spiral galaxy NGC 4631 as seen with Spitzer and the James Clerk Maxwell telescope

We explore variations in dust emission within the edge-on Sd spiral galaxy NGC 4631 using 3.6-160 μm Spitzer Space Telescope data and 450-850 μm JCMT data with the goals of understanding the relation between PAHs and dust emission, studying the variations in the colors of the dust emission, and searching for possible excess submillimeter emission compared to what is expected from dust models extrapolated from far-infrared wavelengths. The 8 μm PAH emission correlates best with 24 μm hot dust emission on 1.7 kpc scales, but the relation breaks down on 650 pc scales, possibly because of differences in the mean free paths between photons that excite the PAHs and photons that heat the dust and possibly because the PAHs are destroyed by the hard radiation fields within some star formation regions. The ratio of 8 μm PAH emission to 160 μm cool dust emission appears to vary as a function of radius. The 70 μm/160 μm and 160 μm/450 μm flux density ratios are remarkably constant even though the surface brightnesses vary by factors of 25, which suggests that the emission is from dust heated by a nearly uniform radiation field. Globally, we find an excess of 850-1230 μm emission relative to what would be predicted by dust models. The 850 μm excess is highest in regions with low 160 μm surface brightnesses, although the magnitude depends on the model fit to the data. We rule out variable emissivity functions or ~4 K dust as the possible origins of this 850 μm emission, but we do discuss the other possible mechanisms that could produce the emission

On Ultrasmall Silicate Grains in the Diffuse Interstellar Medium

The abundance of both amorphous and crystalline silicates in very small grains is limited by the fact that the 10 micron silicate emission feature is not detected in the diffuse ISM. On the basis of the observed IR emission spectrum for the diffuse ISM, the observed ultraviolet extinction curve, and the 10 micron silicate absorption profile, we obtain upper limits on the abundances of ultrasmall (a < 15 Angstrom) amorphous and crystalline silicate grains. Contrary to previous work, as much as ~20% of interstellar Si could be in a < 15 Angstrom silicate grains without violating observational constraints. Not more than ~5% of the Si can be in crystalline silicates (of any size).Comment: Submitted to ApJ Letters, 11 pages, 4 figures, Late

Excitation of Polycyclic Aromatic Hydrocarbon Emission: Dependence on Size Distribution, Ionization, and Starlight Spectrum and Intensity

Using physical models, we study the sensitivity of polycyclic aromatic hydrocarbon (PAH) emission spectra to the character of the illuminating starlight, to the PAH size distribution, and to the PAH charge distribution. The starlight models considered range from the emission from a 3 Myr old starburst, rich in far-ultraviolet (FUV) radiation, to the FUV-poor spectrum of the very old population of the M31 bulge. A wide range of starlight intensities is considered. The effects of reddening in dusty clouds are investigated for different starlight spectra. For a fixed PAH abundance parameter q PAH (the fraction of the total dust mass in PAHs with <103 C atoms), the fraction of the infrared power appearing in the PAH emission features can vary by a factor of two as the starlight spectrum varies from FUV-poor (M31 bulge) to FUV-rich (young starburst). We show how q PAH can be measured from the strength of the 7.7 μm emission. The fractional power in the 17 μm feature can be suppressed by high starlight intensities

The Spitzer Survey of the Small Magellanic Cloud: S3MC Imaging and Photometry in the Mid- and Far-Infrared Wavebands

We present the initial results from the Spitzer Survey of the Small Magellanic Cloud (S3MC), which imaged the star-forming body of the Small Magellanic Cloud (SMC) in all seven MIPS and IRAC wavebands. We find that the F_8/F_24 ratio (an estimate of PAH abundance) has large spatial variations and takes a wide range of values that are unrelated to metallicity but anticorrelated with 24 um brightness and F_24/F_70 ratio. This suggests that photodestruction is primarily responsible for the low abundance of PAHs observed in star-forming low-metallicity galaxies. We use the S3MC images to compile a photometric catalog of ~400,000 mid- and far-infrared point sources in the SMC. The sources detected at the longest wavelengths fall into four main categories: 1) bright 5.8 um sources with very faint optical counterparts and very red mid-infrared colors ([5.8]-[8.0]>1.2), which we identify as YSOs. 2) Bright mid-infrared sources with mildly red colors (0.16<[5.8]-[8.0]<0.6), identified as carbon stars. 3) Bright mid-infrared sources with neutral colors and bright optical counterparts, corresponding to oxygen-rich evolved stars. And, 4) unreddened early B stars (B3 to O9) with a large 24 um excess. This excess is reminiscent of debris disks, and is detected in only a small fraction of these stars (<5%). The majority of the brightest infrared point sources in the SMC fall into groups one to three. We use this photometric information to produce a catalog of 282 bright YSOs in the SMC with a very low level of contamination (~7%).Comment: Accepted for publication in The Astrophysical Journal. Given the draconian figure file-size limits implemented in astro-ph, readers are encouraged to download the manuscript with full quality images from http://celestial.berkeley.edu/spitzer/publications/s3mcsurvey.pd

Do the Infrared Emission Features Need Ultraviolet Excitation? The PAH Model in UV-Poor Reflection Nebulae

One of the major challenges to identification of the 3.3, 6.2, 7.7, 8.6, and 11.3um interstellar IR emission bands with polycyclic aromatic hydrocarbon (PAH) molecules has been the recent detection of these bands in regions with little UV illumination, since small, neutral PAH molecules have little or no absorption at visible wavelengths and therefore require UV photons for excitation. We show here that our "astronomical" PAH model, incorporating the experimental result that the visual absorption edge shifts to longer wavelength upon ionization and/or as the PAH size increases, can closely reproduce the observed infrared emission bands of vdB 133, a UV-poor reflection nebula. It is also shown that single-photon heating of ``astronomical'' PAHs in reflection nebulae near stars as cool as T_eff=3000K can result in observable emission at 6.2, 7.7, 8.6, and 11.3um. Illustrative mid-IR emission spectra are also calculated for reflection nebulae illuminated by cool stars with T_eff=3500, 4500, 5000K. These will allow comparison with future Space Infrared Telescope Facility (SIRTF) observations of vdB 135 (T_eff=3600K), vdB 47 (T_eff=4500K), and vdB 101 (T_eff=5000K). It is also shown that the dependence of the 12um IRAS emission relative to the total far-IR emission on the effective temperature of the exciting star is consistent with the PAH model expectation for 3000K < T_eff < 30000K.Comment: 12 pages. Submitted to The Astrophysical Journal Letter

Dust and Gas in the Magellanic Clouds from the HERITAGE Herschel Key Project. II. Gas-to-Dust Ratio Variations across ISM Phases

The spatial variations of the gas-to-dust ratio (GDR) provide constraints on the chemical evolution and lifecycle of dust in galaxies. We examine the relation between dust and gas at 10-50 pc resolution in the Large and Small Magellanic Clouds (LMC and SMC) based on Herschel far-infrared (FIR), H I 21 cm, CO, and Halpha observations. In the diffuse atomic ISM, we derive the gas-to-dust ratio as the slope of the dust-gas relation and find gas-to-dust ratios of 380+250-130 in the LMC, and 1200+1600-420 in the SMC, not including helium. The atomic-to-molecular transition is located at dust surface densities of 0.05 Mo pc-2 in the LMC and 0.03 Mo pc-2 in the SMC, corresponding to AV ~ 0.4 and 0.2, respectively. We investigate the range of CO-to-H2 conversion factor to best account for all the molecular gas in the beam of the observations, and find upper limits on XCO to be 6x1020 cm-2 K-1 km-1 s in the LMC (Z=0.5Zo) at 15 pc resolution, and 4x 1021 cm-2 K-1 km-1 s in the SMC (Z=0.2Zo) at 45 pc resolution. In the LMC, the slope of the dust-gas relation in the dense ISM is lower than in the diffuse ISM by a factor ~2, even after accounting for the effects of CO-dark H2 in the translucent envelopes of molecular clouds. Coagulation of dust grains and the subsequent dust emissivity increase in molecular clouds, and/or accretion of gas-phase metals onto dust grains, and the subsequent dust abundance (dust-to-gas ratio) increase in molecular clouds could explain the observations. In the SMC, variations in the dust-gas slope caused by coagulation or accretion are degenerate with the effects of CO-dark H2. Within the expected 5--20 times Galactic XCO range, the dust-gas slope can be either constant or decrease by a factor of several across ISM phases. Further modeling and observations are required to break the degeneracy between dust grain coagulation, accretion, and CO-dark H2

Infrared Emission from Interstellar Dust. II. The Diffuse Interstellar Medium

We present a quantitative model for the infrared emission from dust in the diffuse interstellar medium. The model consists of a mixture of amorphous silicate grains and carbonaceous grains, each with a wide size distribution ranging from molecules containing tens of atoms to large grains > 1 um in diameter. We assume that the carbonaceous grains have polycyclic aromatic hydrocarbon (PAH)-like properties at very small sizes, and graphitic properties for radii a > 50 A. On the basis of recent laboratory studies and guided by astronomical observations, we propose "astronomical" absorption cross sections for use in modeling neutral and ionized PAHs from the far ultraviolet to the far infrared. We also propose modifications to the far-infrared emissivity of "astronomical silicate". We calculate energy distribution functions for small grains undergoing "temperature spikes" due to stochastic absorption of starlight photons, using realistic heat capacities and optical properties. Using a grain size distribution consistent with the observed interstellar extinction, we are able to reproduce the near-IR to submillimeter emission spectrum of the diffuse interstellar medium, including the PAH emission features at 3.3, 6.2, 7.7, 8.6, and 11.3um. The model is compared with the observed emission at high Galactic latitudes as well as in the Galactic plane, as measured by COBE and IRTS. We calculate infrared emission spectra for our dust model heated by a range of starlight intensities, and we provide tabulated dust opacities (extended tables available at http://www.astro.princeton.edu/~draine/dust/dustmix.html)Comment: Final version published in ApJ, 554, 778 but with factor 1.086 error in Table 6 and Fig. 16 corrected. Main change from astro-ph version 1 is correction of typographical errors in Table 1, and correction of typo in eq. (A2). 51 pages, 16 figures, Late