2,801 research outputs found
Nature of the spin dynamics and 1/3 magnetization plateau in azurite
We present a specific heat and inelastic neutron scattering study in magnetic
fields up into the 1/3 magnetization plateau phase of the diamond chain
compound azurite Cu(CO)(OH). We establish that the
magnetization plateau is a dimer-monomer state, {\it i.e.}, consisting of a
chain of monomers, which are separated by dimers on the
diamond chain backbone. The effective spin couplings K
and K are derived from the monomer and dimer
dispersions. They are associated to microscopic couplings K,
K and a ferromagnetic K, possibly as
result of orbitals in the Cu-O bonds providing the superexchange
pathways.Comment: 5 pages, 4 figure
Magic Islands and Barriers to Attachment: A Si/Si(111)7x7 Growth Model
Surface reconstructions can drastically modify growth kinetics during initial
stages of epitaxial growth as well as during the process of surface
equilibration after termination of growth. We investigate the effect of
activation barriers hindering attachment of material to existing islands on the
density and size distribution of islands in a model of homoepitaxial growth on
Si(111)7x7 reconstructed surface. An unusual distribution of island sizes
peaked around "magic" sizes and a steep dependence of the island density on the
growth rate are observed. "Magic" islands (of a different shape as compared to
those obtained during growth) are observed also during surface equilibration.Comment: 4 pages including 5 figures, REVTeX, submitted to Physical Review
Study of the island morphology at the early stages of Fe/Mo(110) MBE growth
We present theoretical study of morphology of Fe islands grown at Mo(110)
surface in sub-monolayer MBE mode. We utilize atomistic SOS model with bond
counting, and interactions of Fe adatom up to third nearest neighbors. We
performed KMC simulations for different values of adatom interactions and
varying temperatures. We have found that, while for the low temperature islands
are fat fractals, for the temperature 500K islands have faceted rhombic-like
shape. For the higher temperature, islands acquire a rounded shape. In order to
evaluated qualitatively morphological changes, we measured averaged aspect
ration of islands. We calculated dependence of the average aspect ratio on the
temperature, and on the strength of interactions of an adatom with neighbors.Comment: 6 pages, 6 figures. Proceedings of 11-th Symposium on Surface
Physics, Prague 200
Monte Carlo study of Si(111) homoepitaxy
An attempt is made to simulate the homoepitaxial growth of a Si(111) surface
by the kinetic Monte Carlo method in which the standard Solid-on-Solid model
and the planar model of the (7x7) surface reconstruction are used in
combination.
By taking account of surface reconstructions as well as atomic deposition and
migrations, it is shown that the effect of a coorparative stacking
transformation is necessary for a layer growth.Comment: 4 pages, 5 figures. For Fig.1 of this article, please see Fig.2 of
Phys.Rev. B56, 3583 (1997). To appear in Phys.Rev.B. (June 1998
Vanadium (β-(Dimethylamino)ethyl)cyclopentadienyl Complexes with Diphenylacetylene Ligands
Reduction of the V(III) (β-(dimethylamino)ethyl)cyclopentadienyl dichloride complex [η5:η1-C5H4(CH2)2NMe2]VCl2(PMe3) with 1 equiv of Na/Hg yielded the V(II) dimer {[η5:η1-C5H4(CH2)2NMe2]V(µ-Cl)}2 (2). This compound reacted with diphenylacetylene in THF to give the V(II) alkyne adduct [η5:η1-C5H4(CH2)2NMe2]VCl(η2-PhC≡CPh). Further reduction of 2 with Mg in the presence of diphenylacetylene resulted in oxidative coupling of two diphenylacetylene groups to yield the diamagnetic, formally V(V), bent metallacyclopentatriene complex [η5:η1-C5H4(CH2)2NMe2]V(C4Ph4).
Heterogeneous microstructures tuned in a high throughput architecture
A new method applied to the sensor proposed by Zhang et al. in 2018 is demonstrated in this paper that combines the benefits of this design with the fast heating possible with nanocalorimetry. By applying a PID regulated pulse instead of a constant wattage, we unlock an accessible method to sense morphological changes occurring over short time periods that would be invisible to methods based only on heat capacity. In this study, multilayer Ni/Al thin films were linearly heated at 25, 50, 100, and 200 K/s to over 700°C, showing two distinct peaks in resistance change with activation energies of 554 and 747 kJ/mol, respectively. Through Scanning Transmission Electron Microscopy (STEM) and Energy Dispersive X-ray Analysis (EDX) analysis on cross sections taken ex situ from samples quenched before and after the peaks of interest, we find strong evidence that peak 1 corresponds to Ni diffusing through Al grain boundaries forming intermetallic phases that essentially block the highly conductive Al pathway. This presents the potential to design and calibrate novel heterogeneous structures in a high throughput manner
Why could Electron Spin Resonance be observed in a heavy fermion Kondo lattice?
We develop a theoretical basis for understanding the spin relaxation
processes in Kondo lattice systems with heavy fermions as experimentally
observed by electron spin resonance (ESR). The Kondo effect leads to a common
energy scale that regulates a logarithmic divergence of different spin kinetic
coefficients and supports a collective spin motion of the Kondo ions with
conduction electrons. We find that the relaxation rate of a collective spin
mode is greatly reduced due to a mutual cancelation of all the divergent
contributions even in the case of the strongly anisotropic Kondo interaction.
The contribution to the ESR linewidth caused by the local magnetic field
distribution is subject to motional narrowing supported by ferromagnetic
correlations. The developed theoretical model successfully explains the ESR
data of YbRh2Si2 in terms of their dependence on temperature and magnetic
field.Comment: 5pages, 1 Figur
Monoclonal antibodies against human astrocytomas and their reactivity pattern
The establishment of hybridomas after fusion of X63-Ag8.653 mouse myeloma cells and splenocytes from mice hyperimmunized against human astrocytomas is presented. The animals were primed with 5 × 106 chemically modified uncultured or cultured glioma cells. Six weeks after the last immunization step an intrasplenal booster injection was administrated and 3 days later the spleen cells were prepared for fusion experiments. According to the specificity analysis of the generated antibodies 7 hybridoma products (MUC 7-22, MUC 8-22, MUC 10-22, MUC 11-22, MUC 14-22, MUC 15-22 and MUC 2-63) react with gliomas, neuroblastomas and melanomas as well as with embryonic and fetal cells but do not recognize non-neurogenic tumors. The selected monoclonal antibodies (McAbs) of IgG1 and IgG2a isotypes are not extensively characterized but these antibodies have been demonstrated to be reactive with a panel of glioma cell lines with varying patterns of antigen distribution. Using the McAbs described above and a series of cryosections of glioma biopsies and paraffin sections of the same material as well as glioma cultures established from these, variable antigenic profiles among glioma cell populations could be demonstrated. From these results it is evident that there is not only a distinct degree of antigenic heterogeneity among and within brain tumors, but also that the pattern of antigenic expression can change continuously. Some of the glioma associated antigens recognized by the selected antibodies persist after fixation with methanol/acetone and Karnovsky's fixative and probably are oncoembryonic/oncofetal antigen(s). The data suggest that the use of McAbs recognizing tumor associated oncofetal antigens in immunohistochemistry facilitates objective typing of intracranial malignancies and precise analysis of fine needle brain/tumor biopsies in a sensitive and reproducible manner
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