Importance of many-body correlations in glass transition: an example from polydisperse hard spheres

Most of the liquid-state theories, including glass-transition theories, are constructed on the basis of two-body density correlations. However, we have recently shown that many-body correlations, in particular bond orientational correlations, play a key role in both the glass transition and the crystallization transition. Here we show, with numerical simulations of supercooled polydisperse hard spheres systems, that the lengthscale associated with any two-point spatial correlation function does not increase toward the glass transition. A growing lengthscale is instead revealed by considering many-body correlation functions, such as correlators of orientational order, which follows the lengthscale of the dynamic heterogeneities. Despite the growing of crystal-like bond orientational order, we reveal that the stability against crystallization with increasing polydispersity is due to an increasing population of icosahedral arrangements of particles. Our results suggest that, for this type of systems, many-body correlations are a manifestation of the link between the vitrification and the crystallization phenomena. Whether a system is vitrified or crystallized can be controlled by the degree of frustration against crystallization, polydispersity in this case.Comment: To appear in J. Chem. Phys. for a special issue on the Glass Transitio

External luminescence and photon recycling in near-field thermophotovoltaics

The importance of considering near-field effects on photon recycling and spontaneous emission in a thermophotovoltaic device is investigated. Fluctuational electrodynamics is used to calculate external luminescence from a photovoltaic cell as a function of emitter type, vacuum gap thickness between emitter and cell, and cell thickness. The observed changes in external luminescence suggest strong modifications of photon recycling caused by the presence of the emitter. Photon recycling for propagating modes is affected by reflection at the vacuum-emitter interface and is substantially decreased by the leakage towards the emitter through tunneling of frustrated modes. In addition, spontaneous emission by the cell can be strongly enhanced by the presence of an emitter supporting surface polariton modes. It follows that using a radiative recombination model with a spatially uniform radiative lifetime, even corrected by a photon recycling factor, is inappropriate. Applying the principles of detailed balance, and accounting for non-radiative recombination mechanisms, the impact of external luminescence enhancement in the near field on thermophotovoltaic performance is investigated. It is shown that unlike isolated cells, the external luminescence efficiency is not solely dependent on cell quality, but significantly increases as the vacuum gap thickness decreases below 400 nm for the case of an intrinsic silicon emitter. In turn, the open-circuit voltage and power density benefit from this enhanced external luminescence toward the emitter. This benefit is larger as cell quality, characterized by the contribution of non-radiative recombination, decreases.Comment: 44 pages, 8 figures, 1 table, 4 supplemental figure

Probabilistic Opacity in Refinement-Based Modeling

Given a probabilistic transition system (PTS) $\cal A$ partially observed by an attacker, and an $\omega$-regular predicate $\varphi$over the traces of $\cal A$, measuring the disclosure of the secret $\varphi$ in $\cal A$ means computing the probability that an attacker who observes a run of $\cal A$ can ascertain that its trace belongs to $\varphi$. In the context of refinement, we consider specifications given as Interval-valued Discrete Time Markov Chains (IDTMCs), which are underspecified Markov chains where probabilities on edges are only required to belong to intervals. Scheduling an IDTMC $\cal S$ produces a concrete implementation as a PTS and we define the worst case disclosure of secret $\varphi$ in ${\cal S}$ as the maximal disclosure of $\varphi$ over all PTSs thus produced. We compute this value for a subclass of IDTMCs and we prove that refinement can only improve the opacity of implementations

Alien Registration- Mathieu, John (Lewiston, Androscoggin County)

https://digitalmaine.com/alien_docs/28942/thumbnail.jp

DNA methylation and DNA methyltransferases

The prevailing views as to the form, function, and regulation of genomic methylation patterns have their origin many years in the past, at a time when the structure of the mammalian genome was only dimly perceived, when the number of protein-encoding mammalian genes was believed to be at least five times greater than the actual number, and when it was not understood that only ~10% of the genome is under selective pressure and likely to have biological function. We use more recent findings from genome biology and whole-genome methylation profiling to provide a reappraisal of the shape of genomic methylation patterns and the nature of the changes that they undergo during gametogenesis and early development. We observe that the sequences that undergo deep changes in methylation status during early development are largely sequences without regulatory function. We also discuss recent findings that begin to explain the remarkable fidelity of maintenance methylation. Rather than a general overview of DNA methylation in mammals (which has been the subject of many reviews), we present a new analysis of the distribution of methylated CpG dinucleotides across the multiple sequence compartments that make up the mammalian genome, and we offer an updated interpretation of the nature of the changes in methylation patterns that occur in germ cells and early embryos. We discuss the cues that might designate specific sequences for demethylation or de novo methylation during development, and we summarize recent findings on mechanisms that maintain methylation patterns in mammalian genomes. We also describe the several human disorders, each very different from the other, that are caused by mutations in DNA methyltransferase genes

A Perception Based Integrative Theory of Individual Behavior in Organizations

The purpose of this study was to develop an integrative theoretical approach to the study of individuals\u27 behavior in organizations, and to present an application of the approach to understanding the performance of Reserve Officer Training Corps (ROTC) cadets. Individuals\u27 perceptions of the environment were proposed to exist at three levels of analysis: (1) psychological climate (i.e., individual); (2) group climate; and organizational climate. Further, climate perceptions were proposed to result from the simultaneous influence of objective (i.e., actual) situational characteristics, and individuals\u27 needs and characteristics. The underlying dimensions that linked climate perceptions operationalized at the three levels of analysis with objective situational characteristics were referred to as life space dimensions and used in a causal model of three forms of affective responses: (1) a valence-instrumentality-expectancy motivation composite; (2) organizational commitment; and (3) general satisfaction, intention to remain in the service, and performance. Performance was examined both with self-ratings and with supervisor ratings. Army (N = 456) and Navy (N = 132) ROTC cadets from three universities in the Southeast participated in the study. The results provided support for the existence of aggregate climate perceptions and their relationship both to objective situational characteristics and to individual needs and characteristics. A causal model of life space dimensions, affective responses, intention to remain, and performance was proposed and tested with the Army sample. The hypothesized model was disconfirmed by the observed correlations of the Army sample using either self or supervisor performance ratings. Revised causal models for both self and supervisor rated performance were developed from the observed correlations of the Army sample and the earlier developed theory. The revised models were assessed using the Navy sample. The Army sample revised supervisor rated performance model exhibited a reasonable fit with the Navy sample. The revised self rated performance model failed to generalize to the Navy sample. Several differences between, and similarities among the findings from the two samples were highlighted. The results were discussed in terms of their application to the recruitment, selection, and training of ROTC cadets. In addition, limitations of the study were identified and an agenda for future applications of the theoretical approach to the study of individuals\u27 behavior in organizations was offered

COSMOS 2044: Lung morphology study, experiment K-7-28

Researchers examined the effect of microgravity during spaceflight on lung tissue. The ultrastructure of the left lungs of 5 Czechoslovakian Wister rats flown on the 13 day, 19+ hour Cosmos 2044 mission was examined and compared to 5 vivarium and 5 synchronous controls at 1-g conditions, and 5 rats exposed to 14 days of tail suspension. Pulmonary hemorrage and alveolar adema of unknown origin occurred to a greater extent in the flight, tail-suspended, and synchronous control animals, and in the dorsal regions of the lung when compared with the vivarium controls. The cause of these changes, which are possibly due to an increase in pulmonary vascular pressure, requires further investigation

A Canonical Form for Positive Definite Matrices

We exhibit an explicit, deterministic algorithm for finding a canonical form for a positive definite matrix under unimodular integral transformations. We use characteristic sets of short vectors and partition-backtracking graph software. The algorithm runs in a number of arithmetic operations that is exponential in the dimension $n$, but it is practical and more efficient than canonical forms based on Minkowski reduction

Mechanically Compliant Grating Reflectors for Optomechanics

We demonstrate micromechanical reflectors with a reflectivity as large as 99.4% and a mechanical quality factor Q as large as 7.8*10^5 for optomechanical applications. The reflectors are silicon nitride membranes patterned with sub-wavelength grating structures, obviating the need for the many dielectric layers used in conventional mirrors. We have employed the reflectors in the construction of a Fabry-Perot cavity with a finesse as high as F=1200, and used the optical response to probe the mechanical properties of the membrane. By driving the cavity with light detuned to the high-frequency side of a cavity resonance, we create an optical antidamping force that causes the reflector to self-oscillate at 211 kHz