Tin concentration in hydrothermal sulphides related to ultramafic rocks along the Mid-Atlantic Ridge: a mineralogical study

Hydrothermal polymetallic sulphides collected along the Mid-Atlantic Ridge and hosted in ultramafic rocks (Ashadze, Logatchev and Rainbow ore fields) are enriched in Sn compared to sulphides associated with volcanic rocks. At Logatchev, the averaged Sn ore concentration reaches 2000 ppm. The distribution of Sn among sulphides was studied using scanning electron microscopy and electron-microprobe analysis. The Sn concentration can reach up to 6 wt.% in sphalerite and 2 wt.% in chalcopyrite. Raman micro-spectroscopy investigation suggests that most of Sn is carried by stannite micro-inclusions in sulphides. According to the mineralogical and chemical studies, the following paragenetic sequence is proposed: (1) Sn (<1 wt.%) first precipitates as solid solution in low-temperature sphalerite; (2) at high temperature (300 C) and low pH (∼3) sphalerite is replaced by chalcopyrite; Sn, previously contained in the low-temperature sphalerite, contributes to the formation of stannite, as micro-inclusions in the replacement front; (3) eventually Sn is distributed within newly formed chalcopyrite (<1 wt.%). Tin enrichment of Zn-Cu ores appears as an indicator of hydrothermal reworking of ultramafic sulphide deposits

Methanogenesis and clay minerals diagenesis during the formation of dolomite nodules from the Tortonian marls of southern Spain

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REEs in authigenic carbonates: A new proxy for tracing fluid sources at cold seeps

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Mineralogy, fluid inclusions and stable isotope study of epithermal Au-Ag-Bi-Te mineralization from the SE Afar Rift (Djibouti)

International audienceIn this paper, the mineralogy, fluid inclusions and stable isotopes of hydrothermal veins from the SE part of the Afar Rift (Djibouti) were studied. Mineralization occurs as gold-silver in quartz/carbonate veins and is mainly associated with felsic volcanism. The morphologies and textures of quartz show crustiform colloform banding, massive and breccias. Microthermometric measurements were made on quartzhosted two phases (liquid + vapor) inclusions. Mean homogenization temperature ranges from 150°C to 340°C and ice-melting temperatures range from-0.2°C to-1.6°C indicating that inclusion solutions contain 0.35 to 2.7 eq. wt. % NaCl. Furthermore, δ18O and δ13C values from calcite range from 3.7 to 26.6 ‰ and-7.5 to 0.3 ‰, respectively. The presence of platy calcite and adularia are consistent with boiling conditions. Our study shows that the deposit of precious-metal deposition occurred at around 250°C and is linked to a fluid generated by the mixture of magmatic fluid, hydrothermal fluid and seawater. Please note that this is an author-produced PDF of an article accepted for publication following peer review. The definitive publisher-authenticated version is available on the publisher Web site

Publisher Correction: Formation of carbonate chimneys in the Mediterranean Sea linked to deep-water oxygen depletion

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First evidence of epithermal gold occurrences in the SE Afar Rift, Republic of Djibouti

International audienceThe geology of the Republic of Djibouti, in the SE Afar Triangle, is characterized by intense tectonic and bimodal volcanic activity that began as early as 25-30 Ma. Each magmatic event was accompanied by hydrothermal activity. Mineralization generally occurs as gold-silver bearing chalcedony veins and is associated with felsic volcanism. Eighty samples from mineralized hydrothermal chalcedony, quartz ± carbonate veins and breccias were studied from ten sites representing four major volcanic events that range in age from early Miocene to the present. The most recent veins are controlled by fractures at the edges of grabens established during the last 4 Myr. Gold in excess of 200 ppb is present in 30% of the samples, with values up to 16 ppm. Mineralogical compositions allowed us to identify different types of mineralization corresponding to different depths in the hydrothermal system: (1) surface and subsurface mineralization characterized by carbonate chimneys, gypsum, silica cap and quartz ± carbonate veins that are depleted in metals and Au; (2) shallow banded chalcedony ± adularia veins related to boiling that contain up to 16 ppm Au, occurring as native gold and electrum with pyrite, and tetradymite; (3) quartz veins with sulfides, and (4) epidote alteration in the deepest hydrothermal zones. Samples in which pyrite is enriched in As tend to have a high Au content. The association with bimodal volcanism, the occurrence of adularia and the native Au and electrum in banded chalcedony veins are typical of epithermal systems and confirm that this type of mineralization can occur in a young intracontinental rift system

Formation of carbonate chimneys in the Mediterranean Sea linked to deep-water oxygen depletion

Marine sediments at ocean margins vent substantial amounts of methane1, 2. Microbial oxidation of the methane released can trigger the precipitation of carbonate within sediments and support a broad diversity of seafloor ecosystems3, 4. The factors controlling microbial activity and carbonate precipitation associated with the seepage of submarine fluid over geological time remain poorly constrained. Here, we characterize the petrology and geochemistry of rocks sampled from metre-size build-ups of methane-derived carbonate chimneys located at the Amon mud volcano on the Nile deep-sea fan. We find that these carbonates comprise porous structures composed of aggregated spherules of aragonite, and closely resemble microbial carbonate reefs forming at present in the anoxic bottom waters of the Black Sea5. Using U-series dating, we show that the Amon carbonate build-ups formed between 12 and 7 thousand years ago, contemporaneous with the deposition of organic-rich sediments in the eastern Mediterranean, the so-called sapropel layer S1. We propose that the onset of deep-water suboxic or anoxic conditions associated with sapropel formation resulted in the development of intense anaerobic microbial activity at the sea floor, and thus the formation of carbonate chimneys