Youth water polo performance determinants: the INEX study

Due to the growing engagement of youth in water polo practice, we aimed to characterize age-grouped players across anthropometric, general and specific motor abilities and contextual domains. We have also examined the associations of players’ specific skills with their anthropometric and general motor characteristics. One-hundred-and-one male water polo players, grouped into 12-, 13- and 14-year age cohorts were recruited. One-way ANOVA explained age-cohort variance, and a multiple linear regression was used to assess the association between variables. The variance in cohorts was explained by arm span (25%), stature, hand breadth and length (17%) fat-free mass (18%), 20 m sprint (16%), sit-ups (18%), medicine ball throw (27%), anaerobic (31%) and aerobic performance (21%), change of direction (18%), and in-water vertical jump (14%). The variance of in-water vertical jump, 10 m sprint, change of direction and aerobic fitness for players’ anthropometric characteristics were, 32, 25, 14 and 10% (respectively). The players’ upper-limb explosive power explained 30, 22 and 17% of variance for in-water vertical jump, 10 m sprint and aerobic fitness, respectively. Body mass had an inverse, and arm span had a direct association with in-water vertical jump and swim velocity capability, arm span had an inverse and direct association with change of direction and aerobic fitness, respectively. The upper limbs’ explosive power related directly to in-water vertical jump and aerobic fitness skills, but inversely with 10 m sprint scores

A biophysical analysis on the arm stroke efficiency in front crawl swimming : comparing methods and determining the main performance predictors

Purpose: to compare different methods to assess the arm stroke efficiency ( ηF ), when swimming front crawl using the arms only on the Measurement of Active Drag System (MAD System) and in a free-swimming condition, and to identify biophysical adaptations to swimming on the MAD System and the main biophysical predictors of maximal swimming speed in the 200 m front crawl using the arms only ( v200m ). Methods: fourteen swimmers performed twice a 5 × 200 m incremental trial swimming the front crawl stroke using the arms only, once swimming freely, and once swimming on the MAD System. The total metabolic power was assessed in both conditions. The biomechanical parameters were obtained from video analysis and force data recorded on the MAD System. The ηF was calculated using: (i) direct measures of mechanical and metabolic power (power-based method); (ii) forward speed/hand speed ratio (speed-based method), and (iii) the simplified paddle-wheel model. Results: both methods to assess ηF on the MAD System differed (p < 0.001) from the expected values for this condition ( ηF = 1), with the speed-based method providing the closest values ( ηF ~0.96). In the free-swimming condition, the power-based ( ηF ~0.75), speed-based ( ηF ~0.62), and paddle-wheel ( ηF ~0.39) efficiencies were significantly different (p < 0.001). Although all methods provided values within the limits of agreement, the speed-based method provided the closest values to the “actual efficiency”. The main biophysical predictors of v200m were included in two models: biomechanical (R2 = 0.98) and physiological (R2 = 0.98). Conclusions: our results suggest that the speed-based method provides the closest values to the “actual ηF ” and confirm that swimming performance depends on the balance of biomechanical and bioenergetic parameter

Group-IV graphene- and graphane-like nanosheets

We performed a first principles investigation on the structural and electronic properties of group-IV (C, SiC, Si, Ge, and Sn) graphene-like sheets in flat and buckled configurations and the respective hydrogenated or fluorinated graphane-like ones. The analysis on the energetics, associated with the formation of those structures, showed that fluorinated graphane-like sheets are very stable, and should be easily synthesized in laboratory. We also studied the changes on the properties of the graphene-like sheets, as result of hydrogenation or fluorination. The interatomic distances in those graphane-like sheets are consistent with the respective crystalline ones, a property that may facilitate integration of those sheets within three-dimensional nanodevices

Enhancing Volumetric Bouligand-Minkowski Fractal Descriptors by using Functional Data Analysis

This work proposes and study the concept of Functional Data Analysis transform, applying it to the performance improving of volumetric Bouligand-Minkowski fractal descriptors. The proposed transform consists essentially in changing the descriptors originally defined in the space of the calculus of fractal dimension into the space of coefficients used in the functional data representation of these descriptors. The transformed decriptors are used here in texture classification problems. The enhancement provided by the FDA transform is measured by comparing the transformed to the original descriptors in terms of the correctness rate in the classification of well known datasets

Crystal Structure, Optical Second Harmonic Generation, Piezoelectricity and Pyroelectricity

Funding Information: This research was funded by Fundação para a Ciência e Tecnologia through FEDER (European Fund for Regional Development)-COMPETE-QREN-EU (ref. UID/FIS/04650/2013 and UID/FIS/04650/2019) and E-Field—“Electric-Field Engineered Lattice Distortions (E-FiELD) for optoelectronic devices”, ref. PTDC/NAN-MAT/0098/2020. C.S.B.G. acknowledges funding from Fundação para a Ciência e Tecnologia FCT/MCTES through projects UIDB/50006/2020, UIDP/50006/2020 and LA/P/0008/2020 of the Associate Laboratory for Green Chemistry—LAQV, UIDB/04378/2020, UIDP/04378/2020 and LA/P/0140/2020 of UCIBIO and Associate Laboratory i4HB, respectively. Funding Information: We acknowledge national funds (OE), through FCT − Fundação para a Ciência e a Tecnologia, I.P., in the scope of the framework contract foreseen in the numbers 4, 5 and 6 of article 23 of the Decree-Law 57/2016, of August 29, changed by Law 57/2017, of July 19. Publisher Copyright: © 2023 by the authors.A polymorph of glycyl-L-alanine HI.H2O is synthesized from chiral cyclo-glycyl-L-alanine dipeptide. The dipeptide is known to show molecular flexibility in different environments, which leads to polymorphism. The crystal structure of the glycyl-L-alanine HI.H2O polymorph is determined at room temperature and indicates that the space group is polar (P21), with two molecules per unit cell and unit cell parameters a = 7.747 Å, b = 6.435 Å, c = 10.941 Å, α = 90°, β = 107.53(3)°, γ = 90° and V = 520.1(7) Å3. Crystallization in the polar point group 2, with one polar axis parallel to the b axis, allows pyroelectricity and optical second harmonic generation. Thermal melting of the glycyl-L-alanine HI.H2O polymorph starts at 533 K, close to the melting temperature reported for cyclo-glycyl-L-alanine (531 K) and 32 K lower than that reported for linear glycyl-L-alanine dipeptide (563 K), suggesting that although the dipeptide, when crystallized in the polymorphic form, is not anymore in its cyclic form, it keeps a memory of its initial closed chain and therefore shows a thermal memory effect. Here, we report a pyroelectric coefficient as high as 45 µC/m2K occurring at 345 K, one order of magnitude smaller than that of semi-organic ferroelectric triglycine sulphate (TGS) crystal. Moreover, the glycyl-L-alanine HI.H2O polymorph displays a nonlinear optical effective coefficient of 0.14 pm/V, around 14 times smaller than the value from a phase-matched inorganic barium borate (BBO) single crystal. The new polymorph displays an effective piezoelectric coefficient equal to (Formula presented.), when embedded into electrospun polymer fibers, indicating its suitability as an active system for energy harvesting.publishersversionpublishe