BAs and boride III-V alloys

Boron arsenide, the typically-ignored member of the III-V arsenide series BAs-AlAs-GaAs-InAs is found to resemble silicon electronically: its Gamma conduction band minimum is p-like (Gamma_15), not s-like (Gamma_1c), it has an X_1c-like indirect band gap, and its bond charge is distributed almost equally on the two atoms in the unit cell, exhibiting nearly perfect covalency. The reasons for these are tracked down to the anomalously low atomic p orbital energy in the boron and to the unusually strong s-s repulsion in BAs relative to most other III-V compounds. We find unexpected valence band offsets of BAs with respect to GaAs and AlAs. The valence band maximum (VBM) of BAs is significantly higher than that of AlAs, despite the much smaller bond length of BAs, and the VBM of GaAs is only slightly higher than in BAs. These effects result from the unusually strong mixing of the cation and anion states at the VBM. For the BAs-GaAs alloys, we find (i) a relatively small (~3.5 eV) and composition-independent band gap bowing. This means that while addition of small amounts of nitrogen to GaAs lowers the gap, addition of small amounts of boron to GaAs raises the gap (ii) boron ``semi-localized'' states in the conduction band (similar to those in GaN-GaAs alloys), and (iii) bulk mixing enthalpies which are smaller than in GaN-GaAs alloys. The unique features of boride III-V alloys offer new opportunities in band gap engineering.Comment: 18 pages, 14 figures, 6 tables, 61 references. Accepted for publication in Phys. Rev. B. Scheduled to appear Oct. 15 200

Overview of Land Use Transport Models

The previous chapters in this Handbook have shown that spatial development, or land use, determines the need for spatial interaction, or transport, but that transport, by the accessibility it provides, also determines spatial development. However, it is difficult to empirically isolate impacts of land use on transport and vice versa because of the multitude of concurrent changes of other factors. This poses a problem if the likely impacts of integrated land-use and transport policies to reduce the demand for travel are to be predicted. There are principally three methods to predict those impacts. The first is to ask people how they would change their location and mobility behaviour if certain factors, such as land use regulations or transport costs, would change ('stated preference'). The second consists of drawing conclusions from observed decision behaviour of people under different conditions on how they would be likely to behave if these factors would change ('revealed preference'). The third method is to simulate human decision behaviour in mathematical models. All three methods have their advantages and disadvantages. Surveys can reveal also subjective factors of location and mobility decisions, however, their respondents can only make conjec-tures about how they would behave in still unknown situations, and the validity of such con

Nutrição mineral de hortaliças: XXIX. absorção de macronutrientes por quatro cultivares de morangueiro (Fragaria spp.)

The aim of this work was to estimate the differences in growth (dry weight basis), nutrients uptake, fruits yield, total uptake and exportation of nutrients among several strawberry cultivars: Campinas (IAC-2712), Camanducaia (IAC-3530), Monte Alegre (IAC-3113) and SH-2. The experimental was carried out in the Escola Superior de Agricultura "Luiz de Queiroz", in field conditions, in 1975/76. The soil belongs to Terra Roxa Estruturada type, and "Luiz de Queiroz" serie. This soil has been cultivated for more than 25 years. The experimental design was that randomized blocks with four replications and analysed together following the design of split-plot. The soil of the plots were revolved to a deep of 12 cm following application of 10 kg organic matter/m². The fertilizers were applied in the groove and in the same amount for all cultivars: Ammonium sulfate (20% N), 10 g/m; triple superphosphate (20% P(2)0(5)) 10 g/m; Potassium cloride (60% K(2)0), 10 g/m. Therty days after planting, 10 g/plant of ammonium sulfate was applied. After 76 days from planting, the firsa sample was taken. Other samples were taken in equal intervals of 20 days, up to 216 days. When a decrease in fruitproduction was noted. The sample (plants) were divided in stems, leaves and fruits and chemical analysis were made for N, R, K, Ca, Mg e S. The variation on production (dry matter) nutrient uptake' and fruits yield, were obtained from data calculated by adjusted regression equation analysis. The maxima point from these equations were taken to show the total nutrient uptake. From the data obtained, the following conclusions could be drawn. Growth - The dry matter of stems, leaves and fruits were different among the cultivars. The production of dry matter by the stems and fruits were linnear for all cultivars up to 196 and 216 days. The highest productions on dry matter varied between 15 to 25 g and 12 to 20 g/plant. The maximum production of dry matter in the leaves among the cultivars varied between 20 to 30 g at 196 and 173 days respectivelly. The cultivars Campinas (IAC-2712) and Camanducaia (IAC-3530) produced more dry matter than SH-2 cultivar. Nutrient uptake -< The were differences on nutrient content in stems and leaves among cultivars (R, K, Ca, S, B) and in the fruits for N, R, K, Mg, S. The highest absorption of nutrients (days after planting) is shown in Table I. Yield - No significant difference in fruit production was observed among the cultivars. The highest yield among the cultivars showed a variation between 103 to 151 g per plant at the 207 and 207 days,Efetuou-se um estudo para avaliar a absorção e a extração dos macronutrientes nos seguintes cultivares de morangueiro: Campinas (IAC-2712); Camanducaia (IAC-3530) ; Monte Alegre (IAC-3113) e SH-2 em condições de campo. A instalação deu-se em um solo pertencente ao grande grupo Terra Roxa Estruturada, e à série "Luiz de Queiroz" cultivado intensivamente com hortaliças há mais de 25 anos, em Piracicaba-SP. A adubação aplicada foi uniforme para todos os cultivares. São apresentadas as concentrações dos macronutrientes em porcentagem nos seguintes órgãos: caules, folhas e frutos dos cultivares em função da idade (X) em dias. Constatou-se que os cultivares diferem quanto à absorção dos macronutrientes (R, K, Ca e S em relação a caules e folhas, e, N, R, K, Mg e S em relação aos frutos). Constatou-se também que os cultivares extraem totais diferentes de R, K, Ca, Mg e S sendo as extrações de R pelos cultivares menores do que as extrações de Ca e Mg, e no global as de Mg são equivalentes às de S. As quantidades máximas extraídas pelos cultivares para uma população de 150.000 plantas/ha foram : N - 192 kg; R - 24-50 kg; K - 133-244 kg; Ca - 76-116 kg; Mg - 30-34 kg; S - 13-27 kg. - A maior produção de matéria seca tanto nos órgãos como na planta inteira, ocorreu nos cultivares Campinas (IAC-2712) e Camanducaia (IAC-3530) e a menor produção verificou-se no cultivar SH-2. - Os cultivares diferem na absorção dos nutrientes: R, K, Ca, S para caules e folhas. E para frutos, N, R, K, Mg e S. - Os cultivares atingem o máximo da absorção de nutrientes nos órgãos nas seguintes épocas, em dias: - Os cultivares extraem e exportam totais diferentes de R, K, Ca e Mg. - Tanto os macronutrientes são extraídos em quantidades mais elevadas através das folhas e em menor proporção por caules e frutos. - As extrações de N, K e Ca são mais altas que aquelas dos demais macronutrientes. - As extrações de R pelos cultivares são menores que as de Ca e Mg, sendo ainda as extrações de Ca superiores às de Mg, enquanto no global as de Mg são equivalentes às de S. - A extração de macronutrientes verifica-se na ordem decrescente: K, N, Ca, Mg, S e P

Velocity-space sensitivity of the time-of-flight neutron spectrometer at JET

The velocity-space sensitivities of fast-ion diagnostics are often described by so-called weight functions. Recently, we formulated weight functions showing the velocity-space sensitivity of the often dominant beam-target part of neutron energy spectra. These weight functions for neutron emission spectrometry (NES) are independent of the particular NES diagnostic. Here we apply these NES weight functions to the time-of-flight spectrometer TOFOR at JET. By taking the instrumental response function of TOFOR into account, we calculate time-of-flight NES weight functions that enable us to directly determine the velocity-space sensitivity of a given part of a measured time-of-flight spectrum from TOFOR

Relationship of edge localized mode burst times with divertor flux loop signal phase in JET

A phase relationship is identified between sequential edge localized modes (ELMs) occurrence times in a set of H-mode tokamak plasmas to the voltage measured in full flux azimuthal loops in the divertor region. We focus on plasmas in the Joint European Torus where a steady H-mode is sustained over several seconds, during which ELMs are observed in the Be II emission at the divertor. The ELMs analysed arise from intrinsic ELMing, in that there is no deliberate intent to control the ELMing process by external means. We use ELM timings derived from the Be II signal to perform direct time domain analysis of the full flux loop VLD2 and VLD3 signals, which provide a high cadence global measurement proportional to the voltage induced by changes in poloidal magnetic flux. Specifically, we examine how the time interval between pairs of successive ELMs is linked to the time-evolving phase of the full flux loop signals. Each ELM produces a clear early pulse in the full flux loop signals, whose peak time is used to condition our analysis. The arrival time of the following ELM, relative to this pulse, is found to fall into one of two categories: (i) prompt ELMs, which are directly paced by the initial response seen in the flux loop signals; and (ii) all other ELMs, which occur after the initial response of the full flux loop signals has decayed in amplitude. The times at which ELMs in category (ii) occur, relative to the first ELM of the pair, are clustered at times when the instantaneous phase of the full flux loop signal is close to its value at the time of the first ELM

TIC 172900988: A transiting circumbinary planet detected in one sector of TESS data

We report the first discovery of a transiting circumbinary planet detected from a single sector of Transiting Exoplanet Survey Satellite (TESS) data. During Sector 21, the planet TIC 172900988b transited the primary star and then five days later it transited the secondary star. The binary is itself eclipsing, with a period P ≈ 19.7 days and an eccentricity e ≈ 0.45. Archival data from ASAS-SN, Evryscope, KELT, and SuperWASP reveal a prominent apsidal motion of the binary orbit, caused by the dynamical interactions between the binary and the planet. A comprehensive photodynamical analysis of the TESS, archival and follow-up data yields stellar masses and radii of M1 = 1.2384 ± 0.0007 Me and R1 = 1.3827 ± 0.0016 Re for the primary and M2 = 1.2019 ± 0.0007 Me and R2 = 1.3124 ± 0.0012 Re for the secondary. The radius of the planet is R3 = 11.25 ± 0.44 R (1.004 ± 0.039RJup). The planet's mass and orbital properties are not uniquely determined-there are six solutions with nearly equal likelihood. Specifically, we find that the planet's mass is in the range of 824 M3 981 M (2.65 M3 3.09MJup), its orbital period could be 188.8, 190.4, 194.0, 199.0, 200.4, or 204.1 days, and the eccentricity is between 0.02 and 0.09. At V = 10.141 mag, the system is accessible for high-resolution spectroscopic observations, e.g., the Rossiter-McLaughlin effect and transit spectroscopy