Development of a carbon dioxide-water solid oxide electrolyte electrolysis system Annual report, 29 Mar. 1968 - 29 May 1969

Carbon dioxide-water solid oxide electrolyte electrolysis syste

Spin transitions induced by a magnetic field in quantum dot molecules

We present a theoretical study of magnetic field driven spin transitions of electrons in coupled lateral quantum dot molecules. A detailed numerical study of spin phases of artificial molecules composed of two laterally coupled quantum dots with N=8 electrons is presented as a function of magnetic field, Zeeman energy, and the detuning using real space Hartree-Fock Configuration Interaction (HF-CI) technique. A microscopic picture of quantum Hall ferromagnetic phases corresponding to zero and full spin polarization at filling factors $\nu=2$ and $\nu=1$, and ferrimagnetic phases resulting from coupling of the two dots, is presented.Comment: 12 pages, 18 figure

Approaching the Ground State of Frustrated A-site Spinels: A Combined Magnetization and Polarized Neutron Scattering Study

We re-investigate the magnetically frustrated, {\it diamond-lattice-antiferromagnet} spinels FeAl$_2$O$_4$ and MnAl$_2$O$_4$ using magnetization measurements and diffuse scattering of polarized neutrons. In FeAl$_2$O$_4$, macroscopic measurements evidence a "cusp" in zero field-cooled susceptibility around 13~K. Dynamic magnetic susceptibility and {\it memory effect} experiments provide results that do not conform with a canonical spin-glass scenario in this material. Through polarized neutron scattering studies, absence of long-range magnetic order down to 4~K is confirmed in FeAl$_2$O$_4$. By modeling the powder averaged differential magnetic neutron scattering cross-section, we estimate that the spin-spin correlations in this compound extend up to the third nearest-neighbour shell. The estimated value of the Land\'{e} $g$ factor points towards orbital contributions from Fe$^{2+}$. This is also supported by a Curie-Weiss analysis of the magnetic susceptibility. MnAl$_2$O$_4$, on the contrary, undergoes a magnetic phase transition into a long-range ordered state below $\approx$ 40~K, which is confirmed by macroscopic measurements and polarized neutron diffraction. However, the polarized neutron studies reveal the existence of prominent spin-fluctuations co-existing with long-range antiferromagnetic order. The magnetic diffuse intensity suggests a similar short range order as in FeAl$_2$O$_4$. Results of the present work supports the importance of spin-spin correlations in understanding magnetic response of frustrated magnets like $A$-site spinels which have predominant short-range spin correlations reminiscent of the "spin liquid" state.Comment: 10 pages, 10 figures, double-column, accepted in Phys. Rev. B, 201

Hunting for brown dwarf binaries and testing atmospheric models with X-Shooter

The determination of the brown dwarf binary fraction may contribute to the understanding of the substellar formation mechanisms. Unresolved brown dwarf binaries may be revealed through their peculiar spectra or the discrepancy between optical and near-infrared spectral type classification. We obtained medium-resolution spectra of 22 brown dwarfs with these characteristics using the X-Shooter spectrograph at the VLT. We aimed to identify brown dwarf binary candidates, and to test if the BT-Settl 2014 atmospheric models reproduce their observed spectra. To find binaries spanning the L-T boundary, we used spectral indices and compared the spectra of the selected candidates to single spectra and synthetic binary spectra. We used synthetic binary spectra with components of same spectral type to determine as well the sensitivity of the method to this class of binaries. We identified three candidates to be combination of L plus T brown dwarfs. We are not able to identify binaries with components of similar spectral type. In our sample, we measured minimum binary fraction of $9.1^{+9.9}_{-3.0}$. From the best fit of the BT-Settl models 2014 to the observed spectra, we derived the atmospheric parameters for the single objects. The BT-Settl models were able to reproduce the majority of the SEDs from our objects, and the variation of the equivalent width of the RbI (794.8 nm) and CsI (852.0 nm) lines with the spectral type. Nonetheless, these models did not reproduce the evolution of the equivalent widths of the NaI (818.3 nm and 819.5 nm) and KI (1253 nm) lines with the spectral type.Comment: Accepted for publication in MNRA

Spitzer Mid-Infrared Photometry of 500 - 750 K Brown Dwarfs

Mid-infrared data, including Spitzer warm-IRAC [3.6] and [4.5] photometry, is critical for understanding the cold population of brown dwarfs now being found, objects which have more in common with planets than stars. As effective temperature (T_eff) drops from 800 K to 400 K, the fraction of flux emitted beyond 3 microns increases rapidly, from about 40% to >75%. This rapid increase makes a color like H-[4.5] a very sensitive temperature indicator, and it can be combined with a gravity- and metallicity-sensitive color like H-K to constrain all three of these fundamental properties, which in turn gives us mass and age for these slowly cooling objects. Determination of mid-infrared color trends also allows better exploitation of the WISE mission by the community. We use new Spitzer Cycle 6 IRAC photometry, together with published data, to present trends of color with type for L0 to T10 dwarfs. We also use the atmospheric and evolutionary models of Saumon & Marley to investigate the masses and ages of 13 very late-type T dwarfs, which have H-[4.5] > 3.2 and T_eff ~ 500 K to 750 K.Comment: To be published in the on-line version of the Proceedings of Cool Stars 16 (ASP Conference Series). This is an updated version of Leggett et al. 2010 ApJ 710 1627; a photometry compilation is available at http://www.gemini.edu/staff/slegget

Influence of fly ash particles on dry sliding wear behavior of AA6061 aluminum alloy

Abstract: In the present study AA6061 aluminium alloy composites containing 0, 4, 8 and 12 Wt. % of fly ash particles have been fabricated by the compocasting process. The dry sliding wear behaviour of unreinforced alloy and composites are studied using Pin-On-Disc machine. The dry sliding wear test was conducted at a load of 4.9, 9.8, 14.7, 19.6, and 24.5 N, sliding velocity of 1.57 m/s, sliding distance of 4000 m and a track radius of 100mm at an ambient temperature respectively for all the tests. Results indicate that the dry sliding wear resistance of Al-fly ash composite increases with an increase in the amount of fly ash content. The load bearing capacity of the AA6061 alloy during dry sliding wear has increased in presence of fly ash particles. Composites exhibit better wear resistance compared to unreinforced alloy up to a load of 24.5 N. Study of the wear surfaces and debris of both alloy and composites using the scanning electron microscope suggests that at high loads (>4.9 N), where fly ash particles act as load bearing constituents, the wear resistance of AA6061 Al alloy reinforced with a size range (2-3 μm) fly ash particles

Epitaxial influence on the ferromagnetic semiconducotor EuO

From first principles calculations we investigate the electronic structure and the magnetic properties of EuO under hydrostatic and epitaxial forces. There is a complex interdependence of the O 2p and Eu 4f and 5d bands on the magnetism in EuO, and decreasing lattice parameters is an ideal method to increase the Curie temperature, T_c. Compared to hydrostatic pressure, the out-of-plane compensation that is available to epitaxial films influences this increase in T_c, although it is minimized by the small value of poisson's ratio for EuO. We find the semiconducting gap closes at a 6% in-plane lattice compression for epitaxy, at which point a significant conceptual change must occur in the active exchange mechanisms

What’s sex got to do with it? A family-based investigation of growing up heterosexual during the twentieth century

This paper explores findings from a cross-generational study of the making of heterosexual relationships in East Yorkshire, which has interviewed women and men within extended families. Using a feminist perspective, it examines the relationship between heterosexuality and adulthood, focussing on sexual attraction, courtship, first kisses, first love and first sex, as mediated within family relationships, and at different historical moments. In this way, the contemporary experiences of young people growing up are compared and contrasted with those of mid-lifers and older adults who formed heterosexual relationships within the context of the changing social and sexual mores of the 1960s/1970s, and the upheavals of World War Two

The effects of H2SO4 and (NH4)2SO4 treatments on the chemistry of soil drainage water and pine seedlings in forest soil microcosms

International audienceAn experiment comparing effects of sulphuric acid and reduced N deposition on soil water quality and on chemical and physical growth indicators for forest ecosystems is described. Six H2SO4 and (NH4)2SO4 treatment loads, from 0 ? 44 and 0 ? 25 kmolc ha-1 yr-1, respectively, were applied to outdoor microcosms of Pinus sylvestris seedlings in 3 acid to intermediate upland soils (calc-silicate, quartzite and granite) for 2 years. Different soil types responded similarly to H2SO4 loads, resulting in decreased leachate pH, but differently to reduced N inputs. In microcosms of calc-silicate soil, nitrification of NH4 resulted in lower pH and higher cation leaching than in acid treatments. By contrast, in quartzite and granite soils, (NH4)2SO4 promoted direct cation leaching, although leachate pH increased. The results highlighted the importance of soil composition on the nature of the cations leached, the SO4 adsorption capacities and microbial N transformations. Greater seedling growth on calc-silicate soils under both treatment types was related to sustained nutrient availability. Reductions in foliar P and Mg with higher N treatments were observed for seedlings in the calc-silicate soil. There were few treatment effects on quartzite and granite microcosm tree seedlings since P limitation precluded seedling growth responses to treatments. Hence, any benefits of N deposition to seedlings on quartzite and granite soils appeared limited by availability of co-nutrients, exacerbated by rapid depletion of soil exchangeable base cations. Keywords: acidification, manipulation, nitrogen, ammonium, deposition, soil, drainage, pine, microcosms, fores