13,709 research outputs found
Searching for X-ray sources in nearby late-type galaxies with low star formation rates
Late type non-starburst galaxies have been shown to contain X-ray emitting
objects, some being ultraluminous X-ray sources. We report on XMM-Newton
observations of 11 nearby, late-type galaxies previously observed with the
Hubble Space Telescope (HST) in order to find such objects. We found 18 X-ray
sources in or near the optical extent of the galaxies, most being point-like.
If associated with the corresponding galaxies, the source luminosities range
from erg s to erg s. We
found one ultraluminous X-ray source, which is in the galaxy IC 5052, and one
source coincident with the galaxy IC 4662 with a blackbody temperature of
keV that could be a quasi-soft source or a quiescent neutron
star X-ray binary in the Milky Way. One X-ray source, XMMU J205206.0691316,
is extended and coincident with a galaxy cluster visible on an HST image. The
X-ray spectrum of the cluster reveals a redshift of and a
temperature of 3.60.4 keV. The redshift was mainly determined by a cluster
of Fe XXIV lines between the observed energy range keV.Comment: 8 pages, to appear in MNRA
Computing equilibrium states of cholesteric liquid crystals in elliptical channels with deflation algorithms
We study the problem of a cholesteric liquid crystal confined to an
elliptical channel. The system is geometrically frustrated because the
cholesteric prefers to adopt a uniform rate of twist deformation, but the
elliptical domain precludes this. The frustration is resolved by deformation of
the layers or introduction of defects, leading to a particularly rich family of
equilibrium configurations. To identify the solution set, we adapt and apply a
new family of algorithms, known as deflation methods, that iteratively modify
the free energy extremisation problem by removing previously known solutions. A
second algorithm, deflated continuation, is used to track solution branches as
a function of the aspect ratio of the ellipse and preferred pitch of the
cholesteric.Comment: 9 pages, 6 figure
Optical variability of the accretion disk around the intermediate mass black hole ESO 243-49 HLX-1 during the 2012 outburst
We present dedicated quasi-simultaneous X-ray (Swift) and optical (Very Large
Telescope (VLT), V- and R-band) observations of the intermediate mass black
hole candidate ESO 243-49 HLX-1 before and during the 2012 outburst. We show
that the V-band magnitudes vary with time, thus proving that a portion of the
observed emission originates in the accretion disk. Using the first quiescent
optical observations of HLX-1, we show that the stellar population surrounding
HLX-1 is fainter than V~25.1 and R~24.2. We show that the optical emission may
increase before the X-ray emission consistent with the scenario proposed by
Lasota et al. (2011) in which the regular outbursts could be related to the
passage at periastron of a star circling the intermediate mass black hole in an
eccentric orbit, which triggers mass transfer into a quasi-permanent accretion
disk around the black hole. Further, if there is indeed a delay in the X-ray
emission we estimate the mass-transfer delivery radius to be ~1e11 cm.Comment: 9 pages, 2 figures, accepted for publication in ApJ
Cucurbit[n]uril binding of platinum anticancer complexes
The encapsulation of cisplatin by cucurbit[7]uril (Q[7]) and multinuclear platinum complexes linked via a 4,4′-dipyrazolylmethane (dpzm) ligand by Q[7] and cucurbit[8]uril (Q[8]) has been studied by NMR spectroscopy and molecular modelling. The NMR studies suggest that some cisplatin binds in the cucurbituril cavity, while cis-[PtCl(NH3)2(H2O)]+ only binds at the portals. Alternatively, the dpzm-linked multinuclear platinum complexes are quantitatively encapsulated within the cavities of both Q[7] and Q[8]. Upon encapsulation, the non-exchangeable proton resonances of the multinuclear platinum complexes show significant upfield shifts in 1H NMR spectra. The H3/H3* resonances shift upfield by 0.08 to 0.55 ppm, the H5/H5* shift by 0.9 to 1.6 ppm, while the methylene resonances shift by 0.74 to 0.88 ppm. The size of the resonance shift is dependent on the cavity size of the encapsulating cucurbituril, with Q[7] encapsulation producing larger shifts than Q[8]. The upfield shifts of the dpzm resonances observed upon cucurbituril encapsulation indicate that the Q[7] or Q[8] is positioned directly over the dpzm linking ligand. The terminal platinum groups of trans-[{PtCl(NH3)2}2μ-dpzm]2+ (di-Pt) and trans-[trans-{PtCl(NH3)2}2-trans-{Pt(dpzm)2(NH3)2}]4+ (tri-Pt) provide a barrier to the on and off movement of cucurbituril, resulting in binding kinetics that are slow on the NMR timescale for the metal complex. Although the dpzm ligand has relatively few rotamers, encapsulation by the larger Q[8] resulted in a more compact di-Pt conformation with each platinum centre retracted further into each Q[8] portal. Encapsulation of the hydrolysed forms of di-Pt and tri-Pt is considerably slower than for the corresponding Cl forms, presumably due to the high-energy cost of passing the +2 platinum centres through the cucurbituril portals. The results of this study suggest that cucurbiturils could be suitable hosts for the pharmacological delivery of multinuclear platinum complexe
The series Bi2Sr2Ca(n-1) Cu(n)O(2n+4) (1 less than or equal to n less than or equal to 5): Phase stability and superconducting properties
Phase relations at 850 and 870 C, melting transitions in air, oxygen, and helium were studied for Bi(2.1)Sr(1.9) CuO6 and for the Bi2Sr2Ca(n-1) Cu(n)O(2n+4) for n = 1, 2, 3, 4, 5, and infinity (CaCuO2). Up to 870 C, the n = 2 composition resides in the compatibility tetrahedron bounded by Bi(2+x)(Sr,Ca)(3-y) Cu2O8, (Sr,Ca)14 Cu24O41, Ca2CuO3, and a Bi-Sr-Ca-O phase. The n is greater than or equal to 3 compositions reside in the compatibility tetrahedron Bi(2+x)(Sr,Ca)(3-y) Cu2O8 - (Sr,Ca)14 Cu24O41 - Ca2CuO3 - CuO up to 850 C. However, Bi(2+x)Sr(4-y) Cu3O10 forms for n is greater than or equal to 3 after extended heating at 870 C. Bi(2+x)Sr(2-y) CuO6 and Bi(2+x)(Sr,Ca)(3-y) Cu2O8 melt in air at 914 C and 895 C respectively. During melting, all of the compositions studied lose 1 to 2 percent by weight of oxygen from the reduction of copper. Bi(2+x)Sr(2-y) CuO6, Bi(2+n)(Sr,Ca)(3-y) Cu2O8, and Bi(2+x)(Sr,Ca)(4-y) Cu3O10 exhibit crystallographic alignment in a magnetic field, with the c-axes orienting parallel to the field
Ultramafic xenoliths from the Bearpaw Mountains, Montana, USA: evidence for multiple metasomatic events in the lithospheric mantle beneath the Wyoming craton
Ultramafic xenoliths in Eocene minettes of the Bearpaw Mountains volcanic field (Montana, USA), derived from the lower lithosphere of the Wyoming craton, can be divided based on textural criteria into tectonite and cumulate groups. The tectonites consist of strongly depleted spinel lherzolites, harzburgites and dunites. Although their mineralogical compositions are generally similar to those of spinel peridotites in off-craton settings, some contain pyroxenes and spinels that have unusually low Al2O3 contents more akin to those found in cratonic spinel peridotites. Furthermore, the tectonite peridotites have whole-rock major element compositions that tend to be significantly more depleted than non-cratonic mantle spinel peridotites (high MgO, low CaO, Al2O3 and TiO2) and resemble those of cratonic mantle. These compositions could have been generated by up to 30% partial melting of an undepleted mantle source. Petrographic evidence suggests that the mantle beneath the Wyoming craton was re-enriched in three ways: (1) by silicate melts that formed mica websterite and clinopyroxenite veins; (2) by growth of phlogopite from K-rich hydrous fluids; (3) by interaction with aqueous fluids to form orthopyroxene porphyroblasts and orthopyroxenite veins. In contrast to their depleted major element compositions, the tectonite peridotites are mostly light rare earth element (LREE)-enriched and show enrichment in fluid-mobile elements such as Cs, Rb, U and Pb on mantle-normalized diagrams. Lack of enrichment in high field strength elements (HFSE; e.g. Nb, Ta, Zr and Hf) suggests that the tectonite peridotites have been metasomatized by a subduction-related fluid. Clinopyroxenes from the tectonite peridotites have distinct U-shaped REE patterns with strong LREE enrichment. They have 143Nd/144Nd values that range from 0·5121 (close to the host minette values) to 0·5107, similar to those of xenoliths from the nearby Highwood Mountains. Foliated mica websterites also have low 143Nd/144Nd values (0·5113) and extremely high 87Sr/86Sr ratios in their constituent phlogopite, indicating an ancient (probably mid-Proterozoic) enrichment. This enriched mantle lithosphere later contributed to the formation of the high-K Eocene host magmas. The cumulate group ranges from clinopyroxene-rich mica peridotites (including abundant mica wehrlites) to mica clinopyroxenites. Most contain >30% phlogopite. Their mineral compositions are similar to those of phenocrysts in the host minettes. Their whole-rock compositions are generally poorer in MgO but richer in incompatible trace elements than those of the tectonite peridotites. Whole-rock trace element patterns are enriched in large ion lithophile elements (LILE; Rb, Cs, U and Pb) and depleted in HFSE (Nb, Ta Zr and Hf) as in the host minettes, and their Sr–Nd isotopic compositions are also identical to those of the minettes. Their clinopyroxenes are LREE-enriched and formed in equilibrium with a LREE-enriched melt closely resembling the minettes. The cumulates therefore represent a much younger magmatic event, related to crystallization at mantle depths of minette magmas in Eocene times, that caused further metasomatic enrichment of the lithosphere
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