918 research outputs found

    Resonant-to-nonresonant transition in electrostatic ion-cyclotron wave phase velocity

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    Because of the implications for plasmas in the laboratory and in space, attention has been drawn to inhomogeneous energy-density driven (IEDD) waves that are sustained by velocity-shear-induced inhomogeneity in cross-field plasma flow. These waves have a frequency vr in the lab frame within an order of magnitude of the ion gyrofrequency vci, propagate nearly perpendicular to the magnetic field (kz/k^ \u3c\u3c 1), and can be Landau resonant (0 \u3c v1/kz \u3c nd) with a parallel drifting electron population (drift speed nd), where subscripts 1 and r indicate frequency in the frame of flowing ions and in the lab frame, respectively, and kz is the parallel component of the wavevector. A transition in phase velocity from 0 \u3c v1/kz \u3c nd to 0 \u3e v1/kz \u3e nd for a pair of IEDD eigenmodes is observed as the degree of in-homogeneity in the transverse E × B flow is increased in a magnetized plasma column. For weaker velocity shear, both eigenmodes are dissipative, i.e. in Landau resonance, with kz nd \u3e 0. For stronger shear, both eigenmodes become reactive, with one\u27s wavevector component kz remaining parallel, but with v1/kz \u3e nd , and the other\u27s wavevector component kz becoming anti-parallel, so that 0 \u3e v1/kz . For both eigenmodes, the transition (1) involves a small frequency shift and (2) does not involve a sign change in the wave energy density, which is proportional to vr v1, both of which are previously unrecognized aspects of inhomogeneous energy-density driven waves

    Resonant-to-nonresonant transition in electrostatic ion-cyclotron wave phase velocity

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    Because of the implications for plasmas in the laboratory and in space, attention has been drawn to inhomogeneous energy-density driven (IEDD) waves that are sustained by velocity-shear-induced inhomogeneity in cross-field plasma flow. These waves have a frequency vr in the lab frame within an order of magnitude of the ion gyrofrequency vci, propagate nearly perpendicular to the magnetic field (kz /k^ v1/kz nd) with a parallel drifting electron population (drift speed nd), where subscripts 1 and r indicate frequency in the frame of flowing ions and in the lab frame, respectively, and kz is the parallel component of the wavevector. A transition in phase velocity from 0 v1/kz nd to 0 > v1/kz > nd for a pair of IEDD eigenmodes is observed as the degree of in-homogeneity in the transverse E × B flow is increased in a magnetized plasma column. For weaker velocity shear, both eigenmodes are dissipative, i.e. in Landau resonance, with kz nd > 0. For stronger shear, both eigenmodes become reactive, with one's wavevector component kz remaining parallel, but with v1/kz > nd , and the other's wavevector component kz becoming anti-parallel, so that 0 > v1/kz . For both eigenmodes, the transition (1) involves a small frequency shift and (2) does not involve a sign change in the wave energy density, which is proportional to vr v1, both of which are previously unrecognized aspects of inhomogeneous energy-density driven waves

    A CSO Search for ll-C3_3H+^+: Detection in the Orion Bar PDR

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    The results of a Caltech Submillimeter Observatory (CSO) search for ll-C3_3H+^+, first detected by Pety et al. (2012) in observations toward the Horsehead photodissociation region (PDR), are presented. A total of 39 sources were observed in the 1 mm window. Evidence of emission from ll-C3_3H+^+ is found in only a single source - the Orion Bar PDR region, which shows a rotational temperature of 178(13) K and a column density of 7(2) x 101110^{11} cm−2^{-2}. In the remaining sources, upper limits of ~1011−1013^{11} - 10^{13} cm−2^{-2} are found. These results are discussed in the context of guiding future observational searches for this species.Comment: 9 pages, 8 figures, 4 table

    Annealing of amorphous FexCo100-x nanoparticles synthesized by a modified aqueous reduction using NaBH4

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    FexCo100−x nanoparticles were synthesized by aqueous reduction in iron (II) sulfate and cobalt (II) sulfate using sodium borohydride and sodium citrate. The initial concentrations of iron and cobalt were varied while maintaining an overall metal concentration of 4.60 mM. Increasing the cobalt content from 0 to 100 at. % decreased the magnetization saturation from 152 to 48 emu/g, as determined by room temperature vibrating sample magnetometry. Annealing the samples at 450 and 600 °C showed an increase in crystallite size. Powder x-ray diffraction and transmission electron microscopy was performed to determine the phases and morphology of the materials

    Microwave background anisotropies in quasiopen inflation

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    Quasiopenness seems to be generic to multi-field models of single-bubble open inflation. Instead of producing infinite open universes, these models actually produce an ensemble of very large but finite inflating islands. In this paper we study the possible constraints from CMB anisotropies on existing models of open inflation. The effect of supercurvature anisotropies combined with the quasiopenness of the inflating regions make some models incompatible with observations, and severely reduces the parameter space of others. Supernatural open inflation and the uncoupled two-field model seem to be ruled out due to these constraints for values of Ω0≲0.98\Omega_0\lesssim0.98. Others, such as the open hybrid inflation model with suitable parameters for the slow roll potential can be made compatible with observations.Comment: 19 pages, ReVTeX, 10 figures inserted with eps

    Conformational Preferences of trans-1,2- and cis-1,3- Cyclohexanedicarboxylic Acids in Water and Dimethyl Sulfoxide as a Function of the Ionization State As Determined from NMR Spectroscopy and Density Functional Theory Quantum Mechanical Calculations

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    The populations of diaxial (aa) and diequatorial (ee) conformers of trans-1,2- and cis-1,3-cyclohexanedicarboxylic acids (CDCAs; 1 and 2, respectively) and their salts were determined in water and dimethyl sulfoxide (DMSO) solutions from vicinal proton–proton NMR J couplings (3J_(HH)). Optimized geometries and free energies for these compounds were obtained at the M06-2X/cc-pVTZ(-f)++ level. Although carboxylic acid groups in cyclohexane rings are generally believed to be far more stable (~2 kcal/mol) in equatorial than axial positions, this investigation demonstrated that an aa conformation (normally assumed to be completely insignificant for these compounds) can be favored depending on the medium and ionization state: strong ee preferences (>90%) were observed in water and DMSO for both diacids and their salts, except for the dianion of 1 in DMSO, which was found to be substantially aa (~57%). The possibility of intramolecular hydrogen bonding (H-bonding) was also investigated; the ratios of the ionization constants (K_1/K_2) indicated an absence of intramolecular H-bonding because K_1/K_2 « 10^4 (a standard criterion for non-H-bonding in dicarboxylic acids) for both 1 and 2 in water and also for 2 in DMSO. For 1, K_1/K_2 increased drastically in DMSO (K_1/K_2 = 4 × 10^6), where ^3J_(HH) and the ratio K_1/K_E = 10, K_E being the acidity constant of the monomethyl ester of 1, indicated the formation of an intramolecular H-bond for the monoanion in this solvent. An explanation for the observation of compact dianions in solution in terms of the generalized Born equation is also provided

    No Time Machine Construction in Open 2+1 Gravity with Timelike Total Energy Momentum

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    It is shown that in 2+1 dimensional gravity an open spacetime with timelike sources and total energy momentum cannot have a stable compactly generated Cauchy horizon. This constitutes a proof of a version of Kabat's conjecture and shows, in particular, that not only a Gott pair cannot be formed from processes such as the decay of a single cosmic string as has been shown by Carroll et al., but that, in a precise sense, a time machine cannot be constructed at all.Comment: 7 pages. Several changes and 3 figures added. To appear in Phys. Rev.

    Crystal coherence length effects on the infrared optical response of MgO thin films

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    The role of crystal coherence length on the infrared optical response of MgO thin films was investigated with regard to Reststrahlen band photon-phonon coupling. Preferentially (001)-oriented sputtered and evaporated ion-beam assisted deposited thin films were prepared on silicon and annealed to vary film microstructure. Film crystalline coherence was characterized by x-ray diffraction line broadening and transmission electron microscopy. The infrared dielectric response revealed a strong dependence of dielectric resonance magnitude on crystalline coherence. Shifts to lower transverse optical phonon frequencies were observed with increased crystalline coherence. Increased optical phonon damping is attributed to increasing granularity and intergrain misorientation

    Cosmic optical activity in the spacetime of a scalar-tensor screwed cosmic string

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    Measurements of radio emission from distant galaxies and quasars verify that the polarization vectors of these radiations are not randomly oriented as naturally expected. This peculiar phenomenon suggests that the spacetime intervening between the source and observer may be exhibiting some sort of optical activity, the origin of which is not known. In the present paper we provide a plausible explanation to this phenomenon by investigating the r\^ole played by a Chern-Simons-like term in the background of an ordinary or superconducting screwed cosmic string in a scalar-tensor gravity. We discuss the possibility that the excess in polarization of the light from radio-galaxies and quasars can be understood as if the electromagnetic waves emitted by these cosmic objects interact with a scalar-tensor screwed cosmic string through a Chern-Simons coupling. We use current astronomical data to constrain possible values for the coupling constant of this theory, and show that it turns out to be: λ∼10−26\lambda \sim 10^{-26} eV, which is two orders of magnitude larger than in string-inspired theories.Comment: Revised version, to appear in Phys. Rev.
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