205 research outputs found
Correlation between Processing Conditions, Lattice Defect Structure and Mechanical Performance of Ultrafine-Grained Materials
The mechanical performance of ultrafine-grained materials is strongly influenced by the lattice defect structure, i.e. the vacancy concentration, the type, arrangement and density of dislocations, the planar fault probability, as well as the amount and character of grain boundaries. In this paper, the correlation between the processing conditions, the lattice defect structure and the plastic behavior of ultrafine-grained materials is overviewed. For the processing route of severe plastic deformation, the influence of applied strain, hydrostatic pressure, as well as melting point, stacking fault energy and alloying on grain size, dislocation density and strength is studied. For nanopowder sintering techniques, the effect of atmosphere, temperature and time of consolidation on lattice defects and mechanical properties is discussed in detail
Nanocrystalline materials studied by powder diffraction line profile analysis
X-ray powder diffraction is a powerful tool for characterising the microstructure of crystalline materials in terms of size and strain. It is widely applied for nanocrystalline materials, especially since other methods, in particular electron microscopy is, on the one hand tedious and time consuming, on the other hand, due to the often metastable states of nanomaterials it might change their microstructures. It is attempted to overview the applications of microstructure characterization by powder diffraction on nanocrystalline metals, alloys, ceramics and carbon base materials. Whenever opportunity is given, the data provided by the X-ray method are compared and discussed together with results of electron microscopy. Since the topic is vast we do not try to cover the entire field
Correlation between subgrains and coherently scattering domains
Crystallite size determined by X-ray line profile analysis is often smaller than the grain or subgrain size obtained by transmission electron microscopy, especially when the material has been produced by plastic deformation. It is shown that besides differences in orientation between grains or subgrains, dipolar dislocation walls without differences in orientation also break down coherency of X-rays scattering. This means that the coherently scattering domain size provided by X-ray line profile analysis provides subgrain or cell size bounded by dislocation boundaries or dipolar walls
Thermal stability of the microstructure of severely deformed copper
Copper specimens were deformed by equal channel angular pressing (ECAP) up to 8 passes. The microstructure was studied by X-ray line profile analysis. The crystallite size is reduced to a few tens of nanometers even after the first ECAP pass and it does not change significantly during further deformation. At the same time, the dislocation density increases gradually up to 4 ECAP passes. The thermal stability of the microstructure is examined by differential scanning calorimetry (DSC). The temperature of the DSC peak decreases whereas the stored energy increases with increasing strain. At the beginning of the heat release a bimodal grain structure develops indicated by a special double-peak shape of the diffraction line profiles
Influence of sintering temperature and pressure on crystallite size and lattice defect structure in nanocrystalline SiC
Microstructure of sintered nanocrystalline SiC is studied by x-ray line profile analysis and transmission electron microscopy. The lattice defect structure and the crystallite size are determined as a function of pressure between 2 and 5.5 GPa for different sintering temperatures in the range from 1400 to 1800 degrees C. At a constant sintering temperature, the increase of pressure promotes crystallite growth. At 1800 degrees C when the pressure reaches 8 GPa, the increase of the crystallite size is impeded. The grain growth during sintering is accompanied by a decrease in the population of planar faults and an increase in the density of dislocations. A critical crystallite size above which dislocations are more abundant than planar defects is suggested
A new method for hardness determination from depth sensing indentation tests
A new semiempirical formula is developed for the hardness determination of the materials from depth sensing indentation tests. The indentation works measured both during loading and unloading periods are used in the evaluation. The values of the Meyer hardness calculated in this way agree well with those obtained by conventional optical observation, where this latter is possible. While the new hardness formula characterizes well the behavior of the conventional hardness number even for the ideally elastic material, the mean contact pressure generally used in hardness determination differs significantly from the conventional hardness number when the ideally elastic limiting case is being approached
Phase transition in nanomagnetite
Recently, the application of nanosized magnetite particles became an area of growing interest for
their potential practical applications. Nanosized magnetite samples of 36 and 9 nm sizes were
synthesized. Special care was taken on the right stoichiometry of the magnetite particles. Mössbauer
spectroscopy measurements were made in 4.2–300 K temperature range. The temperature
dependence of the intensities of the spectral components indicated size dependent transition taking
place in a broad temperature range. For nanosized samples, the hyperfine interaction values and their
relative intensities changed above the Verwey transition temperature value of bulk megnetite. The
continuous transition indicated the formation of dendritelike granular assemblies formed during the
preparation of the samples
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