Recently, the application of nanosized magnetite particles became an area of growing interest for
their potential practical applications. Nanosized magnetite samples of 36 and 9 nm sizes were
synthesized. Special care was taken on the right stoichiometry of the magnetite particles. Mössbauer
spectroscopy measurements were made in 4.2–300 K temperature range. The temperature
dependence of the intensities of the spectral components indicated size dependent transition taking
place in a broad temperature range. For nanosized samples, the hyperfine interaction values and their
relative intensities changed above the Verwey transition temperature value of bulk megnetite. The
continuous transition indicated the formation of dendritelike granular assemblies formed during the
preparation of the samples