Hydrogen in α\alpha-iron: stress and diffusion

First-principles density-functional theory has been used to investigate equilibrium geometries, total energies, and diffusion barriers for H as an interstitial impurity absorbed in $\alpha$-Fe. Internal strains/stresses upon hydrogen absorption are a crucial factor to understand preferred absorption sites and diffusion. For high concentrations, H absorbs near the octahedral site favoring a large tetragonal distortion of the BCC lattice. For low concentration, H absorbs near the tetrahedral site minimizing the elastic energy stored on nearby cells. Diffusion paths depend on the concentration regime too; hydrogen diffuses about ten times faster in the distorted BCT lattice. External stresses of several GPa modify barriers by $\approx$ 10%, and diffusion rates by $\approx$ 30%

Ab-initio molecular dynamics simulation of hydrogen diffusion in α\alpha-iron

First-principles atomistic molecular dynamics simulation in the micro-canonical and canonical ensembles has been used to study the diffusion of interstitial hydrogen in $\alpha$-iron. Hydrogen to Iron ratios between $\theta=1/16 and 1/2 have been considered by locating interstitial hydrogen atoms at random positions in a$2 \times 2 \times 2$ supercell. We find that the average optimum absorption site and the barrier for diffusion depend on the concentration of interestitials. Iron Debye temperature decreases monotonically for increasing concentration of interstitial hydrogen, proving that iron-iron interatomic potential is significantly weakened in the presence of a large number of diffusing hydrogen atoms

Hydrothermal monitoring using embedded sensors of the actual roof system of the prado museum

El Prado Museum in Madrid has been recently submitted to a refurbishment of its roof which from been made with the traditional tiles has been changed to the use of modern waterproofing layers covered with a metallic lead finishing. Due to an unexpected damp patch that produced leaking in the hall in which Las Meninas by Velázquez was exhibited, the authors were commissioned by the Ministry of Education and Culture to study the suitability of the roof and its waterproofing properties. The study led to suggestions of modifications in the design of the roof layers, which are out of the scope of present paper. In present paper are given the behaviour of the sensors embedded in two specific areas of the roof. The sensors installed were of: temperature, relative humidity, measurement of local strain and detection of liquid water. The liquid water sensors reveal that some water is withheld in the layer just below the thermal insulation material, although it is standing. The results of over four years of readings show that the temperature attenuates over distance away from the outermost layer, where the readings are very high in summer, due to it consists of lead. During the colder seasons, in turn, the temperature in the inner layers of the roof is higher than in the outer layers. The strain recorded follows the logical evolution of temperature with no abnormal behaviour being detected. Some of relative humidity sensors had measuring problems due to water condensing on them. In summary however, if the behaviour in this area is extrapolated to the rest of the roof, it can be considered to perform correctly as intended. No more leaking events have been detected from the design modifications were incorporated to the existing roof

Integrated geophysical-petrological modeling of lithosphere-asthenosphere boundary in central Tibet using electromagnetic and seismic data

We undertake a petrologically driven approach to jointly model magnetotelluric (MT) and seismic surface wave dispersion (SW) data from central Tibet, constrained by topographic height. The approach derives realistic temperature and pressure distributions within the upper mantle and characterizes mineral assemblages of given bulk chemical compositions as well as water content. This allows us to define a bulk geophysical model of the upper mantle based on laboratory and xenolith data for the most relevant mantle mineral assemblages and to derive corresponding predicted geophysical observables. One-dimensional deep resistivity models were derived for two groups of MT stations. One group, located in the Lhasa Terrane, shows the existence of an electrically conductive upper mantle layer and shallower conductive upper mantle layer for the other group, located in the Qiangtang Terrane. The subsequent one-dimensional integrated petrological-geophysical modeling suggests a lithosphere-asthenosphere boundary (LAB) at a depth of 80¿120 km with a dry lithosphere for the Qiangtang Terrane. In contrast, for the Lhasa Terrane the LAB is located at about 180 km but the presence of a small amount of water in the lithospheric mantle (<0.02 wt%) is required to fit the longest period MT responses. Our results suggest two different lithospheric configurations beneath the southern and central Tibetan Plateau. The model for the Lhasa Terrane implies underthrusting of a moderately wet Indian plate. The model for the Qiangtang Terrane shows relatively thick and conductive crust and implies thin and dry Tibetan lithosphere.Peer Reviewe

Molecular Dynamics simulations of Hydrogen Embrittlement: preliminary results

Hydrogen embrittlement is believed to be one of the main reasons for cracking of structures under stress. High strength steels in these structures often include a ferritic core made of alpha-iron (body centered cubic lattice). Previous work [1] was concerned with the interaction of atomic hydrogen with iron using first principles calculations. We studied the effect of interstitial hydrogen in the iron lattice and the stress induced by the interstitial hydrogen in the host lattice. In this paper we study the dynamical behaviour of hydrogen inside the iron lattice. Using ab-initio Molecular Dynamics we obtain hydrogen diffusion paths and by taking statistical averages we extract diffusion coefficients from Einstein&rsquo;s equation. Depending on temperature, the diffusion path involve going through tetrahedral or octahedral sites. Simulations where a number of hydrogens occasionally coincide in one unit cell have been performed to elucidate the effect of interactions between hydrogen

Nuevas técnicas avanzadas para la medida in situ de la corrosión en hormigón armado

Measurement techniques of reinforcement corrosion are scarcely researched if compared with the increasing number of publications in the subject. However, numerous possibilities and challenges remain without being explored. In present paper mention is made to some of the present possibilities of electrochemical techniques, either on-site or in the laboratory. Concerning on-site techniques it is commented the possibilities and limitations of present methods of measuring Polarization Resistance, Rp. Particular attention is given to the need to use a modulated guardring with sensors controlling this modulation to obtain accurate values of the corrosion rate. After, description of the basis of new techniques related to the measurements of the passivation state in cathodically protected structures, is made. The basis of a new method of measuring corrosion without the need to touch the metal is also presented. Regarding the use of embedded sensors, the experience until now shows the difficulty of interpretation of the data collected, due to the important influence of ambient temperature. Finally, some comments are presented on the need of joint work of material and structural specialists.Las técnicas de medida de la corrosión en hormigón armado se investigan muy poco en comparación con el creciente número de publicaciones sobre este tema. Sin embargo, existen muchas posibilidades y retos que todavía no han sido exploradas. En el presente artículo se descubren algunas de las presentes posibilidades de las técnicas electroquímicas, tanto in-situ como en laboratorio. En cuanto a las técnicas in situ se refiere, se comentan las posibilidades y limitaciones de los métodos actuales de medida de la Resistencia de Polarización, Rp. Se presta particular atención ante la necesidad de utilizar un anillo de guarda modulado con sensores que controlen esta modulación para obtener valores adecuados de velocidad de corrosión. Después se describen las bases de la nueva técnica relacionada con la medida del estado pasivo en estructuras protegidas catódicamente. También se presentan las bases de un nuevo método de medida de la corrosión sin necesidad de tocar el metal. En cuanto al uso de sensores embebidos, la experiencia, hasta el momento, muestra la difícil interpretación de los datos obtenidos, debido a la importante influencia del efecto de la temperatura. Finalmente, se presentan algunos comentarios sobre la necesidad de trabajar conjuntamente los especialistas en materiales y en estructuras

4D Antarctica: a new effort aims to help bridge the gap between Antarctic crust and lithosphere structure and geothermal heat flux

Seismology, satellite-magnetic and aeromagnetic data, and sparse MT provide the only available geophysical proxies for large parts of Antarctica\u2019s Geothermal Heat Flux (GHF) due to the sparseness of direct measurements. However, these geophysical methods have yielded significantly different GHF estimates. This restricts our knowledge of Antarctica\u2019s contrasting tectono-thermal provinces and their influence on subglacial hydrology and ice sheet dynamics. For example, some models derived from aeromagnetic data predict remarkably high GHF in the interior of the West Antarctic Rift System (WARS), while other satellite magnetic and seismological models favour instead a significantly colder rift interior but higher GHF stretching from the Marie Byrd Land dome towards the Antarctic Peninsula, and beneath parts of the Transantarctic Mountains. Reconciling these differences in West Antarctica is imperative to better comprehend the degree to which the WARS influences the West Antarctic Ice Sheet, including thermal influences on GIA. Equally important, is quantifying geothermal heat flux variability in the generally colder but composite East Antarctic craton, especially beneath its giant marine-based basins. Here we present a new ESA project- 4D Antarctica that aims to better connect international Antarctic crust and lithosphere studies with GHF, and assess its influence on subglacial hydrology by analysing and modelling recent satellite and airborne geophysical datasets. The state of the art, hypotheses to test, and methodological approaches for five key study areas, including the Amundsen Sea Embayment, the Wilkes Subglacial Basin and the Totten catchment, the Recovery and Pensacola-Pole Basins and the Gamburtsev Sublgacial Mountains/East Antarctic Rift System are highlighted

Evidence for surface uplift of the Atlas Mountains and the surrounding peripheral plateaux: Combining apatite fission-track results and geomorphic indicators in the Western Moroccan Meseta (coastal Variscan Paleozoic basement)

This work represents an initial attempt to link the evolution of the topography in relation to the general tectonic framework of western Morocco. For this purpose, in a section of the Western Moroccan Meseta different tools are combined in order to attain the general objective. Apatite fission-track (AFT) data of granitic rocks of the Rabat–Khenifra area give ages around 200 Ma with track length distributions which are compatible with the thermal models already established for the area. An inverse correlation between AFT ages and elevation is observed which is compatible with previous models indicating northward tilting of the whole Western Moroccan Meseta which is younger than 20–25 Ma. In order to test this possibility a detailed analysis of the topography at different scales in the Western Moroccan Meseta has been performed. Results indicate that two open folds with different amplitudes are recognized and that the one with wider wavelength could correspond to a lithospheric fold as previously stated by other authors on the basis of independent geological arguments. The northward tilting proposed based on the AFT data agrees with the results obtained in the analysis of the topography which reinforces the presence of a very open fold with a wavelength of 200–300 km in the north-western limb of the Western Moroccan Meseta

Failure analysis of prestressed anchor bars

Three broken steel bars from a sewed crack in a dam are reported. The inspection of the fracture surfaces of the prestressed bars suggests that fractures were triggered by small cracks and by the inherent brittleness of the bars, as fracture toughness was about 40 MPa m1/2. The analysis of the failures shows that the usual design requirements for prestressing bars fail to warn against brittle failures if some damage exists. Some recommendations, based on the concept of damage tolerance, are suggested to avoid similar unfortunate incidents