47,432 research outputs found
Low-density series expansions for directed percolation III. Some two-dimensional lattices
We use very efficient algorithms to calculate low-density series for bond and
site percolation on the directed triangular, honeycomb, kagom\'e, and
lattices. Analysis of the series yields accurate estimates of the critical
point and various critical exponents. The exponent estimates differ only
in the digit, thus providing strong numerical evidence for the
expected universality of the critical exponents for directed percolation
problems. In addition we also study the non-physical singularities of the
series.Comment: 20 pages, 8 figure
Static feed water electrolysis module
An advanced static feed water electrolysis module (SFWEM) and associated instrumentation for generating breathable O2 was developed. The system also generates a H2 byproduct for use in an air revitalization system for O2 recovery from metabolic CO2. Special attention was given to: (1) eliminating water feed compartment degassing, (2) eliminating need for zero gravity condenser/separators, (3) increasing current density capability, and (4) providing a self contained module so that operation is independent of laboratory instrumentation and complicated startup/shutdown procedures
Conformal field theory correlations in the Abelian sandpile mode
We calculate all multipoint correlation functions of all local bond
modifications in the two-dimensional Abelian sandpile model, both at the
critical point, and in the model with dissipation. The set of local bond
modifications includes, as the most physically interesting case, all weakly
allowed cluster variables. The correlation functions show that all local bond
modifications have scaling dimension two, and can be written as linear
combinations of operators in the central charge -2 logarithmic conformal field
theory, in agreement with a form conjectured earlier by Mahieu and Ruelle in
Phys. Rev. E 64, 066130 (2001). We find closed form expressions for the
coefficients of the operators, and describe methods that allow their rapid
calculation. We determine the fields associated with adding or removing bonds,
both in the bulk, and along open and closed boundaries; some bond defects have
scaling dimension two, while others have scaling dimension four. We also
determine the corrections to bulk probabilities for local bond modifications
near open and closed boundaries.Comment: 13 pages, 5 figures; referee comments incorporated; Accepted by Phys.
Rev.
Advanced combined iodine dispenser and detector
A total weight of 1.23 kg (2.7 lb), a total volume of 1213 cu m (74 cu in), and an average power consumption of 5.5W was achieved in the advanced combined iodine dispenser/detector by integrating the detector with the iodine source, arranging all iodinator components within a compact package and lowering the parasitic power to the detector and electronics circuits. These achievements surpassed the design goals of 1.36 kg (3.0 lb), 1671 cu m (102 cu in) and 8W. The reliability and maintainability were improved by reducing the detector lamp power, using an interchangeable lamp concept, making the electronic circuit boards easily accessible, providing redundant water seals and improving the accessibility to the iodine accumulator for refilling. The system was designed to iodinate (to 5 ppm iodine) the fuel cell water generated during 27 seven-day orbiter missions (equivalent to 18,500 kg (40,700 lb) of water) before the unit must be recharged with iodine crystals
Direct Observation of Early-stage Quantum Dot Growth Mechanisms with High-temperature Ab Initio Molecular Dynamics
Colloidal quantum dots (QDs) exhibit highly desirable size- and
shape-dependent properties for applications from electronic devices to imaging.
Indium phosphide QDs have emerged as a primary candidate to replace the more
toxic CdSe QDs, but production of InP QDs with the desired properties lags
behind other QD materials due to a poor understanding of how to tune the growth
process. Using high-temperature ab initio molecular dynamics (AIMD)
simulations, we report the first direct observation of the early stage
intermediates and subsequent formation of an InP cluster from separated indium
and phosphorus precursors. In our simulations, indium agglomeration precedes
formation of In-P bonds. We observe a predominantly intercomplex pathway in
which In-P bonds form between one set of precursor copies while the carboxylate
ligand of a second indium precursor in the agglomerated indium abstracts a
ligand from the phosphorus precursor. This process produces an indium-rich
cluster with structural properties comparable to those in bulk zinc-blende InP
crystals. Minimum energy pathway characterization of the AIMD-sampled reaction
events confirms these observations and identifies that In-carboxylate
dissociation energetics solely determine the barrier along the In-P bond
formation pathway, which is lower for intercomplex (13 kcal/mol) than
intracomplex (21 kcal/mol) mechanisms. The phosphorus precursor chemistry, on
the other hand, controls the thermodynamics of the reaction. Our observations
of the differing roles of precursors in controlling QD formation strongly
suggests that the challenges thus far encountered in InP QD synthesis
optimization may be attributed to an overlooked need for a cooperative tuning
strategy that simultaneously addresses the chemistry of both indium and
phosphorus precursors.Comment: 40 pages, 9 figures, submitted for publicatio
Carbon incorporation in ZnSe grown by metalorganic chemical vapor deposition
Carbon incorporation in ZnSe films grown by metalorganic chemical vapor deposition is reported. Secondary‐ion mass spectrometry measurements in ZnSe films grown from methylallylselenide and dimethylzinc show an enhanced carbon accumulation at the interface between ZnSe and GaAs. The carbon incorporation in the bulk ZnSe increases with the VI/II ratio and for a value of VI/II=3–4, the amount of incorporated carbon abruptly jumps to concentrations of 10^(21) cm^(−3), whereupon the films become polycrystalline. A new shallow peak I^C at 2.7920 eV dominates the near‐band‐edge low‐temperature photoluminescence spectra of all carbon‐contaminated ZnSe films. The intensity and linewidth of I^C increase with the VI/II ratio in a similar manner to the carbon concentration. This peak is proposed to be due to the radiative decay of excitons bound to a complex defect, which is associated with the presence of carbon in the films
Compressed self-avoiding walks, bridges and polygons
We study various self-avoiding walks (SAWs) which are constrained to lie in
the upper half-plane and are subjected to a compressive force. This force is
applied to the vertex or vertices of the walk located at the maximum distance
above the boundary of the half-space. In the case of bridges, this is the
unique end-point. In the case of SAWs or self-avoiding polygons, this
corresponds to all vertices of maximal height. We first use the conjectured
relation with the Schramm-Loewner evolution to predict the form of the
partition function including the values of the exponents, and then we use
series analysis to test these predictions.Comment: 29 pages, 6 figure
Statistical properties of an ensemble of vortices interacting with a turbulent field
We develop an analytical formalism to determine the statistical properties of
a system consisting of an ensemble of vortices with random position in plane
interacting with a turbulent field. We calculate the generating functional by
path-integral methods. The function space is the statistical ensemble composed
of two parts, the first one representing the vortices influenced by the
turbulence and the second one the turbulent field scattered by the randomly
placed vortices.Comment: Third version; Important corrections in the normalization for the gas
of vortices, et
Transport and reduction of nitrate in clayey till underneath forest and arable land.
Transport and reduction of nitrate in a typically macroporous clayey till were examined at variable flow rate and nitrate flux. The experiments were carried out using saturated, large diameter (0.5 m), undisturbed soil columns (LUC), from a forest and nearby agricultural sites. Transport of nitrate was controlled by flow along the macropores (fractures and biopores) in the columns. Nitrate reduction (denitrification) determined under active flow mainly followed first order reactions with half-lives (t1/2) increasing with depth (1.5–3.5 m) from 7 to 35 days at the forest site and 1–7 h at the agricultural site. Nitrate reduction was likely due to microbial degradation of accumulated organic matter coupled with successive consumption of O2 and NO3− in the macropore water followed by reductive dissolution of Fe and Mn from minerals along the macropores. Concentrations of total organic carbon measured in soil samples were near identical at the two study sites and consequently not useful as indicator for the observed differences in nitrate reduction. Instead the high reduction rates at the agricultural site were positively correlated with elevated concentration of water-soluble organic carbon and nitrate-removing bacteria relative to the forest site. After high concentrations of water-soluble organic carbon in the columns from the agricultural site were leached they lost their elevated reduction rates, which, however, was successfully re-established by infiltration of new reactive organics represented by pesticides. Simulations using a calibrated discrete fracture matrix diffusion (DFMD) model could reasonably reproduce the denitrification and resulting flux of nitrate observed during variable flow rate from the columns
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