Image-potential band-gap narrowing at a metal/semiconductor interface

GW approximation is used to systematically revisit the image-potential band-gap narrowing at metal/semiconductor interfaces proposed by Inkson in the 1970's. Here we have questioned how the narrowing as calculated from quasi-particle energy spectra for the jellium/Si interface depends on $r_s$ of the jellium. The gap narrowing is found to only weakly depend on $r_s$ (i.e., narrowing $\simeq 0.3$ eV even for a large $r_s = 6)$. Hence we can turn to smaller polarizability in the semiconductor side as an important factor in looking for larger narrowing.Comment: 6 pages, 7 figure

Design of electron correlation effects in interfaces and nanostructures

We propose that one of the best grounds for the materials design from the viewpoint of {\it electron correlation} such as ferromagnetism, superconductivity is the atomically controlled nanostructures and heterointerfaces, as theoretically demonstrated here from three examples with first-principles calculations: (i) Band ferromagnetism in a purely organic polymer of five-membered rings, where the flat-band ferromagnetism due to the electron-electron repulsion is proposed. (ii) Metal-induced gap states (MIGS) of about one atomic monolayer thick at insulator/metal heterointerfaces, recently detected experimentally, for which an exciton-mechanism superconductivity is considered. (iii) Alkali-metal doped zeolite, a class of nanostructured host-guest systems, where ferromagnetism has been experimentally discovered, for which a picture of the "supercrystal" composed of "superatoms" is proposed and Mott-insulator properties are considered. These indicate that design of electron correlation is indeed a promising avenue for nanostructures and heterointerfaces.Comment: to be published in Proc. 7th Int. Conf. on Atomically Controlled Surfaces, Interfaces and Nanostructures, Nara, Nov. 2003, 14 pages, 10 figure

A comparison of He and Ne FIB imaging of cracks in microindented silicon nitride

Helium ion microscopy (HIM) offers potential as a high spatial resolution technique for imaging insulating samples that are susceptible to charging artifacts. In this study helium and neon ion microscopy are used to image cracking in microindented samples of the non-conductive ceramic silicon nitride. The crack morphology of radial cracks emanating from the microindentations has been characterized for two different compositions of silicon nitride, with and without conductive coatings. Gold coating enhances crack edge contrast, but masks grain contrast for both He and Ne ion-induced secondary electron (ISE) imaging. Carbon coating enables the crystalline and glassy phases to be distinguished, more clearly with Ne-ISE, and the cracking pathway is found to be primarily intergranular. Zones of < 100 nm diameter depleted ion-induced secondary electron emission along the crack paths are identified, consistent with charging ‘hotspots’

Occupational Attainment and Earnings among Immigrant Groups: Evidence from New Zealand

This paper concerns the prediction of career success among migrants. We focus specifically on the role of occupation as a mediating variable between the predictor variables education and time since migration, and the dependent variable career success as denoted by occupational status, linked to earnings. This is the first application of this analysis to New Zealand data. New Zealand provides an interesting case, as a country where migrants from diverse ethnic groups comprise a significant part of the population. Following a review of the literature specifically focused on occupation, we apply Ordered Probit analysis to a sample of over 37,900 employed males. We focus on the occupational attainment of immigrants and the native-born populations and provide evidence on the mediating effect of occupational attainment on earnings. Our analyses show the interplay of factors leading to occupational attainment: for example, education level is of greatest importance, and much of its effect on earnings is through occupational attainment; different immigrant groups have differentiable outcomes, and years of experience in the host country enable gradual occupational advancement. Our results highlight the significant mediating role of occupational attainment in explaining earnings across immigrant and native-born groups

Ceria-Water-Reactions Studied by Liquid Cell TEM

Liquid cell TEM is demonstrated to be a highly suitable new technology to study chemical reactions of cerium oxide nanostructures in aqueous environment. Ceria nanoparticles are found to show a diversity of behaviour. At low beam intensity, particle hopping movements and particle attachment, including chain formation is observable. At high intensity, when the water is turned ultra-enriched in ions by radiolysis, we find (in order of observation) particle rounding and shrinkage, followed by complete dissolution, along with formation of new reaction phases, and finally gas bubble formation

Electronic damping of molecular motion at metal surfaces

A method for the calculation of the damping rate due to electron-hole pair excitation for atomic and molecular motion at metal surfaces is presented. The theoretical basis is provided by Time Dependent Density Functional Theory (TDDFT) in the quasi-static limit and calculations are performed within a standard plane-wave, pseudopotential framework. The artificial periodicity introduced by using a super-cell geometry is removed to derive results for the motion of an isolated atom or molecule, rather than for the coherent motion of an ordered over-layer. The algorithm is implemented in parallel, distributed across both ${\bf k}$ and ${\bf g}$ space, and in a form compatible with the CASTEP code. Test results for the damping of the motion of hydrogen atoms above the Cu(111) surface are presented.Comment: 10 pages, 3 figure

Variational solution of the T-matrix integral equation

We present a variational solution of the T-matrix integral equation within a local approximation. This solution provides a simple form for the T matrix similar to Hubbard models but with the local interaction depending on momentum and frequency. By examining the ladder diagrams for irreducible polarizability, a connection between this interaction and the local-field factor is established. Based on the obtained solution, a form for the T-matrix contribution to the electron self-energy in addition to the GW term is proposed. In the case of the electron-hole multiple scattering, this form allows one to avoid double counting.Comment: 7 pages, 7 figure

Kiwi talent flow : a study of chartered accountants and business professionals overseas

New Zealanders have always had a propensity to travel overseas. The globalisation of the world has seen an increase in the number of people who, having completed their education and gained some work experience, set off on their overseas experience. Concern has been expressed as to the potential “brain drain” that would result should these well-educated and talented citizens remain overseas permanently. This research considers the propensity to return of over 1,500 expatriate Kiwis working in the areas of accounting and finance. It examines their demographics, attitudes, values, motivations, factors of attraction to, and repulsion from, New Zealand and their concerns for change in New Zealand. It therefore provides insights into the nature and purpose of this significant group of professionals resident mainly in the United Kingdom and Australia. We find that less than half are likely to return to New Zealand. This is because of the lack of career and business opportunities despite the “pull” of family and relations in New Zealand