Comparison of electron injection and recombination on TiO2 nanoparticles and ZnO nanorods photosensitized by phthalocyanine

Titanium dioxide (TiO2) and zinc oxide (ZnO) semiconductors have similar band gap positions but TiO2performs better as an anode material in dye-sensitized solar cell applications. We compared two electrodes made of TiO2nanoparticles and ZnO nanorods sensitized by an aggregation-protected phthalocyanine derivative using ultrafast transient absorption spectroscopy. In agreement with previous studies, the primary electron injection is two times faster on TiO2, but contrary to the previous results the charge recombination is slower on ZnO. The latter could be due to morphology differences and the ability of the injected electrons to travel much further from the sensitizer cation in ZnO nanorodsSpanish MINECO (CTQ2017-85393-P) and the Comunidad de Madrid (FOTOCARBON, S2013/MIT-2841) are highly acknowledged. K.V. acknowledges the Doctoral Programme of Tampere University of Technology for the financial support

Properties of the series solution for Painlevé I

We present some observations on the asymptotic behaviour of the coefficients in the Laurent series expansion of solutions of the first Painlevé equation. For the general solution, explicit recursive formulae for the Taylor expansion of the tau-function around a zero are given, which are natural extensions of analogous formulae for the elliptic sigma function, as given by Weierstrass. Numerical and exact results on the symmetric solution which is singular at the origin are also presented

On the Linearization of the Painleve' III-VI Equations and Reductions of the Three-Wave Resonant System

We extend similarity reductions of the coupled (2+1)-dimensional three-wave resonant interaction system to its Lax pair. Thus we obtain new 3x3 matrix Fuchs--Garnier pairs for the third and fifth Painleve' equations, together with the previously known Fuchs--Garnier pair for the fourth and sixth Painleve' equations. These Fuchs--Garnier pairs have an important feature: they are linear with respect to the spectral parameter. Therefore we can apply the Laplace transform to study these pairs. In this way we found reductions of all pairs to the standard 2x2 matrix Fuchs--Garnier pairs obtained by M. Jimbo and T. Miwa. As an application of the 3x3 matrix pairs, we found an integral auto-transformation for the standard Fuchs--Garnier pair for the fifth Painleve' equation. It generates an Okamoto-like B\"acklund transformation for the fifth Painleve' equation. Another application is an integral transformation relating two different 2x2 matrix Fuchs--Garnier pairs for the third Painleve' equation.Comment: Typos are corrected, journal and DOI references are adde

On a q-difference Painlev\'e III equation: I. Derivation, symmetry and Riccati type solutions

A q-difference analogue of the Painlev\'e III equation is considered. Its derivations, affine Weyl group symmetry, and two kinds of special function type solutions are discussed.Comment: arxiv version is already officia

Rational solutions of the discrete time Toda lattice and the alternate discrete Painleve II equation

The Yablonskii-Vorob'ev polynomials $y_{n}(t)$, which are defined by a second order bilinear differential-difference equation, provide rational solutions of the Toda lattice. They are also polynomial tau-functions for the rational solutions of the second Painlev\'{e} equation ($P_{II}$). Here we define two-variable polynomials $Y_{n}(t,h)$ on a lattice with spacing $h$, by considering rational solutions of the discrete time Toda lattice as introduced by Suris. These polynomials are shown to have many properties that are analogous to those of the Yablonskii-Vorob'ev polynomials, to which they reduce when $h=0$. They also provide rational solutions for a particular discretisation of $P_{II}$, namely the so called {\it alternate discrete} $P_{II}$, and this connection leads to an expression in terms of the Umemura polynomials for the third Painlev\'{e} equation ($P_{III}$). It is shown that B\"{a}cklund transformation for the alternate discrete Painlev\'{e} equation is a symplectic map, and the shift in time is also symplectic. Finally we present a Lax pair for the alternate discrete $P_{II}$, which recovers Jimbo and Miwa's Lax pair for $P_{II}$ in the continuum limit $h\to 0$.Comment: 23 pages, IOP style. Title changed, and connection with Umemura polynomials adde

Finite-dimensional reductions of the discrete Toda chain

The problem of construction of integrable boundary conditions for the discrete Toda chain is considered. The restricted chains for properly chosen closure conditions are reduced to the well known discrete Painlev\'e equations $dP_{III}$, $dP_{V}$, $dP_{VI}$. Lax representations for these discrete Painlev\'e equations are found.Comment: Submitted to Jornal of Physics A: Math. Gen., 14 page

Factorization and Lie point symmetries of general Lienard-type equation in the complex plane

We present a variational approach to a general Lienard-type equation in order to linearize it and, as an example, the Van der Pol oscillator is discussed. The new equation which is almost linear is factorized. The point symmetries of the deformed equation are also discussed and the two-dimensional Lie algebraic generators are obtained

A nonlocal connection between certain linear and nonlinear ordinary differential equations/oscillators

We explore a nonlocal connection between certain linear and nonlinear ordinary differential equations (ODEs), representing physically important oscillator systems, and identify a class of integrable nonlinear ODEs of any order. We also devise a method to derive explicit general solutions of the nonlinear ODEs. Interestingly, many well known integrable models can be accommodated into our scheme and our procedure thereby provides further understanding of these models.Comment: 12 pages. J. Phys. A: Math. Gen. 39 (2006) in pres

Movable algebraic singularities of second-order ordinary differential equations

Any nonlinear equation of the form y''=\sum_{n=0}^N a_n(z)y^n has a (generally branched) solution with leading order behaviour proportional to (z-z_0)^{-2/(N-1)} about a point z_0, where the coefficients a_n are analytic at z_0 and a_N(z_0)\ne 0. We consider the subclass of equations for which each possible leading order term of this form corresponds to a one-parameter family of solutions represented near z_0 by a Laurent series in fractional powers of z-z_0. For this class of equations we show that the only movable singularities that can be reached by analytic continuation along finite-length curves are of the algebraic type just described. This work generalizes previous results of S. Shimomura. The only other possible kind of movable singularity that might occur is an accumulation point of algebraic singularities that can be reached by analytic continuation along infinitely long paths ending at a finite point in the complex plane. This behaviour cannot occur for constant coefficient equations in the class considered. However, an example of R. A. Smith shows that such singularities do occur in solutions of a simple autonomous second-order differential equation outside the class we consider here

The stochastic pump current and the non-adiabatic geometrical phase

We calculate a pump current in a classical two-state stochastic chemical kinetics by means of the non-adiabatic geometrical phase interpretation. The two-state system is attached to two particle reservoirs, and under a periodic perturbation of the kinetic rates, it gives rise to a pump current between the two-state system and the absorbing states. In order to calculate the pump current, the Floquet theory for the non-adiabatic geometrical phase is extended from a Hermitian case to a non-Hermitian case. The dependence of the pump current on the frequency of the perturbative kinetic rates is explicitly derived, and a stochastic resonance-like behavior is obtained.Comment: 11 page