CRADA Final Report for NFE-08-01826: Development and application of processing and processcontrol for nano-composite materials for lithium ion batteries

Oak Ridge National Laboratory and A123 Systems, Inc. collaborated on this project to develop a better understanding, quality control procedures, and safety testing for A123 System’s nanocomposite separator (NCS) technology which is a cell based patented technology and separator. NCS demonstrated excellent performance. x3450 prismatic cells were shown to survive >8000 cycles (1C/2C rate) at room temperature with greater than 80% capacity retention with only NCS present as an alternative to conventional polyolefin. However, for a successful commercialization, the coating conditions required to provide consistent and reliable product had not been optimized and QC techniques for being able to remove defective material before incorporation into a cell had not been developed. The work outlined in this report addresses these latter two points. First, experiments were conducted to understand temperature profiles during the different drying stages of the NCS coating when applied to both anode and cathode. One of the more interesting discoveries of this study was the observation of the large temperature decrease experienced by the wet coating between the end of the infrared (IR) drying stage and the beginning of the exposure to the convection drying oven. This is not a desirable situation as the temperature gradient could have a deleterious effect on coating quality. Based on this and other experimental data a radiative transfer model was developed for IR heating that also included a mass transfer module for drying. This will prove invaluable for battery coating optimization especially where IR drying is being employed. A stress model was also developed that predicts that under certain drying conditions tensile stresses are formed in the coating which could lead to cracking that is sometimes observed after drying is complete. Prediction of under what conditions these stresses form is vital to improving coating quality. In addition to understanding the drying process other parameters such as slurry quality and equipment optimization were examined. Removal of particles and gels by filtering, control of viscosity by %solids and mixing adjustments, removal of trapped gas in the slurry and modification of coater speed and slot die gap were all found to be important for producing uniform and flaw-free coatings. Second, an in-line Hi-Pot testing method has been developed specifically for NCS that will enable detection of coating flaws that could lead to soft or hard electrical shorts within the cell. In this way flawed material can be rejected before incorporation into the cell thus greatly reducing the amount of scrap that is generated. Improved battery safety is an extremely important benefit of NCS. Evaluation of battery safety is usually accomplished by conducting a variety of tests including nail penetration, hot box, over charge, etc. For these tests entire batteries must be built but the resultant temperature and voltage responses reveal little about the breakdown mechanism. In this report is described a pinch test which is used to evaluate NCS quality at various stages including coated anode and cathode as well as assembled cell. Coupled with post-microscopic examination of the damaged ‘pinch point’ test data can assist in the coating optimization from an improved end-use standpoint. As a result of this work two invention disclosures, one for optimizing drying methodology and the other for an in-line system for flaw detection, have been filed. In addition, 2 papers are being written for submission to peer-reviewed journals

Abraham Lincoln Statue

This postcard features an Abraham Lincoln memorial in Washington, D.C.https://scholarsjunction.msstate.edu/fvw-artifacts/5870/thumbnail.jp

Diamond Dicing

In OLAP, analysts often select an interesting sample of the data. For example, an analyst might focus on products bringing revenues of at least 100 000 dollars, or on shops having sales greater than 400 000 dollars. However, current systems do not allow the application of both of these thresholds simultaneously, selecting products and shops satisfying both thresholds. For such purposes, we introduce the diamond cube operator, filling a gap among existing data warehouse operations. Because of the interaction between dimensions the computation of diamond cubes is challenging. We compare and test various algorithms on large data sets of more than 100 million facts. We find that while it is possible to implement diamonds in SQL, it is inefficient. Indeed, our custom implementation can be a hundred times faster than popular database engines (including a row-store and a column-store).Comment: 29 page

Dew-worms in white nights: High-latitude light constrains earthworm (Lumbricus terrestris) behaviour at the soil surface

Soil is an effective barrier to light penetration that limits the direct influence of light on belowground organisms. Variation in aboveground light conditions, however, is important to soil-dwelling animals that are periodically active on the soil surface. A prime example is the earthworm Lumbricus terrestris L. (the dew-worm), an ecosystem engineer that emerges nocturnally on the soil surface. In the summer, the northernmost populations of L. terrestris are exposed to a time interval with no daily dark period. During a two-week period preceding the summer solstice, we studied the constraints that boreal night illumination imposes on L. terrestris surface activity by comparing their behaviour under ambient light with artificially-induced darkness. Looking for evidence of geographical divergence in light response, we compared the behaviour of native L. terrestris (Jokioinen, S–W Finland; 60°48′N) with two markedly more southern populations, from Preston (Lancashire, UK; 53°47′N) and Coshocton (Ohio, USA; 40°22′N) where the nights have a period of darkness throughout the year (total latitudinal range ca. 2300 km). Under ambient light conditions, L. terrestris emergence on the soil surface was diminished by half compared with the darkened treatment and it peaked at the darkest period of the night. Also mating rate decreased considerably under ambient light. The native dew-worms were generally the most active under ambient light. They emerged earlier in the evening and ceased their activity later in the morning than dew-worms from the two more southerly populations. The differences in behaviour were, however, significant mainly between native and UK dew-worms. In the darkened treatment, the behaviour of the three earthworm origins did not differ. Under the experimental conditions light condition was the dominant environmental factor controlling surface activity, but elevated night-time air temperature and humidity also encouraged dew-worm emergence without discernible differences among geographical origins. Our results show, that in boreal summer, the high level of night illumination strongly limits soil-surface activity of dew-worms. Considering the important regulatory role of L. terrestris in many ecosystem processes, this can have significant corollaries in dew-worm impacts on the environment. Although evidence for geographical differentiation in behaviour was obtained, the results point to phenotypic flexibility in L. terrestris light response

Braille text entry on smartwatches : an evaluation of methods for composing the Braille cell

Smartwatches are gaining popularity on market with a set of features comparable to smartphones in a wearable device. This novice technology brings new interaction paradigms and challenges for blind users, who have difficulties dealing with touchscreens. Among a variety of tasks that must be studied, text entry is analyzed, considering that current existing solutions may be unsatisfactory (as voice input) or even unfeasible (as working with tiny QWERTY keyboards) for a blind user. More specifically, this paper presents a study on possible solutions for composing a Braille cell on smart-watches. Five prototypes were developed and different feedback features were proposed. These are confronted with seven specialists on an evaluation study that results in a qualitative analysis of which strategies can be more useful for blind users in a Braille text entry.Postprin

Motorcycle Racer Training Device

To date, there are no devices in the motorcycle market that assist the rider in providing lean information. Our product is uniquely situated to exploit with oversight and provide motorcyclists with this information.  Our device will assist the enthusiast rider, providing information in real‐time on rider performance. For the race rider, a more sophisticated version of the device will couple GPS tracking capability with lean information and transmit that data to software running on a PC, providing real‐time information to a race crew. The crew can then analyze this information to make improvements to machine and rider and better their chances at achieving victory on the circuit

ArachnoBot [lightweight robotic spider]

Using the art of biomimetics, ArachnoBotics Research Inc. is proud to present its proposal for ArachnoBot™, a lightweight robotic spider. The ArachnoBot™ is based on a project commissioned by the European Space Agency (ESA) whose main aim is to design a spider robot prototype to be used in outer space travel. Its small, lightweight form factor is based on both the weight requirement for launching it into space, as well as that of its biological counterpart: the Arachnid

Quick Response Freight Manual II

DTFH61-06-D-00004This manual is an update to the Quick Response Freight Manual developed for FHWA in 1996. Like its predecessor, it is designed to provide background information on the freight transportation system and factors affecting freight demand to planners who may be relatively new to this area; to help planners locate available data and freight-related forecasts compiled by others, and to apply this information in developing forecasts for specific facilities; to provide simple techniques and transferable parameters that can be used to develop freight vehicle trip tables