Use of a submersible spectrophotometer probe to fingerprint spatial suspended sediment sources at catchment scale

Sediment fingerprinting is used to identify catchment sediment sources. Traditionally, it has been based on the collection and analysis of potential soil sources and target sediment. Differences between soil source properties (i.e., fingerprints) are then used to discriminate between sources, allowing the quantification of the relative source contributions to the target sediment. The traditional approach generally requires substantial resources for sampling and fingerprint analysis, when using conventional laboratory procedures. In pursuit of reducing the resources required, several new fingerprints have been tested and applied. However, despite the lower resource demands for analysis, most recently proposed fingerprints still require resource intensive sampling and laboratory analysis. Against this background, this study describes the use of UV-VIS absorbance spectra for sediment fingerprinting, which can be directly measured by submersible spectrophotometers on water samples in a rapid and non-destructive manner. To test the use of absorbance to estimate spatial source contributions to the target suspended sediment (SS), water samples were collected from a series of confluences during three sampling campaigns in which a confluence-based approach to source fingerprinting was undertaken. Water samples were measured in the laboratory and, after compensation for absorbance influenced by dissolved components and SS concentration, absorbance readings were used in combination with the MixSIAR Bayesian mixing model to quantify spatial source contributions. The contributions were compared with the sediment budget, to evaluate the potential use of absorbance for sediment fingerprinting at catchment scale. Overall deviations between the spatial source contributions using source fingerprinting and sediment budgeting were 18 % for all confluences (n = 11), for all events (n = 3). However, some confluences showed much higher deviations (up to 52 %), indicating the need for careful evaluation of the results using the spectrophotometer probe. Overall, this study shows the potential of using absorbance, directly obtained from grab water samples, for sediment fingerprinting in natural environments

Hydrological impacts of climate change at catchment scale : a case study in the Grand-Duchy of Luxembourg

As a consequence of an increase of days with westerly atmospheric fluxes, bringing humid air masses from the Atlantic Ocean to Western Europe, important changes in the annual and seasonal distribution of rainfall have been observed over the past 150 years. Annual rainfall totals observed during the second half of the 19th century were less important than those observed during the second half of the 20th century. Moreover, during the past 50 years winter rainfall totals have significantly increased, while summer rainfall totals have been decreasing. Streamflow observations through the second half of the 20th century have shown a significant increase of winter maximum daily streamflow, in reaction to the winter rainfall increase. The modelling of the streamflow under the 19th century climatological conditions suggests that since then, the number of winter flood days has increased, while the occurrence of summer flood days has decreased. Moreover, high floods appear to have been more frequent in the second half of the 20th century

Comparing hydrological responses across catchments using a new soil water content metric

Soil water content (SWC) is a fundamental variable involved in several hydrological processes governing catchment functioning. Comparative analysis of hydrological processes in different catchments based on SWC data is therefore beneficial to infer driving factors of catchment response. Here, we explored the use of high-temporal resolution SWC data in three forested catchments (2.4–60 ha) in different European climates to characterize hydrological responses during wet and dry conditions. The investigated systems include Ressi, Italy, with a humid temperate climate, Weierbach, Luxembourg, with a semi-oceanic climate, and Can Vila, Spain, with a Mediterranean climate. We introduced a new SWC metric defined as the difference between seasonal mean SWC at a relatively shallow and a deep soil layer. The difference is classified in three distinct states: similar SWC between the two layers, higher SWC in the deeper layer, and higher SWC in the shallow layer. In the most humid site, Ressi, we frequently found similar SWC at the two soil depths which was associated with high runoff ratios. Despite similar precipitation amounts in Can Vila and Weierbach, SWC patterns were very different in both catchments. In Weierbach, SWC was similar across the entire soil profile during wet conditions, whereas evaporation of shallow water resulted in higher SWC in the deep soil layer during dry conditions. This led to high runoff ratios during wet conditions and low runoff ratios during dry conditions. In Can Vila, SWC was consistently higher in the deeper layer compared to the shallow layer, irrespective of the season, suggesting an important role of hydraulic redistribution and vertical water movement in this site. Our approach provides an easy and useful method to assess differences in hydrological behaviour solely based on SWC data. As similar datasets are increasingly collected and available, this opens the possibility for further analyses and comparisons in sites around the globe with contrasted physiographic and climate characteristics.C. Segura acknowledges a Fulbright Fellowship that supported her stay at the University of Florence, Italy and the National Science Foundation Award No. 1943574. The Weierbach datasets have been collected in the framework of the Doctoral Training Unit HYDRO-CSI (Innovative methodologies for unravelling hydrological, chemical, and biological interactions across multiple scales), funded by the National Research Fund of Luxembourg (grant PRIDE15/10623093). Data collection in Ressi catchment was supported by the projects “Ecohydrological Dynamics and Water Pathways in Forested Catchments” (Bando Starting Grants 2015, Fondazione Cassa di Risparmio di Padova e Rovigo), the project “SILVA-Water fluxes between soil, vegetation and atmosphere: a comparative analysis in two Italian forested catchments” (funded by Premio Florisa Melone 2018, assigned by the Italian Hydrological Society), the Italian MIUR Project (PRIN 2017) “WATer mixing in the critical ZONe: observations and predictions under environmental changes-WATZON” (code: 2017SL7ABC), and the RETURN Extended Partnership, receiving funding from the European Union Next-GenerationEU (National Recovery and Resilience Plan – NRRP, Mission 4, Component 2, Investment 1.3 – D.D. 1243 2/8/2022, PE0000005). J. Latron and L. Pfister contributions have been supported by the RHYSOTTO (PID2019-106583RB-I00) and WARMed (PID2022-141868NB-I00) projects, both funded by the Spanish Ministry of Science and Innovation (Ministerio de Ciencia e Inovación, Agencia Estatal de Investigación). J. Latron and L. Pfister also acknowledge the collaboration of Gisel Bertran and Elisenda Sánchez during field work and data collection. The results of this study were discussed within the COST Action: “WATSON” CA19120. We also thank the constructive reviews from Nitin Singh and an anonymous reviewer.Peer reviewe

A Standardized Morpho-Functional Classification of the Planet’s Humipedons

It was time to take stock. We modified the humipedon classification key published in 2018 to make it easier and more practical. This morpho-functional taxonomy of the topsoil (humipedon) was only available in English; we also translated it into French and Italian. A standardized morphofunctional classification of humipedons (roughly the top 30–40 cm of soil: organic and organomineral surface horizons) would allow for a better understanding of the functioning of the soil ecosystem. This paper provides the founding principles of the classification of humipedon into humus systems and forms. With the recognition of a few diagnostic horizons, all humus systems can be determined. The humus forms that make up these humus systems are revealed by measuring the thicknesses of the diagnostic horizons. In the final part of the article, several figures represent the screenshots of a mobile phone or tablet application that allows for a fast recall of the diagnostic elements of the classification in the field. The article attempts to promote a standardized classification of humipedons for a global and shared management of soil at planet level

A standardized morpho-functional classification of the planet’s humipedons

It was time to take stock. We modified the humipedon classification key published in 2018 to make it easier and more practical. This morpho-functional taxonomy of the topsoil (humipedon) was only available in English; we also translated it into French and Italian. A standardized morphofunctional classification of humipedons (roughly the top 30–40 cm of soil: organic and organomineral surface horizons) would allow for a better understanding of the functioning of the soil ecosystem. This paper provides the founding principles of the classification of humipedon into humus systems and forms. With the recognition of a few diagnostic horizons, all humus systems can be determined. The humus forms that make up these humus systems are revealed by measuring the thicknesses of the diagnostic horizons. In the final part of the article, several figures represent the screenshots of a mobile phone or tablet application that allows for a fast recall of the diagnostic elements of the classification in the field. The article attempts to promote a standardized classification of humipedons for a global and shared management of soil at planet level

Hydrological impacts of climate change at catchment scale: a case study in the Grand-Duchy Luxembourg

As a consequence of an increase of days with westerly atmospheric fluxes, bringing humid air masses from the Atlantic Ocean to Western Europe, important changes in the annual and seasonal distribution of rainfall have been observed over the past 150 years. Annual rainfall totals observed during the second half of the 19th century were less important than those observed during the second half of the 20th century. Moreover, during the past 50 years winter rainfall totals have significantly increased, while summer rainfall totals have been decreasing. Streamflow observations through the second half of the 20th century have shown a significant increase of winter maximum daily streamflow, in reaction to the winter rainfall increase. The modelling of the streamflow under the 19th century climatological conditions suggests that since then, the number of winter flood days has increased, while the occurrence of summer flood days has decreased. Moreover, high floods appear to have been more frequent in the second half of the 20th century

Hydrological impacts of climate change at catchment scale: a case study in the Grand-Duchy Luxembourg

As a consequence of an increase of days with westerly atmospheric fluxes, bringing humid air masses from the Atlantic Ocean to Western Europe, important changes in the annual and seasonal distribution of rainfall have been observed over the past 150 years. Annual rainfall totals observed during the second half of the 19th century were less important than those observed during the second half of the 20th century. Moreover, during the past 50 years winter rainfall totals have significantly increased, while summer rainfall totals have been decreasing. Streamflow observations through the second half of the 20th century have shown a significant increase of winter maximum daily streamflow, in reaction to the winter rainfall increase. The modelling of the streamflow under the 19th century climatological conditions suggests that since then, the number of winter flood days has increased, while the occurrence of summer flood days has decreased. Moreover, high floods appear to have been more frequent in the second half of the 20th century