Electronic Structure of gated graphene and graphene ribbons

We study the electronic structure of gated graphene sheets. We consider both infinite graphene and finite width ribbons. The effect of Coulomb interactions between the electrically injected carriers and the coupling to the external gate are computed self-consistently in the Hartree approximation. We compute the average density of extra carriers, $n_{2D}$, the number of occupied subbands and the density profiles as a function of the gate potential $V_g$. We discuss quantum corrections to the classical capacitance and we calculate the threshold $V_g$ above which semiconducting armchair ribbons conduct. We find that the ideal conductance of perfectly transmitting wide ribbons is proportional to the square root of the gate voltage.Comment: 8 pages, 6 figure

Habitat degradation and predators have independent trait-mediated effects on prey

Coral reefs are degrading globally leading to a catastrophic loss of biodiversity. While shifts in the species composition of communities have been well documented associated with habitat change, the mechanisms that underlie change are often poorly understood. Our study experimentally examines the effects of coral degradation on the trait-mediated effects of predators on the morphology, behaviour and performance of a juvenile coral reef fish. Juvenile damselfish were exposed to predators or controls (omnivore or nothing) in seawater that had flowed over either live or dead-degraded coral over a 45d period. No interaction between water source and predator exposure was found. However, fish exposed to degraded water had larger false eyespots relative to the size of their true eyes, and were more active, both of which may lead to a survival advantage. Non-consumptive effects of predators on prey occurred regardless of water source and included longer and deeper bodies, large false eyespots that may distract predator strikes away from the vulnerable head region, and shorter latencies in their response to a simulated predator strike. Research underscores that phenotypic plasticity may assist fishes in coping with habitat degradation and promote greater resilience to habitat change than may otherwise be predicted

Second-harmonic generation of ZnO nanoparticles synthesized by laser ablation of solids in liquids

We report the synthesis of small zinc oxide nanoparticles (ZnO NPs) based colloidal suspensions and the study of second-harmonic generation from aggregated ZnO NPs deposited on glass substrates. The colloidal suspensions were obtained using the laser ablation of solids in liquids technique, ablating a Zn solid target immersed in acetone as the liquid medium, with ns-laser pulses (1064 nm) of a Nd-YAG laser. The per pulse laser fluence, the laser repetition rate frequency and the ablation time were kept constant. The absorption evolution of the obtained suspensions was optically characterized through absorption spectroscopy until stabilization. Raman spectroscopy, SEM and HRTEM were used to provide evidence of the ZnO NPs structure. HRTEM results showed that 5–8 nm spheroids ZnO NPs were obtained. Strong second-harmonic signal is obtained from random ZnO monocrystalline NPs and from aggregated ZnO NPs, suggesting that the high efficiency of the nonlinear process may not depend on the NPs size or aggregation state

Economic Geology Models 1. Geochemical Exploration and Metallogenic Studies, Northern Chile

Research was initiated in 1998 on geo-chemical methods of exploration for copper porphyry deposits buried under thick, lithified piedmont gravel cover in the Atacama Desert, Chile. Early data suggest that mineralized, saline groundwater has been episodically forced up through fracture zones to the surface during earthquakes, creating geochemical anomalies above ore deposits. Follow-up research supported by the Canadian Mining Industry Research Organization (CAMIRO) examined the composition of both groundwater and surface anomalies, confirming a link between the two. Further work suggests that the geo-chemical anomalies are the surface expression of a process common to the metallogenic evolution of many deposits. Porphyry intrusion and hypo-gene mineralization are controlled by faults, and are followed by supergene enrichment in a semi-arid climate. After burial by Miocene gravels, the climate changed to hyper-arid; estimates of the onset of hyperaridity vary from mid-Miocene (11–14 Ma) to Pliocene (~3–5 Ma). Since then, saline dewatering of the basement along long-lived faults has converted the original super-gene copper oxide assemblage, formed in equilibrium with meteoric water and lacking atacamite, to one containing atacamite [Cu2Cl(OH)3], the copper mineral especially associated with northern Chile. This interpretation is supported by studies showing that the salinity of fluid inclusions in atacamite is similar to that of local groundwater and that atacamite is considerably younger than the co-existing supergene alteration. SOMMAIRE La recherche décrite ici et initiée en 1998 visait à mettre au point des méth-odes d'exploration de gisements de porphyres cuprifères enfouis sous d'épaisses couches lithifiées de graviers dans le désert d'Atacama au Chili. Des données préliminaires indiquent que des eaux souterraines salines minéralisées ont été poussées épisodiquement jusqu'à la surface, à travers des zones de fractures, à l'occasion de séismes, créant ainsi des anomalies au-dessus de gisements minéraux. Une recherche subséquente appuyée par la Canadian Mining Industry Research Organization (CAMIRO) qui a porté sur la composition de l'eau souterraine et des anomalies de surface, a permis de confirmer l'existence d'un lien entre les deux. Les résultats de travaux subséquents permettent de croire que ces anomalies géochimiques sont l'expression en surface d'un processus commun à l'évolution métallogénique de nombreux gisements. L'intrusion porphyrique et la minéralisation hypogène sont tributaires de failles, auxquelles s'est ensuite ajouté un enrichissement supergène sous climat semi-aride. Après l'enfouissement au Miocène par des graviers, le climat est devenu hyper-aride; selon les estimations le climat serait devenu hyperaride entre le Miocène moyen (11-14 Ma) et le Pliocène (~3-5 Ma). Depuis, l'assèchement des eaux salines du socle le long de failles persistantes a entraîné une conversion de l'assemblage original d'oxydes de cuivre supergène - lequel s'était formé en état d'équilibre en milieu d'eau météorique et qui était dépourvu d'atacamite - en un assemblage contenant de l'atacamite [Cu2Cl(OH)3], ce minéral de cuivre typique du Chili du nord. Cette interprétation est corroboré par des études montrant que la salinité des inclusions fluides dans l'atacamite est semblable à celle de l'eau souterraine locale et que l'atacamite est significativement plus jeune que l'altération supergène coexistante

Vortex structure of thin mesoscopic disks in the presence of an inhomogeneous magnetic field

The vortex states in a thin mesoscopic disk are investigated within the phenomenological Ginzburg-Landau theory in the presence of different ''model'' magnetic field profiles with zero average field which may result from a ferromagnetic disk or circulating currents in a loop near the superconductor. We calculated the dependences of both the ground and metastable states on the magnitude and shape of the magnetic field profile for different values of the order parameter angular moment, i.e. the vorticity. The regions of existence of the multi-vortex state and the giant vortex state are found. We analysed the phase transitions between these states and studied the contribution from ring-shaped vortices. A new transition between different multi-vortex configurations as the ground state is found. Furthermore, we found a vortex state consisting of a central giant vortex surrounded by a collection of anti-vortices which are located in a ring around this giant vortex. The limit to a disk with an infinite radius, i.e. a film, will also be discussed. We also extended our results to ''real'' magnetic field profiles and to the case in which an external homogeneous magnetic field is present.Comment: 17 pages, 23 figures. Submitted to PR

Formation of a reliable intermediate band in Si heavily coimplanted with chalcogens (S, Se, Te) and group III elements (B, Al)

This first-principles study describes the properties of Si implanted with several chalcogen species (S, Se, Te) at doses considerably above the equilibrium solubility limit, especially when coimplanted with the group III atoms B and Al. The measurements of chalcogen-implanted Si show strong optical absorption in the infrared range. The calculations carried out show that substitution of Si by chalcogen atoms requires lower formation energy than the interstitial implantation. In the resulting electronic structure, at concentrations close to 0.5%, an impurity band determined by the properties of the chalcogens introduced is observed in the forbidden energy gap of Si. Although this band is a few tenths of an electron volt wide, it remains energetically isolated from both the valence and the conduction bands. Appropriate coimplantation with group III elements allows control over the occupation of the intermediate band while modifying its energies only slightly. A moderate energy gain (especially small for B) seems to be obtained when p-doping atoms occupy the sites next to those of the chalcogens. Therefore, the apparent electrostatic attraction between species that in isolation would act as acceptors and double donors is smaller than expected. The intermediate-band properties have been preserved for all of the coimplanted compounds analyzed here, regardless of the species involved or the distance between them, which constitutes an appreciable advantage for the design of new experimental materials

Vortex matter in superconducting mesoscopic disks: Structure, magnetization, and phase transitions

The dense vortex matter structure and associated magnetization are calculated for type-II superconducting mesoscopic disks. The magnetization exhibits generically first-order phase transitions as the number of vortices changes by one and presents two well-defined regimes: A non-monotonous evolution of the magnitude of the magnetization jumps signals the presence of a vortex glass structure which is separated by a second-order phase transition at $H_{c2}$ from a condensed state of vortices (giant vortex) where the magnitude of the jumps changes monotonously. We compare our results with Hall magnetometry measurements by Geim et al. (Nature 390, 259 (1997)) and claim that the magnetization exhibits clear traces of the presence of these vortex glass states.Comment: 4 pages, 3 figure

Long time universality of black-hole lasers

For flowing quantum gases, it has been found that at long times an initial black-hole laser (BHL) configuration exhibits only two possible states: the ground state or a periodic self-oscillating state of continuous emission of solitons. So far, all the works on this subject are based on a highly idealized model, quite difficult to implement experimentally. Here we study the instability spectrum and the time evolution of a recently proposed realistic model of a BHL, thus providing a useful theoretical tool for the clear identification of black-hole lasing in future experiments. We further confirm the existence of a well-defined phase diagram at long times, which bespeaks universality in the long-time behavior of a BHL. Additionally, we develop a complementary model in which the same potential profile is applied to a subsonic homogeneous flowing condensate that, despite not forming a BHL, evolves towards the same phase diagram as the associated BHL model. This result reveals an even stronger form of robustness in the long-time behavior with respect to the transient, which goes beyond what has been described in the previous literature.Comment: 14 pages, 8 figures. Final version of the manuscrip

Induction of interleukin-1 alpha production by Porphyromonas gingivalis in mononuclear blood cell cultures from periodontitis patients

The capacity of mononuclear blood cells to produce interleukin-1 alpha (IL-1 alpha) after stimulation with Porphyromonas gingivalis in cell culture was studied. The results obtained with cells from periodontitis patients were compared with those from a control population. The concentration of IL-1 alpha in serum and saliva was also determined and compared with the concentration in mononuclear blood cell cultures. No significant relationship was found between the incidence of periodontitis or severity of the lesions and IL-1 alpha production in the presence of P. gingivalis. Nevertheless, 11 of 30 periodontitis patients, showed levels >30pg/ml of IL-1 alpha in mononuclear blood cell cultures stimulated by P. gingivalis, whereas only three healthy control showed these titers of IL-1 alpha.Nous avons étudiés la production d’interleukine-1 alpha (Il-1 alpha) par des monocytes sanguins en culture après stimulation par Porphyromonas gingivalis. Les résultats observés chez des patients atteints de parodontose ont été comparés avec ceux obtenus chez des témoins. La concentration de Il-1 alpha dans le sérum et la salive a également été comparée avec celle des cultures de monocytes. Nous n’avons pas trouvé de différences significatives entre la sévérité des lésions parodontales et les concentrations d’Il-1 alpha. Cependant, 11 des 30 patients atteints de parodontose présentaient des niveaux d’Il-1 alpha supérieurs à 30 µg/ml, tandis que seulement 3 témoins avaient des niveaux élevés