A Stark decelerator on a chip

A microstructured array of 1254 electrodes on a substrate has been configured to generate an array of local minima of electric field strength with a periodicity of 120 $\mu$m about 25 $\mu$m above the substrate. By applying sinusoidally varying potentials to the electrodes, these minima can be made to move smoothly along the array. Polar molecules in low-field seeking quantum states can be trapped in these traveling potential wells. Recently, we experimentally demonstrated this by transporting metastable CO molecules at constant velocities above the substrate [Phys. Rev. Lett. 100 (2008) 153003]. Here, we outline and experimentally demonstrate how this microstructured array can be used to decelerate polar molecules directly from a molecular beam. For this, the sinusoidally varying potentials need to be switched on when the molecules arrive above the chip, their frequency needs to be chirped down in time, and they need to be switched off before the molecules leave the chip again. Deceleration of metastable CO molecules from an initial velocity of 360 m/s to a final velocity as low as 240 m/s is demonstrated in the 15-35 mK deep potential wells above the 5 cm long array of electrodes. This corresponds to a deceleration of almost $10^5$ $g$, and about 85 cm$^{-1}$ of kinetic energy is removed from the metastable CO molecules in this process.Comment: 17 pages, 6 figure

Hybrid One-Shot 3D Hand Pose Estimation by Exploiting Uncertainties

Model-based approaches to 3D hand tracking have been shown to perform well in a wide range of scenarios. However, they require initialisation and cannot recover easily from tracking failures that occur due to fast hand motions. Data-driven approaches, on the other hand, can quickly deliver a solution, but the results often suffer from lower accuracy or missing anatomical validity compared to those obtained from model-based approaches. In this work we propose a hybrid approach for hand pose estimation from a single depth image. First, a learned regressor is employed to deliver multiple initial hypotheses for the 3D position of each hand joint. Subsequently, the kinematic parameters of a 3D hand model are found by deliberately exploiting the inherent uncertainty of the inferred joint proposals. This way, the method provides anatomically valid and accurate solutions without requiring manual initialisation or suffering from track losses. Quantitative results on several standard datasets demonstrate that the proposed method outperforms state-of-the-art representatives of the model-based, data-driven and hybrid paradigms.Comment: BMVC 2015 (oral); see also http://lrs.icg.tugraz.at/research/hybridhape

The Impact of Weld Metal Creep Strength on the Overall Creep Strength of 9% Cr Steel Weldments

In this work, three joints of a X11CrMoWVNb9-1-1 (P911) pipe were welded with three filler metals by conventional arc welding. The filler metals varied in creep strength level, so that one overmatched, one undermatched, and one matched the creep strength of the P911 grade pipe base material. The long-term objective of this work was to study the influence of weld metal creep strength on the overall creep behavior of the welded joints and their failure mechanism. Uniaxial creep tests at 600°C and stresses ranging from 70 MPa to 150 MPa were performed on the cross-weld samples of all three welds. A total creep testing time of more than 470,000 h was accumulated. The longest running sample achieved a time-to-rupture of more than 45,000 h. Creep testing revealed that the use of undermatching weld metal led to a premature fracture in the weld metal at higher stress levels. Compared with undermatching weld metal, the use of matching and overmatching filler materials increased the time-to-rupture at high stress levels by 75% and 33% at lowest stress levels. At typical component stresses below 100 MPa, all samples failed in the grain-refined heat-affected zone by characteristic type IV failure. For investigations of the failure modes, cross sections of fractured samples were investigated by optical light microscopy, scanning electron microscopy, and electron backscatter diffraction. The mechanism of weld metal creep failures and type IV creep failures is discussed in detail

Category learning in a dynamic world

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Trapping molecules on a chip in traveling potential wells

A microstructured array of over 1200 electrodes on a substrate has been configured to generate an array of local minima of electric field strength with a periodicity of $120 \mu$m about $25 \mu$m above the substrate. By applying sinusoidally varying potentials to the electrodes, these minima can be made to move smoothly along the array. Polar molecules in low field seeking quantum states can be trapped in these traveling potential wells. This is experimentally demonstrated by transporting metastable CO molecules in 30 mK deep wells that move at constant velocities above the substrate.Comment: 4 pages, 3 figure

Achieving the Shot-noise Limit Using Experimental Multi-shot Digital Holography Data

In this paper, we achieve the shot-noise limit using straightforward image-post-processing techniques with experimental multi-shot digital holography data (i.e., off-axis data composed of multiple noise and speckle realizations). First, we quantify the effects of frame subtraction (of the mean reference-only frame and the mean signal-only frame from the digital-hologram frames), which boosts the signal-to-noise ratio (SNR) of the baseline dataset with a gain of 2.4 dB. Next, we quantify the effects of frame averaging, both with and without the frame subtraction. We show that even though the frame averaging boosts the SNR by itself, the frame subtraction and the stability of the digital-hologram fringes are necessary to achieve the shot-noise limit. Overall, we boost the SNR of the baseline dataset with a gain of 8.1 dB, which is the gain needed to achieve the shot-noise limit

Nuclear-Spin Relaxation in the Rotating Frame in Solid D\u3csub\u3e2\u3c/sub\u3e

The decay of the nuclear magnetization along a spin-locking field in the rotating frame has been studied in solid deuterium, at a frequency of 4.7 MHz, following the method of Rowland and Fradin. Measurements were made between 4 and 13 K, on samples having para (J=1) mole fractions X ranging from 0.04 to 0.9. The lab-frame transverse relaxation time T2 was measured in the range 13-17 K. These data permitted the observation of thermally activated diffusion between 9 and 17 K, corresponding to a change in the characteristic time τ between molecular jumps of some seven orders of magnitude. The activation energy is (276 ± 20) K, independent of concentration. No evidence could be detected of the slow diffusion from quantum tunneling of vacancies predicted by Ebner and Sung. For the temperature range below about 8 K, the rotating-frame formalism has been adapted to the specific spin-lattice relaxation mechanisms present in D2, and account has been taken of the intramolecular spin-spin interactions. Effects of translational molecular motion were not seen in this region. This is consistent with the very slow rates expected theoretically by Oyarzun and Van Kranendonk. At intermediate and high (J=1) mole fractions X and below about 8 K, the exponential decay of the spin-locked magnetization was preceded by a short transient of approximately 0.1-sec duration. This transient is thought to be associated with the internal equilibration of the nuclear-spin energy systems. Its lifetime Tx is much longer than T2 of the rigid lattice because the NMR line is inhomogeneously broadened by the intramolecular spin-spin interactions. The magnitude of Tx has been correlated with previously reported cross-relaxation times for the lab frame

Prenucleation self-assembly and chiral discrimination mechanisms during solution crystallisation of racemic diprophylline

The crystallisation behaviour of (RS)-diprophylline (DPL) in two different solvents is investigated to assess the incidence of solvated pre-associations on nucleation, crystal growth and chiral discrimination. In the solvated state, Raman spectroscopy shows that dimeric associations similar to those depicted in the crystalline solid solution (ssRII) predominate in isopropanol (IPA), which may account for the systematic spontaneous nucleation of this crystal form from this solvent. By contrast, spontaneous nucleation in DMF yields the stable racemic compound RI, consistently with the distinct features of the Raman spectrum collected in this solvent. A crystal growth study of ssRII in IPA reveals that the crystal habitus is impacted by the solution enantiomeric excess; this is explained by increased competition between homo- and heterochiral pre-associations. This is supported by a molecular modelling study on the enantiomeric selectivity of the DPL crystal lattices. The combination of assessment methods on solution chemistry, nucleation and chiral discrimination provides methodological tools from which the occurrence of solid solutions can be rationalised