132 research outputs found
Electron-Phonon Interactions in C-derived Molecular Solids
We present {\it ab initio} density-functional calculations of molecular
solids formed from C-derived closed-shell fullerenes. Solid
CH is found to bind weakly and exhibits many of the electronic
structure features of solid C with an enhanced electron-phonon
interaction potential. We show that chemical doping of this structure is
feasible, albeit more restrictive than its C counterpart, with an
estimated superconducting transition temperature exceeding those of the
alkali-doped C solids.Comment: Lower quality postscript file for Figure 1 is used in the manuscript
in order to meet submission quota for pre-print server. Higher quality
postscript file available from author: [email protected] This article has
been updated to reflect changes incorporated during the peer review process.
It is published in PRB 70, 140504(R) 200
An axisymmetric hydrodynamical model for the torus wind in AGN. III: Spectra from 3D radiation transfer calculations
We calculate a series of synthetic X-ray spectra from outflows originating
from the obscuring torus in active galactic nuclei (AGN). Such modeling
includes 2.5D hydrodynamical simulations of an X-ray excited torus wind,
including the effects of X-ray heating, ionization, and radiation pressure. 3D
radiation transfer calculations are performed in the 3D Sobolev approximation.
Synthetic X-ray line spectra and individual profiles of several strong lines
are shown at different inclination angles, observing times, and for different
characteristics of the torus.
Our calculations show that rich synthetic warm absorber spectra from 3D
modeling are typically observed at a larger range of inclinations than was
previously inferred from simple analysis of the transmitted spectra. In
general, our results are supportive of warm absorber models based on the
hypothesis of an "X-ray excited funnel flow" and are consistent with
characteristics of such flows inferred from observations of warm absorbers from
Seyfert 1 galaxies.Comment: 31 pages, 10 figure
Kepler423b: a half-Jupiter mass planet transiting a very old solar-like star
We report the spectroscopic confirmation of the Kepler object of interest
KOI-183.01 (Kepler-423b), a half-Jupiter mass planet transiting an old
solar-like star every 2.7 days. Our analysis is the first to combine the full
Kepler photometry (quarters 1-17) with high-precision radial velocity
measurements taken with the FIES spectrograph at the Nordic Optical Telescope.
We simultaneously modelled the photometric and spectroscopic data-sets using
Bayesian approach coupled with Markov chain Monte Carlo sampling. We found that
the Kepler pre-search data conditioned (PDC) light curve of KOI-183 exhibits
quarter-to-quarter systematic variations of the transit depth, with a
peak-to-peak amplitude of about 4.3 % and seasonal trends reoccurring every
four quarters. We attributed these systematics to an incorrect assessment of
the quarterly variation of the crowding metric. The host star KOI-183 is a G4
dwarf with M_\rm{Sun},
R_\rm{Sun}, K, dex, and with
an age of Gyr. The planet KOI-183b has a mass of
M and a radius of
R, yielding a planetary bulk
density of g/cm. The radius of KOI-183b
is consistent with both theoretical models for irradiated coreless giant
planets and expectations based on empirical laws. The inclination of the
stellar spin axis suggests that the system is aligned along the line of sight.
We detected a tentative secondary eclipse of the planet at a 2-
confidence level ( ppm) and found that the
orbit might have a small non-zero eccentricity of .
With a Bond albedo of , KOI-183b is one of the
gas-giant planets with the lowest albedo known so far.Comment: 13 pages, 13 figures, 5 tables. Accepted for publication in A&A.
Planet designation changed from KOI-183b to Kepler-423
Fine-tuning of AMPK–ULK1–mTORC1 regulatory triangle is crucial for autophagy oscillation
Autophagy is an intracellular digestive process, which has a crucial role in maintaining cellular homeostasis by self-eating the unnecessary and/or damaged components of the cell at various stress events. ULK1, one of the key elements of autophagy activator complex, together with the two sensors of nutrient and energy conditions, called mTORC1 and AMPK kinases, guarantee the precise function of cell response mechanism. We claim that the feedback loops of AMPK–mTORC1–ULK1 regulatory triangle determine an accurate dynamical characteristic of autophagic process upon cellular stress. By using both molecular and theoretical biological techniques, here we reveal that a delayed negative feedback loop between active AMPK and ULK1 is essential to manage a proper cellular answer after prolonged starvation or rapamycin addition. AMPK kinase quickly gets induced followed by AMPK-P-dependent ULK1 activation, whereas active ULK1 has a rapid negative effect on AMPK-P resulting in a delayed inhibition of ULK1. The AMPK-P → ULK1 ˧ AMPK-P negative feedback loop results in a periodic repeat of their activation and inactivation and an oscillatory activation of autophagy, as well. We demonstrate that the periodic induction of self-cannibalism is necessary for the proper dynamical behaviour of the control network when mTORC1 is inhibited with respect to various stress events. By computational simulations we also suggest various scenario to introduce “delay” on AMPK-P-dependent ULK1 activation (i.e. extra regulatory element in the wiring diagram or multi-phosphorylation of ULK1). © 2020, The Author(s)
Gaps and excitations in fullerides with partially filled bands : NMR study of Na2C60 and K4C60
We present an NMR study of Na2C60 and K4C60, two compounds that are related
by electron-hole symmetry in the C60 triply degenerate conduction band. In both
systems, it is known that NMR spin-lattice relaxation rate (1/T1) measurements
detect a gap in the electronic structure, most likely related to
singlet-triplet excitations of the Jahn-Teller distorted (JTD) C60^{2-} or
C60^{4-}. However, the extended temperature range of the measurements presented
here (10 K to 700 K) allows to reveal deviations with respect to this general
trend, both at high and low temperatures. Above room temperature, 1/T1 deviates
from the activated law that one would expect from the presence of the gap and
saturates. In the same temperature range, a lowering of symmetry is detected in
Na2C60 by the appearance of quadrupole effects on the 23Na spectra. In K4C60,
modifications of the 13C spectra lineshapes also indicate a structural
modification. We discuss this high temperature deviation in terms of a coupling
between JTD and local symmetry. At low temperatures, 1/TT tends to a
constant value for Na2C60, both for 13C and 23Na NMR. This indicates a residual
metallic character, which emphasizes the proximity of metallic and insulting
behaviors in alkali fullerides.Comment: 12 pages, 13 figure
Metal-Insulator Transitions in Degenerate Hubbard Models and AC
Mott-Hubbard metal-insulator transitions in -fold degenerate Hubbard
models are studied within the Gutzwiller approximation. For any rational
filling with (integer) electrons per site it is found that metal-insulator
transition occurs at a critical correlation energy
, where
is the band energy per particle for the uncorrelated Fermi-liquid state and
is a geometric factor which increases linearly with . We
propose that the alkali metal doped fullerides can be described by
a 3-fold degenerate Hubbard model. Using the current estimate of band width and
correlation energy this implies that most of , at integer ,
are Mott-Hubbard insulators and is a strongly correlated
metal.Comment: 10 pages, Revte
Multiwavelength campaign on Mrk 509. III. The 600 ks RGS spectrum: unravelling the inner region of an AGN
We present the results of our 600 ks RGS observation as part of the
multiwavelength campaign on Mrk 509. The very high quality of the spectrum
allows us to investigate the ionized outflow with an unprecedented accuracy due
to the long exposure and the use of the RGS multipointing mode. We detect
multiple absorption lines from the interstellar medium and from the ionized
absorber in Mrk 509. A number of emission components are also detected,
including broad emission lines consistent with an origin in the broad line
region, the narrow OVII forbidden emission line and also (narrow) radiative
recombination continua. The ionized absorber consists of two velocity
components (v = -13 \pm 11 km/s and v = -319 \pm 14 km/s), which both are
consistent with earlier results, including UV data. There is another tentative
component outflowing at high velocity, -770 \pm 109 km/s, which is only seen in
a few highly ionized absorption lines. The outflow shows discrete ionization
components, spanning four orders of magnitude in ionization parameter. Due to
the excellent statistics of our spectrum, we demonstrate for the first time
that the outflow in Mrk 509 in the important range of log xi between 1-3 cannot
be described by a smooth, continuous absorption measure distribution, but
instead shows two strong, discrete peaks. At the highest and lowest ionization
parameters we cannot differentiate smooth and discrete components.Comment: 17 pages, 13 figures, 7 tables. Accepted for publication in Astronomy
& Astrophysic
PDMS microfluidics developed for polymer based photonic biosensors
In this work, advances in the fabrication technology and functional analysis of a polymer microfluidic system-as a significant part of a developed polymer photonic biosensor-are reported. Robust and cost-effective microfluidics in PDMS including sample preparation functions is designed and realized by using SU-8 moulding replica. Surface modification strategies using Triton X-100 and PDMS-PEO and their effect on device sealing and non-specific protein adsorption are investigated by contact angle measurement and in situ fluorescence microscopy. © 2014 Springer-Verlag Berlin Heidelberg
Observation and Assignment of Silent and Higher Order Vibrations in the Infrared Transmission of C60 Crystals
We report the measurement of infrared transmission of large C60 single
crystals. The spectra exhibit a very rich structure with over 180 vibrational
absorptions visible in the 100 - 4000 cm-1 range. Many silent modes are
observed to have become weakly IR-active. We also observe a large number of
higher order combination modes. The temperature (77K - 300K) and pressure (0 -
25KBar) dependencies of these modes were measured and are presented. Careful
analysis of the IR spectra in conjunction with Raman scattering data showing
second order modes and neutron scattering data, allow the selection of the 46
vibrational modes C60. We are able to fit *all* of the first and second order
data seen in the present IR spectra and the previously published Raman data
(~300 lines total), using these 46 modes and their group theory allowed second
order combinations.Comment: REVTEX v3.0 in LaTeX. 12 pages. 8 Figures by request. c60lon
Microwave Spectroscopy of Thermally Excited Quasiparticles in YBa_2Cu_3O_{6.99}
We present here the microwave surface impedance of a high purity crystal of
measured at 5 frequencies between 1 and 75 GHz. This data
set reveals the main features of the conductivity spectrum of the thermally
excited quasiparticles in the superconducting state. Below 20 K there is a
regime of extremely long quasiparticle lifetimes, due to both the collapse of
inelastic scattering below and the very weak impurity scattering in the
high purity -grown crystal used in this study. Above 20 K, the
scattering increases dramatically, initially at least as fast as .Comment: 13 pages with 10 figures. submitted to Phys Rev
- …