538 research outputs found

    A kinetic study of the photolysis of tris(2,4-pentanedionato)cobalt(III) and bis(2,4-pentanedionato)cobalt(II) in chloroform

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    Under 254nm irradiation in chloroform, Co(acac)3 (Hacac = 2,4-pentanedione) is converted to Co(acac)2 and then to CoCl2. The metal complex is the primary photoactive species in the photoreduction of Co(acac)3, but the photosubstitution of Co(acac)2 appears to occur primarily through absorption of light by the solvent, followed by a chain reaction in which chlorine atoms displace pentanedionyl radicals. The photosubstitution rate law is complex, and the apparent quantum yield (based on total light absorbed) varies with incident light intensity and Co(acac)2 concentration, reaching values as high as 16 under the conditions of this study. Referred only to the light absorbed by CHCL3, the highest quantum yield measured was 150. An observed partial inverse dependence of the photosubstitution rate on the initial concentration of Co(acac)2 is explained in terms of a mechanism in which the pentanedione product competes with Co(acac)2 for an intermediate

    Wheat take-all

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    "Take-all is a root and crown disease of winter wheat that interrupts plant development and may seriously suppress yields. It is a common problem in the winter wheat regions of Southwestern and Northwestern North America, and it occurs occasionally on winter wheat in Missouri."--First page.J. Al Wrather and Al Hoggard (Departments of Plant Pathology and Agronomy, College of Agriculture)New 10/83/10

    Abundance and Seasonal Occurrence of Cetaceans in Outer Continental Shelf and Slope Waters of the North-Central and Northwestern Gulf of Mexico

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    Eight aerial line-transect surveys of outer continental shelf and continental slope waters (range 100-2,000 m deep) were conducted seasonally from summer 1992 through spring 1994 in the north-central and northwestern Gulf of Mexico to study the seasonal occurrence and spatial distribution of cetaceans and to estimate their abundances. The surveys sampled an 85,815 km2 study area, resulting in 49,960 km of effort and sightings of at least 18 cetacean species and 365 cetacean groups. Eight species identified in four seasons included bottlenose dolphin (Tursiops truncatus), pantropical spotted dolphin (Stenella attenuata), Risso\u27s dolphin (Grampus griseus), dwarf sperm whale (Kogia sima) and pygmy sperm whale (Kogia breviceps), sperm whale (Physeter macrocephalus), short-finned pilot whale (Globicephala macrorhynchus), rough-toothed dolphin (Steno bredanensis), and Atlantic spotted dolphin (Stenella frontalis). Clymene dolphin (Stenella clymene), striped dolphin (Stenella coeruleoalba), and beaked whales (Mesoplodon spp.) were sighted in three seasons. The number of species sighted seasonally ranged from 10 in fall to 15 in winter. The overall estimated abundance (number of animals) of five species, which accounted for 71% of the identified group sightings, were as follows: bottlenose dolphin, 2,890 (coefficient of variation [CV] = 0.20); pantropical spotted dolphin, 5,097 (CV = 0.24); Risso\u27s dolphin, 1,237 (CV = 0.28); dwarf-pygmy sperm whale, 176 (CV = 0.31 ); and sperm whale, 87 (CV = 0.27). Melon-headed whales (Peponocephala electra) were sighted less frequently but were abundant (2,561; CV = 0.74) because of large group sizes. Common species were widely distributed spatially but occurred in different water depth ranges. In general, species abundance estimates varied seasonally, but the precision of estimates was usually poor (CV \u3e 0.30) and provided little power to detect significant seasonal differences

    Spatial and temporal patterns of Cenozoic dynamic topography around Australia

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    [1] Despite its importance, the spatial and temporal pattern of dynamic topography generated by mantle convective circulation is poorly known. We present accurate estimates of dynamic topography from oceanic basins and continental margins surrounding Australia. Our starting point is measurement of residual depth anomalies on the oldest oceanic floor adjacent to the continental shelf. These anomalies were determined from a combined dataset of ~200 seismic reflection and wide-angle images of well-sedimented oceanic crust. They have amplitudes of between −1 km and +0.5 km, and their spatial variation is broadly consistent with long-wavelength free-air gravity and shallow seismic tomographic anomalies. Along the Northwest Shelf, a regional depth anomaly of −300 to −700 m intersects the adjacent continental shelf. The temporal evolution of this anomaly was determined by analyzing the stratigraphic architecture of an extensive carbonate platform, which fringes the shelf and records a dramatic switch from progradation to aggradation during Neogene times. Three-dimensional seismic mapping calibrated by boreholes was used to calculate water-loaded subsidence histories at rollover points of clinoforms along the shelf. At 9 ± 3 Ma, the rate of subsidence increases from 5 to up 75 m Myr−1, generating a subsidence anomaly of −300 to −700 m. The amplitude of this anomaly varies along the shelf and cannot be generated by glacio-eustatic sea-level variation. Instead, we propose that a regional subsidence episode, which affects both the proximal shelf and the distal oceanic basin, was generated by convective drawdown. By combining our results with other published estimates of uplift and subsidence, a map of Australia, which shows the spatial and temporal pattern of dynamic topography is presented. Most, but not all, of Australia's epeirogeny can be attributed to rapid northward motion of the Australian plate over a pre-existing pattern of convective circulation

    Global dynamic topography observations reveal limited influence of large-scale mantle flow

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    Convective circulation of the Earth’s mantle maintains some fraction of surface topography that varies with space and time. Most predictive models show that this dynamic topography has peak amplitudes of about ±2km, dominated by wavelengths of 10⁴km. Here, we test these models against our comprehensive observational database of 2,120 spot measurements of dynamic topography that were determined by analysing oceanic seismic surveys. These accurate measurements have typical peak amplitudes of ±1km and wavelengths of approximately 10³km, and are combined with limited continental constraints to generate a global spherical harmonic model whose robustness has been carefully tested and benchmarked. Our power spectral analysis reveals significant discrepancies between observed and predicted dynamic topography. At longer wavelengths (such as 10⁴km), observed dynamic topography has peak amplitudes of about ±500m. At shorter wavelengths (such as 10³km), significant dynamic topography is still observed. We show that these discrepancies can be explained if short-wavelength dynamic topography is generated by temperature-driven density anomalies within a sub-plate asthenospheric channel. Stratigraphic observations from adjacent continental margins show that these dynamic topographic signals evolve quickly with time. More rapid temporal and spatial changes in vertical displacement of the Earth’s surface have direct consequences for fields as diverse as mantle flow, oceanic circulation and long-term climate change

    Non-Invasive Genetic Sampling of Faecal Material and Hair from the Grey-Headed Flying-Fox (Pteropus poliocephalus)

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    Remote-sampling DNA from animals offers obvious benefits for species that are difficult to sample directly and is less disruptive for species of conservation concern. Here we report the results of a pilot study investigating non-invasive DNA sampling of the grey-headed flying-fox (Pteropus poliocephalus), a threatened species that is restricted to the east coast of Australia. We successfully extracted DNA from fresh scats and hair, each of which was of sufficient quality for amplifying mitochondrial DNA markers and microsatellites. A single-locus multitube approach was used to investigate amplification success and genotyping reliability. Faecal samples yielded a higher proportion of successful amplifications and consensus genotype assignments than hair samples. We outline measures that may be utilised to minimise microsatellite genotyping error for future studies. These indirect approaches to obtaining genetic data show much promise given the difficult nature of directly sampling flying-foxes and related species

    Cenozoic Epeirogeny of Arabian Peninsula from Drainage Modeling

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    It is generally accepted that the Arabian Peninsula has been uplifted by subcrustal processes. Positive residual depth anomalies from oceanic crust in the Red Sea and in the Gulf of Aden suggest that a region surrounding this peninsula is dynamically supported. Admittance calculations, surface wave tomography studies, and receiver function analyses all imply that regional topography is generated and maintained by some combination of mantle convective circulation and lithospheric thickness changes. Despite these significant advances, the spatial and temporal uplift rate history of the Arabian Peninsula is not well known. Here we show that a regional uplift rate history can be obtained by jointly inverting 225 longitudinal river profiles that drain this peninsula. Our strategy assumes that shapes of individual river profiles are controlled by uplift rate history and moderated by erosional processes. We used local measurements of incision rate to calibrate the relevant erosional parameters. In our inverse algorithm, uplift rate is permitted to vary smoothly as a function of space and time but upstream drainage area remains invariant. We also assume that knickzone migration is not lithologically controlled. Implications of these important assumptions have been investigated. Our results suggest that the Arabian Peninsula underwent two phases of asymmetric uplift during the last 20–30 Ma at rates of 0.05–0.1 mm a−1. The southwestern flank of the peninsula has been uplifted by 1.5–2.5 km. Regional stratigraphic constraints, the age and composition of volcanism, paleosol formation, incised peneplains, emergent marine terraces, and thermochronometric measurements corroborate our calculated patterns of uplift. Progressive development of three domal swells along the western margin of the peninsula is consistent with localized upwelling of hot asthenospheric mantle

    Low grade glioma: An Update for Radiologists

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    With the recent publication of a new World Health Organization (WHO) brain tumour classification that reflects increased understanding of glioma tumour genetics there is a need for radiologists to understand the changes and their implications for patient management. There has also been an increasing trend for adopting earlier, more aggressive surgical approaches to low grade glioma treatment. We will summarise these changes, give some context to the increased role of tumour genetics and discuss the associated implications for radiologists of their adoption. We will discuss the earlier and more radical surgical resection of low grade gliomas and what it means for imaging patients
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