Facies, outcrop gamma ray and isotopic signature of exposed Miocene subtropical continental shelf carbonates, North West Cape, Western Australia

Exposed, uplifted Miocene carbonate sequences of the Cape Range, North West Cape, Western Australia, provide outcrop analogues of seismic sequences from offshore parts of the shelf. Facies include deep shelf marls (very fine and fine packstone), larger foram wackestone, floatstone and muddy rudstone, foram-coralline algal skeletal fragment packstone wackestone (shallow seagrass facies), lagoonal wackestone mudstone with scattered corals, and tidal flat laminites. The exposed Early Miocene units include the Mandu highstand, a sequence in the Tulki and one in the Middle Miocene Trealla Limestone. Sequences contain decameter scale (5 20 m thick), 4th-order parasequences evident on gamma ray logs and by facies stacking, that shallow and coarsen up; they appear to be due to eccentricity driven sea-level changes which may have been up to 50 m. Higher frequency meter-scale parasequences of deep water marl up into larger foram rudstone/floatstone (perhaps precession/obliquity) are evident at the base of the exposed Mandu section. These parasequences are not merely random storm deposits. This is indicated by the covariance of C and O isotopes, with the lighter values associated with deepening and deposition of deep shelf marls, and the heavier values being associated with shallowing and deposition of larger foram facies.The uplifted Miocene continental shelf sediments of the North West Cape preserve a record of eustasy, paleoclimate and paleoceanography and thus provide a window into factors affecting the shelf, that can be compared with coeval, better studied deep sea cores

USING UNDERWATER 3D KINEMATICS TO IMPROVE THE PARALYMPIC SWIMMING CLASSIFICATION SYSTEM

Swimming is a fundamental sport at the Olympic and Paralympic games, with the Paralympic classification system being the key difference between these games. To improve the accuracy of the classification system this case study investigated differences in the underwater hand kinematics of the affected and unaffected limb of an elite Para swimmer with hemiplegic cerebral palsy. In this case study, hemiplegic cerebral palsy caused impairments in strength, motor coordination and range of motion that affected hand speeds and trajectory paths during the underwater stroke phases. This work illustrates the benefit of using objective impairment and sport-specific measurements to gain insights into the impact that health conditions have on performance to guide Para swimming classification. This biomechanical analysis lays the foundations for the future improvement in international Para classification system

Fluorinated models of the iron-only hydrogenase: An electrochemical study of the influence of an electron-withdrawing bridge on the proton reduction overpotential and catalyst stability

AbstractHere we report the synthesis, electrochemistry and electrocatalytic activity of Fe2(CO)6(μ-SC6F5)2 (1) where the highly fluorinated bridge is electron-withdrawing, resulting in decreased electron-density at the iron–iron bond. Additionally we discuss the related substituted complexes Fe2(CO)5(PPh3)(μ-SC6F5)2 (2) and Fe2(CO)4(μ-Ph2PCH2PPh2)(μ-SC6F5)2 (3). As none of the complexes could be protonated in their neutral form it was found that proton reduction catalysis in the presence of strong acid (HBF4) took place at the potential of the first reduction of complex 1 and 3, following an EC mechanism. Complex 2 was unstable in the presence of strong acid. For 1 the potential at which proton reduction took place represented a relatively mild reduction potential (−1.15V vs. Fc/Fc+ in acetonitrile) that was comparable to examples of similar complexes in the literature. Complex 1 generated a small concentration of a highly catalytic species after electrochemical reduction, which we attribute to cleavage of the Fe–Fe bond and formation of a mono-nuclear iron species or to Fe–S bond breakage generating a vacant coordination site. The contributions to the catalytic currents were simulated using DigiSim, where it was found that the rate limiting step for 3 was the elimination of H2. It was also found that the highly catalytic species generated after reduction of 1 was more basic than 1− and also that protonation of this species was faster

Drinking to Cope is Uniquely Associated with Less Specific and Bleaker Future Goal Generation in Young Hazardous Drinkers

This is the final version. Available on open access from Springer via the DOI in this recordGroups with mental health and/or substance use problems generate less detailed descriptions of their future goals. As substance use to cope with negative affect is common to both groups, this characteristic might be uniquely associated with less specific goal descriptions. To test this prediction, 229 past year hazardous drinking undergraduates aged 18–25 years wrote about three positive future life goals in an open-ended survey, before reporting their internalizing (anxiety and depression) symptoms, alcohol dependence severity and motivations for drinking: coping, conformity, enhancement and social. Future goal descriptions were experimenter-rated for detail specificity, and participant-self-rated for positivity, vividness, achievability, and importance. Effort in goal writing was indexed by time spent writing and total word count. Multiple regression analyses revealed that drinking to cope was uniquely associated with the production of less detailed goals, and lower self-rated positivity and vividness of goals (achievability and importance were also marginally lower), over and above internalizing symptoms, alcohol dependence severity, drinking for conformity, enhancement and social motives, age, and gender. However, drinking to cope was not uniquely associated with reduced effort in writing goals: time spent and word count. In sum, drinking to cope with negative affect is a unique characteristic predicting the generation of less detailed and bleaker (less positive and vivid) future goals, and this is not due to lower effort in reporting. Future goal generation may play a role in the aetiology of comorbidity of mental health and substance use problems, and therapeutic targeting of goal generation might benefit both conditions.Alcohol Change UKMedical Research Council (MRC

Cancer patients enrolled in a smoking cessation clinical trial: characteristics and correlates of smoking rate and nicotine dependence

This is the final version. Available on open access from Hindawi Publishing Corporation via the DOI in this recordIntroduction: A substantial proportion of cancer patients continue to smoke after their diagnosis but relatively few studies have evaluated correlates of nicotine dependence and smoking rate in this population, which could help guide smoking cessation interventions. Aim: This study evaluated correlates of smoking rate and nicotine dependence in a sample of 207 cancer patients. Methods: A cross-sectional analysis using multiple linear regression evaluated disease, demographic, affective, and tobacco-seeking correlates of smoking rate and nicotine dependence. Smoking rate was assessed using a timeline follow-back assessment of cigarettes smoked per day. The Fagerström Test for Nicotine Dependence measured levels of nicotine dependence. Results: The primary analysis, using multiple linear regression predicting nicotine dependence, showed an association with smoking to alleviate a sense of addiction from the Reasons for Smoking Scale and tobacco-seeking behavior from the Concurrent Choice Task (p < .05), but not with affect measured by the HADS and PANAS (p > .05). Multiple linear regression predicting smoking rates prior to pre-quit visit also showed an association with smoking to alleviate addiction (p < .05). ANOVA showed that Caucasian participants reported greater rates of smoking compared to other reported races. Conclusions: The results suggest that behavioral smoking cessation interventions that focus on helping patients to manage tobacco-seeking behavior, rather than mood management interventions, could help cancer patients to quit smoking, as this data could be used to help tailor treatments for this population

Approximate analytical solution of the Boussinesq equation

A new approximate solution of the one-dimensional Boussinesq equation is presented for a semi-infinite aquifer when the hydraulic head at the source is an arbitrary function of time. Estimates for recharge, discharge, and elevation of the water table are given. The simplicity and accuracy of the approximation are compared with 'exact' numerical and analytical solutions. The method of solution is illustrated with several examples including the commonly treated case of a constant boundary head and a nonmonotonically varying boundary head

Alternative job search strategies in remote rural and peri-urban labour markets: the role of social networks

This paper examines the importance of informal methods (especially social networking) to the job search strategies used by unemployed people. It compares three areas: a small rural town; a larger, more sparsely populated, remote rural area; and a centrally-located, peri-urban labour market. The analysis is based first on survey research undertaken with 490 job seekers across the study areas. Emerging issues were then followed up during a series of twelve focus groups. The survey research showed that job seekers in the rural study areas were significantly more likely to use social networks to look for work. However, those who had experienced repeated or long-term periods out of work, the unskilled and young people were significantly less likely to use such networks. Focus groups confirmed the perceived importance of social networking to the job search process in rural areas, in contrast to the more marginal role such methods appear to play in peri-urban settings. For many rural job seekers, formal job search activities conducted through Jobcentres were seen as largely symbolic, lacking the practical value of social networking. These results suggest that service providers seeking to assist unemployed people in rural areas need to address the problems faced by many disadvantaged job seekers who are currently caught between their lack of social network relations and the absence of local public employment service facilities in more remote communities

Fit for purpose? Pattern cutting and seams in wearables development

This paper describes how a group of practitioners and researchers are working across disciplines at Nottingham Trent University in the area of Technical Textiles. It introduces strands of ongoing enquiry centred around the development and application of stretch sensors on the body, focusing on how textile and fashion knowledge are being reflexively revealed in the collaborative development of seamful wearable concepts, and on the tensions between design philosophies as revealed by definitions of purpose. We discuss the current research direction of the Aeolia project, which seeks to exploit the literal gaps found in pattern cutting for fitted stretch garments towards experiential forms and potential interactions. Normative goals of fitness for purpose and seamlessness are interrogated and the potential for more integrated design processes, which may at first appear ‘upside down’, is discussed

Copper-doped CdSe/ZnS quantum dots : controllable photoactivated copper(I) cation storage and release vectors for catalysis

The first photoactivated doped quantum dot vector for metal-ion release has been developed. A facile method for doping copper(I) cations within ZnS quantum dot shells was achieved through the use of metal-dithiocarbamates, with Cu(+) ions elucidated by X-ray photoelectron spectroscopy. Photoexcitation of the quantum dots has been shown to release Cu(+) ions, which was employed as an effective catalyst for the Huisgen [3+2] cycloaddition reaction. The relationship between the extent of doping, catalytic activity, and the fluorescence quenching was also explored