Microwave-assisted extraction of lycopene in tomato peels: effect of extraction conditions on all-trans and cis- isomer yields

Lycopene is the primary carotenoid in tomato peels, a processing byproduct, and can be used as a natural color or bioactive ingredient. Unfortunately, extractions are inefficient as lycopene is extremely nonpolar and susceptible to degradation. As a rapid technique, microwave-assisted extraction (MAE) potentially offers efficient lycopene recovery. Thus, the objectives of this research were to: 1) optimize MAE of lycopene from tomato peels and 2) evaluate the effect of treatment on all-trans and isomer yields. Response surface methodology (RSM) was employed to optimize lycopene extraction with solvent ratio solid-liquid ratios, microwave power, and delivered energy equivalents as factors. High performance liquid chromatography with a diode array detector (HPLC-DAD) was used for isomer separation and quantification. Optimum MAE conditions were determined as: 0:10 solvent ratio at 400 W with a yield of 13.592 mg/100 g of extracted all-trans-lycopene. RSM suggested that ethyl acetate was a better MAE solvent for lycopene recovery as compared to hexane, which overall extracted less lycopene. HPLC-DAD indicated that MAE significantly improved all-trans and total lycopene yields, while conventional extraction demonstrated higher proportions of cis-isomer yields. Additionally, electron micrographs showed that significant structural disruption occurred in MAE-treated samples, possibly allowing for the improved lycopene extraction

Homogeneous Fermion Superfluid with Unequal Spin Populations

For decades, the conventional view is that an s-wave BCS superfluid can not support uniform spin polarization due to a gap $\Delta$ in the quasiparticle excitation spectrum. We show that this is an artifact of the dismissal of quasiparticle interactions $V_{qp}^{}$ in the conventional approach at the outset. Such interactions can cause triplet fluctuations in the ground state and hence non-zero spin polarization at "magnetic field" $h<\Delta$. The resulting ground state is a pairing state of quasiparticles on the ``BCS vacuum". For sufficiently large $V_{qp}$, the spin polarization of at unitarity has the simple form $m\propto \mu^{1/2}$. Our study is motivated by the recent experiments at Rice which found evidence of a homogenous superfluid state with uniform spin polarization.Comment: 4 pages, 3 figure

Thermal Conductivity of Isotopically Enriched 28Si Revisited

The thermal conductivity of isotopically enriched 28Si (enrichment better than 99.9%) was redetermined independently in three laboratories by high precision experiments on a total of 4 samples of different shape and degree of isotope enrichment in the range from 5 to 300 K with particular emphasis on the range near room temperature. The results obtained in the different laboratories are in good agreement with each other. They indicate that at room temperature the thermal conductivity of isotopically enriched 28Si exceeds the thermal conductivity of Si with a natural, unmodified isotope mixture by 10&#61617;2 %. This finding is in disagreement with an earlier report by Ruf et al. At &#61566;26 K the thermal conductivity of 28Si reaches a maximum. The maximum value depends on sample shape and the degree of isotope enrichment and exceeds the thermal conductivity of natural Si by a factor of &#61566;8 for a 99.982% 28Si enriched sample. The thermal conductivity of Si with natural isotope composition is consistently found to be &#61566;3% lower than the values recommended in the literature

Insulator-Superfluid transition of spin-1 bosons in an optical lattice in magnetic field

We study the insulator-superfluid transition of spin-1 bosons in an optical lattice in a uniform magnetic field. Based on a mean-field approximation we obtained a zero-temperature phase diagram. We found that depending on the particle number the transition for bosons with antiferromagnetic interaction may occur into different superfluid phases with spins aligned along or opposite to the field direction. This is qualitatively different from the field-free transition for which the mean-field theory predicts a unique (polar) superfluid state for any particle number.Comment: 10 pages, 2 eps figure

The role of atmospheric CO2 in controlling sea surface temperature change during the Pliocene

We present the role of CO2 forcing in controlling Late Pliocene sea surface temperature (SST) change using six models from Phase 2 of the Pliocene Model Intercomparison Project (PlioMIP2) and palaeoclimate proxy data from the PlioVAR working group. At a global scale, SST change in the Late Pliocene relative to the pre-industrial is predominantly driven by CO2 forcing in the low and mid-latitudes and non-CO2 forcing in the high latitudes. We find that CO2 is the dominant driver of SST change at the vast majority of proxy data sites assessed (17 out of 19), but the relative dominance of this forcing varies between all proxy sites, with CO2 forcing accounting for between 27 % and 82 % of the total change seen. The dearth of proxy data sites in the high latitudes means that only two sites assessed here are predominantly forced by non-CO2 forcing (such as changes to ice sheets and orography), both of which are in the North Atlantic Ocean. We extend the analysis to show the seasonal patterns of SST change and its drivers at a global scale and at a site-specific level for three chosen proxy data sites. We also present a new estimate of Late Pliocene climate sensitivity using site-specific proxy data values. This is the first assessment of site-specific drivers of SST change in the Late Pliocene and highlights the strengths of using palaeoclimate proxy data alongside model outputs to further develop our understanding of the Late Pliocene. We use the best available proxy and model data, but the sample sizes remain limited, and the confidence in our results would be improved with greater data availability

Structure and dynamics of Rh surfaces

Lattice relaxations, surface phonon spectra, surface energies, and work functions are calculated for Rh(100) and Rh(110) surfaces using density-functional theory and the full-potential linearized augmented plane wave method. Both, the local-density approximation and the generalized gradient approximation to the exchange-correlation functional are considered. The force constants are obtained from the directly calculated atomic forces, and the temperature dependence of the surface relaxation is evaluated by minimizing the free energy of the system. The anharmonicity of the atomic vibrations is taken into account within the quasiharmonic approximation. The importance of contributions from different phonons to the surface relaxation is analyzed.Comment: 9 pages, 7 figures, scheduled to appear in Phys. Rev. B, Feb. 15 (1998). Other related publications can be found at http://www.rz-berlin.mpg.de/th/paper.htm

Anisotropic Transport of Quantum Hall Meron-Pair Excitations

Double-layer quantum Hall systems at total filling factor $\nu_T=1$ can exhibit a commensurate-incommensurate phase transition driven by a magnetic field $B_{\parallel}$ oriented parallel to the layers. Within the commensurate phase, the lowest charge excitations are believed to be linearly-confined Meron pairs, which are energetically favored to align with $B_{\parallel}$. In order to investigate this interesting object, we propose a gated double-layer Hall bar experiment in which $B_{\parallel}$ can be rotated with respect to the direction of a constriction. We demonstrate the strong angle-dependent transport due to the anisotropic nature of linearly-confined Meron pairs and discuss how it would be manifested in experiment.Comment: 4 pages, RevTex, 3 postscript figure