11,600 research outputs found
Synthesis of a Se0/Calcite Composite Using Hydrothermal Carbonation of Ca(OH)2 Coupled to a Complex Selenocystine Fragmentation
International audienceElemental selenium (Se0)/calcite composites were synthesized in a batch system by hydrothermal carbonation of calcium hydroxide under high CO2−Ar pressure (90 bar) and high temperature (90 °C) coupled to a complex selenocystine fragmentation. Under O2-poor conditions, the composite consisted predominantly of spherical, amorphous nanoparticles of elemental red selenium (<500 nm) deposited on the calcite matrix. Conversely, under O2-rich conditions, the composite consisted rod-shaped, well-crystallized microparticles of elemental gray selenium (<25 µm) dispersed in the calcite matrix. The carbonate matrix was constituted by nano- to microrhombohedral crystals (<2 µm) and micrometric agglomerates and/or aggregates (<5 µm). Our results present a new synthesis path to Se0/calcite composites, with spherical or rod-shaped Se0 morphology with high potential for medical (e.g., dietary supplement) or industrial (e.g., pigments) applications. Furthermore, this study may have implications in the field of biomineralization
Extreme pressure behaviour of newly formulated oil-in-water emulsions
Oil-in-water (O/W) emulsions are broadly used in metal-machining processes, where combined lubrication and refrigeration are needed, such as in cutting, rolling, or grinding. These fluids consist of tiny oil droplets in water stabilised by small amounts of emulsifiers, namely surfactants. In an emulsion, oil is responsible for the lubricating properties, whereas water provides heat dissipation and fire resistance. Normally, emulsifiable metalworking oils are used in an oil concentration between 2 and 5 vol. %, depending on the application. Despite their wide use, the lubrication mechanisms of o/w emulsions have not been fully understood, mainly because of their complexity. Previous studies on oil-in-water emulsions showed that, in order to form thick lubricant films, oil droplets must wet the metal surfaces, displacing water. The ability of oil to wet is strongly dependent on the concentration of surfactant. Surfactant molecules tend to adsorb preferentially at the interface, modifying the nature of the layers adjacent to the metal surfaces and, thus, playing a key role in processes such as wettability, corrosion, or friction, as well as emulsion stability. The aim of this work is to study the influence of concentration of two different emulsifiers (anionic and non-inonic) on the wettability and extreme pressure properties of an oil-in-water emulsion. A mixture of a synthetic polyalphaolefin and a trimethylol propane ester was used as the base oil, and the concentrations of emulsifiers were below, equal to, and above their critical micellar concentrations (CMC). Extreme pressure tests (ASTM D 2783), which try to simulate the operating conditions of high speeds and pressures taking place in cutting processes, and contact angle measurements were carried out in order to establish a relationship between both properties and to evaluate the performance of these emulsions as lubricants
Detection of Replay Attacks to GNSS based on Partial Correlations and Authentication Data Unpredictability
Intentional interference, and in particular GNSS spoofing, is currently one
of the most significant concerns of the Positioning, Navigation and Timing
(PNT) community. With the adoption of Open Service Navigation Message
Authentication (OSNMA) in Galileo, the E1B signal component will continuously
broadcast unpredictable cryptographic data. This allows GNSS receivers not only
to ensure the authenticity of data origin but also to detect replay spoofing
attacks for receivers already tracking real signals with relatively good
visibility conditions. Since the spoofer needs to estimate the unpredictable
bits introduced by OSNMA with almost zero delay in order to perform a Security
Code Estimation and Replay (SCER) attack, the spoofer unavoidably introduces a
slight distortion into the signal, which can be the basis of a spoofing
detector. In this work, we propose five detectors based on partial correlations
of GNSS signals obtained over predictable and unpredictable parts of the
signals. We evaluate them in a wide set of test cases, including different
types of receiver and spoofing conditions. The results show that one of the
detectors is consistently superior to the others, and it is able to detect SCER
attacks with a high probability even in favorable conditions for the spoofer.
Finally, we discuss some practical considerations for implementing the proposed
detector in receivers, in particular when the Galileo OSNMA message structure
is used
EURONU WP6 2009 yearly report: Update of the physics potential of Nufact, superbeams and betabeams
Many studies in the last ten years have shown that we can measure the unknown
angle theta13, discover leptonic CP violation and determine the neutrino
hierarchy in more precise neutrino oscillation experiments, searching for the
subleading channel nue -> numu in the atmospheric range. In this first report
of WP6 activities the following new results are reviewed: (1) Re-evaluation of
the physics reach of the upcoming generation of experiments to measure theta13
and delta; (2) New tools to explore a larger parameter space as needed beyond
the standard scenario; (3) Neutrino Factory: (a) evaluation of the physics
reach of a Nufact regards sterile neutrinos; (b) evaluation of the physics
reach of a Nufact as regards non-standard interactions; (c) evaluation of the
physics reach of a Nufact as regards violation of unitarity; (d) critical
assessment on long baseline tau-detection at Nufact; (e) new physics searches
at a near detector in a Nufact; (4) Beta-beams: (a) choice of ions and location
for a gamma = 100 CERN-based beta-beam; (b) re-evaluation of atmospheric
neutrino background for the gamma = 100 beta-beam scenario; (c) study of a two
baseline beta-beam; (d) measuring absolute neutrino mass with beta-beams; (e)
progress on monochromatic beta-beams; (5) Update of the physics potential of
the SPL super-beam. Eventually, we present an updated comparison of the
sensitivity to theta13, delta and the neutrino mass hierarchy of several of the
different proposed facilities.Comment: 2009 Yearly report of the Working Package 6 (Physics) of the EUROnu
FP7 EU project. 55 pages, 21 figures
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