228 research outputs found
Vibrational spectra and structures of neutral Si6X clusters (X = Be, B, C, N, O)
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Neutral silicon clusters doped with first row elements (Si6X) have been generated (X = B, C, N, O) and characterized by infrared–ultraviolet (IR–UV) two-photon resonance-enhanced ionization spectroscopy (X = C, O) and quantum chemical calculations (X = Be, B, C, N, O, Si). In the near threshold UV photoionization, the ion signal of specific cluster sizes can be significantly enhanced by resonant excitation with tunable IR light prior to UV irradiation, allowing for the measurement of the IR spectra of Si7, Si6C, and Si6O clusters. Structural assignments are achieved with the help of a global optimization procedure using density functional theory (DFT). The most stable calculated structures show the best agreement between predicted and measured spectra. The dopant atoms in the Si6X clusters have a negative net charge and the Si atoms act as electron donors within the clusters. Moreover, the overall structures of the Si6X clusters depend strongly on the nature of the dopant atom, i.e., its size and valency. While in some of the Si6X clusters one Si atom in Si7 is simply substituted by the dopant atom (X = Be, B, C), other cases exhibit a completely different geometry (X = N, O). As a general trend, doping of the Si7 cluster with first-row dopants is predicted to shift the optically allowed electronic transitions into the visible or even near-IR spectral range due to symmetry reduction or the radical character of the doped cluster.DFG, FOR 1282, Controlling the electronic structure of semiconductor nanoparticles by doping and hybrid formatio
On the gamma-ray emission from the core of the Sagittarius dwarf galaxy
We use data from the Large Area Telescope onboard the Fermi gamma-ray space
telescope (Fermi-LAT) to analyze the faint gamma-ray source located at the
center of the Sagittarius (Sgr) dwarf spheroidal galaxy. In the 4FGL-DR3
catalog, this source is associated with the globular cluster, M54, which is
coincident with the dynamical center of this dwarf galaxy. We investigate the
spectral energy distribution and spatial extension of this source, with the
goal of testing two hypotheses: (1) the emission is due to millisecond pulsars
within M54, or (2) the emission is due to annihilating dark matter from the Sgr
halo. For the pulsar interpretation, we consider a two-component model which
describes both the lower-energy magnetospheric emission and possible
high-energy emission arising from inverse Compton scattering. We find that this
source has a point-like morphology at low energies, consistent with
magnetospheric emission, and find no evidence for a higher-energy component.
For the dark matter interpretation, we find that this signal favors a dark
matter mass of GeV and an annihilation cross section
of s for the channel (or GeV and s for the channel), when
adopting a J-factor of . This
parameter space is consistent with gamma-ray constraints from other dwarf
galaxies and with dark matter interpretations of the Galactic Center Gamma-Ray
Excess.Comment: 12 pages, 9 figures. To be submitted to MNRAS -- comments welcom
The real-world problem of care coordination: a longitudinal qualitative study with patients living with advanced progressive illness and their unpaid caregivers.
OBJECTIVES: To develop a model of care coordination for patients living with advanced progressive illness and their unpaid caregivers, and to understand their perspective regarding care coordination. DESIGN: A prospective longitudinal, multi-perspective qualitative study involving a case-study approach. METHODS: Serial in-depth interviews were conducted, transcribed verbatim and then analyzed through open and axial coding in order to construct categories for three cases (sites). This was followed by continued thematic analysis to identify underlying conceptual coherence across all cases in order to produce one coherent care coordination model. PARTICIPANTS: Fifty-six purposively sampled patients and 27 case-linked unpaid caregivers. SETTINGS: Three cases from contrasting primary, secondary and tertiary settings within Britain. RESULTS: Coordination is a deliberate cross-cutting action that involves high-quality, caring and well-informed staff, patients and unpaid caregivers who must work in partnership together across health and social care settings. For coordination to occur, it must be adequately resourced with efficient systems and services that communicate. Patients and unpaid caregivers contribute substantially to the coordination of their care, which is sometimes volunteered at a personal cost to them. Coordination is facilitated through flexible and patient-centered care, characterized by accurate and timely information communicated in a way that considers patients' and caregivers' needs, preferences, circumstances and abilities. CONCLUSIONS: Within the midst of advanced progressive illness, coordination is a shared and complex intervention involving relational, structural and information components. Our study is one of the first to extensively examine patients' and caregivers' views about coordination, thus aiding conceptual fidelity. These findings can be used to help avoid oversimplifying a real-world problem, such as care coordination. Avoiding oversimplification can help with the development, evaluation and implementation of real-world coordination interventions for patients and their unpaid caregivers in the future
People of the British Isles: preliminary analysis of genotypes and surnames in a UK control population
There is a great deal of interest in fine scale population structure in the UK, both as a signature of historical immigration events and because of the effect population structure may have on disease association studies. Although population structure appears to have a minor impact on the current generation of genome-wide association studies, it is likely to play a significant part in the next generation of studies designed to search for rare variants. A powerful way of detecting such structure is to control and document carefully the provenance of the samples involved. Here we describe the collection of a cohort of rural UK samples (The People of the British Isles), aimed at providing a well-characterised UK control population that can be used as a resource by the research community as well as
providing fine scale genetic information on the British population. So far, some 4,000 samples have been collected, the majority of which fit the criteria of coming from a rural area and having all four grandparents from approximately the same area. Analysis of the first 3,865 samples that have been geocoded indicates that 75% have
a mean distance between grandparental places of birth of 37.3km, and that about 70% of grandparental places of birth can be classed as rural. Preliminary genotyping of 1,057
samples demonstrates the value of these samples for investigating fine scale population structure within the UK, and shows how this can be enhanced by the use of surnames
MAMBO 1.2mm observations of luminous starbursts at z~2 in the SWIRE fields
We report on--off pointed MAMBO observations at 1.2 mm of 61 Spitzer-selected
star-forming galaxies from the SWIRE survey. The sources are selected on the
basis of bright 24um fluxes (f_24um>0.4mJy) and of stellar dominated
near-infrared spectral energy distributions in order to favor z~2 starburst
galaxies. The average 1.2mm flux for the whole sample is 1.5+/-0.2 mJy. Our
analysis focuses on 29 sources in the Lockman Hole field where the average
1.2mm flux (1.9+/-0.3 mJy) is higher than in other fields (1.1+/-0.2 mJy). The
analysis of the sources multi-wavelength spectral energy distributions
indicates that they are starburst galaxies with far-infrared luminosities
~10^12-10^13.3 Lsun, and stellar masses of ~0.2-6 x10^11 M_sun. Compared to
sub-millimeter selected galaxies (SMGs), the SWIRE-MAMBO sources are among
those with the largest 24um/millimeter flux ratios. The origin of such large
ratios is investigated by comparing the average mid-infrared spectra and the
stacked far-infrared spectral energy distributions of the SWIRE-MAMBO sources
and of SMGs. The mid-infrared spectra exhibit strong PAH features, and a warm
dust continuum. The warm dust continuum contributes to ~34% of the mid-infrared
emission, and is likely associated with an AGN component. This constribution is
consistent with what is found in SMGs. The large 24um/1.2mm flux ratios are
thus not due to AGN emission, but rather to enhanced PAH emission compared to
SMGs. The analysis of the stacked far-infrared fluxes yields warmer dust
temperatures than typically observed in SMGs. Our selection favors warm
ultra-luminous infrared sources at high-z, a class of objects that is rarely
found in SMG samples. Our sample is the largest Spitzer-selected sample
detected at millimeter wavelengths currently available.Comment: Accepted for publication in ApJ (51 pages; 16 figures). The quality
of some figures has been degraded for arXiv purposes. Full resolution version
available at this
http://www.iasf-milano.inaf.it/~polletta/mambo_swire/lonsdale08_ApJ_accepted.pd
Associations with photoreceptor thickness measures in the UK Biobank.
Spectral-domain OCT (SD-OCT) provides high resolution images enabling identification of individual retinal layers. We included 32,923 participants aged 40-69 years old from UK Biobank. Questionnaires, physical examination, and eye examination including SD-OCT imaging were performed. SD OCT measured photoreceptor layer thickness includes photoreceptor layer thickness: inner nuclear layer-retinal pigment epithelium (INL-RPE) and the specific sublayers of the photoreceptor: inner nuclear layer-external limiting membrane (INL-ELM); external limiting membrane-inner segment outer segment (ELM-ISOS); and inner segment outer segment-retinal pigment epithelium (ISOS-RPE). In multivariate regression models, the total average INL-RPE was observed to be thinner in older aged, females, Black ethnicity, smokers, participants with higher systolic blood pressure, more negative refractive error, lower IOPcc and lower corneal hysteresis. The overall INL-ELM, ELM-ISOS and ISOS-RPE thickness was significantly associated with sex and race. Total average of INL-ELM thickness was additionally associated with age and refractive error, while ELM-ISOS was additionally associated with age, smoking status, SBP and refractive error; and ISOS-RPE was additionally associated with smoking status, IOPcc and corneal hysteresis. Hence, we found novel associations of ethnicity, smoking, systolic blood pressure, refraction, IOPcc and corneal hysteresis with photoreceptor thickness
The Multi-Object, Fiber-Fed Spectrographs for SDSS and the Baryon Oscillation Spectroscopic Survey
We present the design and performance of the multi-object fiber spectrographs
for the Sloan Digital Sky Survey (SDSS) and their upgrade for the Baryon
Oscillation Spectroscopic Survey (BOSS). Originally commissioned in Fall 1999
on the 2.5-m aperture Sloan Telescope at Apache Point Observatory, the
spectrographs produced more than 1.5 million spectra for the SDSS and SDSS-II
surveys, enabling a wide variety of Galactic and extra-galactic science
including the first observation of baryon acoustic oscillations in 2005. The
spectrographs were upgraded in 2009 and are currently in use for BOSS, the
flagship survey of the third-generation SDSS-III project. BOSS will measure
redshifts of 1.35 million massive galaxies to redshift 0.7 and Lyman-alpha
absorption of 160,000 high redshift quasars over 10,000 square degrees of sky,
making percent level measurements of the absolute cosmic distance scale of the
Universe and placing tight constraints on the equation of state of dark energy.
The twin multi-object fiber spectrographs utilize a simple optical layout
with reflective collimators, gratings, all-refractive cameras, and
state-of-the-art CCD detectors to produce hundreds of spectra simultaneously in
two channels over a bandpass covering the near ultraviolet to the near
infrared, with a resolving power R = \lambda/FWHM ~ 2000. Building on proven
heritage, the spectrographs were upgraded for BOSS with volume-phase
holographic gratings and modern CCD detectors, improving the peak throughput by
nearly a factor of two, extending the bandpass to cover 360 < \lambda < 1000
nm, and increasing the number of fibers from 640 to 1000 per exposure. In this
paper we describe the original SDSS spectrograph design and the upgrades
implemented for BOSS, and document the predicted and measured performances.Comment: 43 pages, 42 figures, revised according to referee report and
accepted by AJ. Provides background for the instrument responsible for SDSS
and BOSS spectra. 4th in a series of survey technical papers released in
Summer 2012, including arXiv:1207.7137 (DR9), arXiv:1207.7326 (Spectral
Classification), and arXiv:1208.0022 (BOSS Overview
The HST Key Project on the Extragalactic Distance Scale XIV. The Cepheids in NGC 1365
We report the detection of Cepheid variable stars in the barred spiral galaxy
NGC 1365, located in the Fornax cluster, using the Hubble Space Telescope Wide
Field and Planetary Camera 2. Twelve V (F555W) and four I (F814W) epochs of
observation were obtained. The two photometry packages, ALLFRAME and DoPHOT,
were separately used to obtain profile-fitting photometry of all the stars in
the HST field. The search for Cepheid variable stars resulted in a sample of 52
variables, with periods between 14 and 60 days, in common with both datasets.
ALLFRAME photometry and light curves of the Cepheids are presented. A subset of
34 Cepheids were selected on the basis of period, light curve shape, similar
ALLFRAME and DoPHOT periods, color, and relative crowding, to fit the Cepheid
period-luminosity relations in V and I for both ALLFRAME and DoPHOT. The
measured distance modulus to NGC 1365 from the ALLFRAME photometry is 31.31 +/-
0.20 (random) +/- 0.18 (systematic) mag, corresponding to a distance of 18.3
+/- 1.7 (random) +/- 1.6 (systematic) Mpc. The reddening is measured to be
E(V-I) = 0.16 +/- 0.08 mag. These values are in excellent agreement with those
obtained using the DoPHOT photometry, namely a distance modulus of 31.26 +/-
0.10 mag, and a reddening of 0.15 +/- 0.10 mag (internal errors only).Comment: 48 pages, 8 tables, 8 figures, to appear in Ap
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