242 research outputs found
Magnetic and microwave properties of (Ni,Co)Fe2O4-ferroelectric and (La,Ca,Sr)MnO3-ferroelectric multilayer structures
Structural, magnetic and ferromagnetic resonance characterization studies
have been performed on lay-ered ferromagnetic-ferroelectric oxides that show
strong magnetoelectric coupling. The samples contained thick films of ferrites
or substituted lanthanum manganites for the ferromagnetic phase and lead
zirconate titanate for the ferroelectric phase, and were sintered high
temperatures. Results indicate defect free ferrites, but deterioration of
manganite parameters due to diffusion at the interface and accounts for poor
magnetoelectric coupling in manganite-PZT samples
Thickness dependence of the stability of the charge-ordered state in PrCaMnO thin films
Thin films of the charge-ordered (CO) compound PrCaMnO
have been deposited onto (100)-oriented SrTiO substrates using the Pulsed
Laser Deposition technique. Magnetization and transport properties are measured
when the thickness of the film is varied. While the thinner films do not
exhibit any temperature induced insulator-metal transition under an applied
magnetic field up to 9T, for thickness larger than 1100\UNICODE{0xc5} a 5T
magnetic field is sufficient to melt the CO state. For this latest film, we
have measured the temperature-field phase diagram. Compared to the bulk
material, it indicates that the robustness of the CO state in thin films is
strongly depending on the strains and the thickness. We proposed an explanation
based on the distortion of the cell of the film.Comment: 9 pages, 6 figures, submitted to Phys. Rev.
Effect of Strain Relaxation on Magnetotransport properties of epitaxial La_0.7Ca_0.3MnO_3 films
In this paper, we have studied the effect of strain relaxation on
magneto-transport properties of La_0.7Ca_0.3MnO_3 epitaxial films (200 nm
thick), which were deposited by pulsed laser deposition technique under
identical conditions. All the films are epitaxial and have cubic unit cell. The
amount of strain relaxation has been varied by taking three different single
crystal substrates of SrTiO_3, LaAlO_3 and MgO. It has been found that for
thicker films the strain gets relaxed and produces variable amount of disorder
depending on the strength of strain relaxation. The magnitude of lattice
relaxation has been found to be 0.384, 3.057 and 6.411 percent for film
deposited on SrTiO_3, LaAlO_3 and MgO respectively. The films on LaAlO_3 and
SrTiO_3 show higher T_{IM} of 243 K and 217 K respectively as compared to
T_{IM} of 191 K for the film on MgO. Similarly T_C of the films on SrTiO_3 and
LaAlO_3 is sharper and has value of 245 K and 220 K respectively whereas the TC
of the film on MgO is 175 K. Higher degree of relaxation creates more defects
and hence TIM (T_C) of the film on MgO is significantly lower than of SrTiO_3
and LaAlO_3. We have adopted a different approach to correlate the effect of
strain relaxation on magneto-transport properties of LCMO films by evaluating
the resistivity variation through Mott's VRH model. The variable presence of
disorder in these thick films due to lattice relaxation which have been
analyzed through Mott's VRH model provides a strong additional evidence that
the strength of lattice relaxation produces disorder dominantly by increase in
density of defects such as stacking faults, dislocations, etc. which affect the
magneto-transport properties of thick epitaxial La_0.7Ca_0.3MnO_3 films
Molecular Microfluidic Bioanalysis: Recent Progress in Preconcentration, Separation, and Detection
This chapter reviews the state-of-art of microfluidic devices for molecular bioanalysis with a focus on the key functionalities that have to be successfully integrated, such as preconcentration, separation, signal amplification, and detection. The first part focuses on both passive and electrophoretic separation/sorting methods, whereas the second part is devoted to miniaturized biosensors that are integrated in the last stage of the fluidic device
Overview of Materials for Microfluidic Applications
For each material dedicated to microfluidic applications, inherent microfabrication and specific physico‐chemical properties are key concerns and play a dominating role in further microfluidic operability. From the first generation of inorganic glass, silicon and ceramics microfluidic devices materials, to diversely competitive polymers alternatives such as soft and rigid thermoset and thermoplastics materials, to finally various paper, biodegradable and hydrogel materials; this chapter will review their advantages and drawbacks regarding their microfabrication perspectives at both research and industrial scale. The chapter will also address, the evolution of the materials used for fabricating microfluidic chips, and will discuss the application‐oriented pros and cons regarding especially their critical strategies and properties for devices assembly and biocompatibility, as well their potential for downstream biochemical surface modification are presented
Room temperature magnetic entropy change and magnetoresistance in La_{0.70}(Ca_{0.30-x}Sr_x)MnO_3:Ag 10% (x = 0.0-0.10)
The magnetic and magnetocaloric properties of polycrystalline
La0.70(Ca0.30-xSrx)MnO3:Ag 10% manganite have been investigated. All the
compositions are crystallized in single phase orthorhombic Pbnm space group.
Both, the Insulator-Metal transition temperature (TIM) and Curie temperature
(Tc) are observed at 298 K for x = 0.10 composition. Though both TIM and Tc are
nearly unchanged with Ag addition, the MR is slightly improved. The MR at 300 K
is found to be as large as 31% with magnetic field change of 1Tesla, whereas it
reaches up to 49% at magnetic field of 3Tesla for La0.70Ca0.20Sr0.10MnO3:Ag0.10
sample. The maximum entropy change (\DeltaSMmax) is 7.6 J.Kg-1.K-1 upon the
magnetic field change of 5Tesla, near its Tc (300.5 K). The
La0.70Ca0.20Sr0.10MnO3:Ag0.10 sample having good MR (31%1Tesla, 49%3Tesla) and
reasonable change in magnetic entropy (7.6 J.Kg-1.K-1, 5 Tesla) at 300 K can be
a potential magnetic refrigerant material at ambient temperatures.Comment: 11 pages text + Figs comments/suggestions
([email protected]
Intricacies of Strain and Magnetic Field Induced Charge Order Melting in Pr0.5Ca0.5MnO3 Thin Films
Thin films of the half doped manganite Pr0.5Ca0.5MnO3 were grown on (100)
oriented MgO substrates by pulsed laser deposition technique. In order to study
the effect of strain on the magnetic field induced charge order melting, films
of different thicknesses were prepared and their properties were studied by
x-ray diffraction, electrical resistivity and magnetoresistance measurements. A
field induced charge order melting is observed for films with very small
thicknesses. The charge order transition temperature and the magnetic filed
induced charge order melting are observed to depend on the nature of strain
that is experienced by the film.Comment: 18 pages, (including 6 figures
Enhanced Room Temperature Coefficient of Resistance and Magneto-resistance of Ag-added La0.7Ca0.3-xBaxMnO3 Composites
In this paper we report an enhanced temperature coefficient of resistance
(TCR) close to room temperature in La0.7Ca0.3-xBaxMnO3 + Agy (x = 0.10, 0.15
and y = 0.0 to 0.40) (LCBMO+Ag) composite manganites. The observed enhancement
of TCR is attributed to the grain growth and opening of new conducting channels
in the composites. Ag addition has also been found to enhance intra-granular
magneto-resistance. Inter-granular MR, however, is seen to decrease with Ag
addition. The enhanced TCR and MR at / near room temperature open up the
possibility of the use of such materials as infrared bolometric and magnetic
field sensors respectively.Comment: 22 pages of Text +
Figs:comments/suggestions([email protected]
High magnetic field transport measurement of charge-ordered PrCaMnO strained thin films
We have investigated the magnetic-field-induced phase transition of
charge-ordered (CO) PrCaMnO thin films, deposited onto
(100)-oriented LaAlO and (100)-oriented SrTiO substrates using the
pulsed laser deposition technique, by measuring the transport properties with
magnetic fields up to 22T. The transition to a metallic state is observed on
both substrates by application of a critical magnetic field ( at 60K).
The value of the field required to destroy the charge-ordered insulating state,
lower than the bulk compound, depends on both the substrate and the thickness
of the film. The difference of the critical magnetic field between the films
and the bulk material is explained by the difference of in-plane parameters at
low temperature (below the CO transition). Finally, these results confirm that
the robustness of the CO state, depends mainly on the stress induced by the
difference in the thermal dilatations between the film and the substrate.Comment: 10 pages, 6 figures. To be published in Phys. Rev.
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