A Chemiluminescent Method for the Detection of H�O� and Glucose Based on Intrinsic Peroxidase-Like Activity of WS� Quantum Dots

Currently, researchers are looking for nanomaterials with peroxidase-like activity to replace natural peroxidase enzymes. For this purpose, WS� quantum dots (WS� QDs) were synthesized via a solvothermal method, which improved the mimetic behavior. The resulting WS� QDs with a size of 1�1.5 nm had a high fluorescence emission, dependent on the excitation wavelength. WS� QDs with uniform morphology showed a high catalytic effect in destroying H�O�. The peroxidase-like activity of synthesized nanostructures was studied in H�O� chemical and electrochemical reduction systems. The mimetic effect of WS� QDs was also shown in an H�O��rhodamine B (RB) chemiluminescence system. For this aim, a stopped-flow chemiluminescence (CL) detection system was applied. Also, in order to confirm the peroxidase-like effect of quantum dots, colorimetry and electrochemical techniques were used. In the enzymatic reaction of glucose, H�O� is one of the products which can be determined. Under optimum conditions, H�O� can be detected in the concentration range of 0�1000 nmol·L-1, with a detection limit of 2.4 nmol·L-1. Using this CL assay, a linear relationship was obtained between the intensity of the CL emission and glucose concentration in the range of 0.01�30 nmol·L-1, with a limit of detection (3S) of 4.2 nmol·L-1

A Chemiluminescent Method for the Detection of H₂O₂ and Glucose Based on Intrinsic Peroxidase-Like Activity of WS₂ Quantum Dots

Currently, researchers are looking for nanomaterials with peroxidase-like activity to replace natural peroxidase enzymes. For this purpose, WS2 quantum dots (WS2 QDs) were synthesized via a solvothermal method, which improved the mimetic behavior. The resulting WS2 QDs with a size of 1⁻1.5 nm had a high fluorescence emission, dependent on the excitation wavelength. WS2 QDs with uniform morphology showed a high catalytic effect in destroying H2O2. The peroxidase-like activity of synthesized nanostructures was studied in H2O2 chemical and electrochemical reduction systems. The mimetic effect of WS2 QDs was also shown in an H2O2⁻rhodamine B (RB) chemiluminescence system. For this aim, a stopped-flow chemiluminescence (CL) detection system was applied. Also, in order to confirm the peroxidase-like effect of quantum dots, colorimetry and electrochemical techniques were used. In the enzymatic reaction of glucose, H2O2 is one of the products which can be determined. Under optimum conditions, H2O2 can be detected in the concentration range of 0⁻1000 nmol·L−1, with a detection limit of 2.4 nmol·L−1. Using this CL assay, a linear relationship was obtained between the intensity of the CL emission and glucose concentration in the range of 0.01⁻30 nmol·L−1, with a limit of detection (3S) of 4.2 nmol·L−1

Fabrication of Ti₂SnC-MAX Phase Blended PES Membranes with Improved Hydrophilicity and Antifouling Properties for Oil/Water Separation

In this research work, the Ti2SnC MAX phase (MP) was synthesized via the reactive sintering procedure. The layered and crystalline structure of this MP was verified by SEM, HRTEM, and XRD analyses. This nano-additive was used for improvement of different features of the polyethersulfone (PES) polymeric membranes. The blended membranes containing diverse quantities of the MP (0–1 wt%) were fabricated by a non-solvent-induced phase inversion method. The asymmetric structure of the membranes with small holes in the top layer and coarse finger-like holes and macro-voids in the sublayer was observed by applying SEM analysis. The improvement of the membrane’s hydrophilicity was verified via reducing the contact angle of the membranes from 63.38° to 49.77° (for bare and optimum membranes, respectively). Additionally, in the presence of 0.5 wt% MP, the pure water flux increased from 286 h to 355 L/m2 h. The average roughness of this membrane increased in comparison with the bare membrane, which shows the increase in the filtration-available area. The high separation efficiency of the oil/water emulsion (80%) with an improved flux recovery ratio of 65% was illustrated by the optimum blended membrane