Magmatic Cu-Ni-PGE-Au sulfide mineralisation in alkaline igneous systems: An example from the Sron Garbh intrusion, Tyndrum, Scotland

Magmatic sulfide deposits typically occur in ultramafic-mafic systems, however, mineralisation can occur in more intermediate and alkaline magmas. Sron Garbh is an appinite-diorite intrusion emplaced into Dalradian metasediments in the Tyndrum area of Scotland that hosts magmatic Cu-Ni-PGE-Au sulfide mineralisation in the appinitic portion. It is thus an example of magmatic sulfide mineralisation hosted by alkaline rocks, and is the most significantly mineralised appinitic intrusion known in the British Isles. The intrusion is irregularly shaped, with an appinite rim, comprising amphibole cumulates classed as vogesites. The central portion of the intrusion is comprised of unmineralised, but pyrite-bearing, diorites. Both appinites and diorites have similar trace element geochemistry that suggests the diorite is a more fractionated differentiate of the appinite from a common source that can be classed with the high Ba-Sr intrusions of the Scottish Caledonides. Mineralisation is present as a disseminated, primary chalcopyrite-pyrite-PGM assemblage and a blebby, pyrite-chalcopyrite assemblage with significant Co-As-rich pyrite. Both assemblages contain minor millerite and Ni-Co-As-sulfides. The mineralisation is Cu-, PPGE-, and Au-rich and IPGE-poor and the platinum group mineral assemblage is overwhelmingly dominated by Pd minerals; however, the bulk rock Pt/Pd ratio is around 0.8. Laser ablation analysis of the sulfides reveals that pyrite and the Ni-Co-sulfides are the primary host for Pt, which is present in solid solution in concentrations of up to 22 ppm in pyrite. Good correlations between all base and precious metals indicate very little hydrothermal remobilisation of metals despite some evidence of secondary pyrite and PGM. Sulfur isotope data indicate some crustal S in the magmatic sulfide assemblages. The source of this is unlikely to have been the local quartzites, but S-rich Dalradian sediments present at depth. The generation of magmatic Cu-Ni-PGE-Au mineralisation at Sron Garbh can be attributed to post-collisional slab drop off that allowed hydrous, low-degree partial melting to take place that produced a Cu-PPGE-Au-enriched melt, which ascended through the crust, assimilating crustal S from the Dalradian sediments. The presence of a number of PGE-enriched sulfide occurrences in appinitic intrusions across the Scottish Caledonides indicates that the region contains certain features that make it more prospective than other alkaline provinces worldwide, which may be linked the post-Caledonian slab drop off event. We propose that the incongruent melting of pre-existing magmatic sulfides or ‘refertilised’ mantle in low-degree partial melts can produce characteristically fractionated, Cu-PPGE-Au-semi metal bearing, hydrous, alkali melts, which, if they undergo sulfide saturation, have the potential to produce alkaline-hosted magmatic sulfide deposits

Study of Neutron-Induced Ionization in Helium and Argon Chamber Gases

Ion chambers used to monitor the secondary hadron and tertiary muon beam in the NuMI neutrino beamline will be exposed to background particles, including low energy neutrons produced in the beam dump. To understand these backgrounds, we have studied Helium- and Argon-filled ionization chambers exposed to intense neutron fluxes from PuBe neutron sources ($E_n=1-10$ MeV). The sources emit about 10$^8$ neutrons per second. The number of ion pairs in the chamber gas volume per incident neutron is derived. While limited in precision because of a large gamma ray background from the PuBe sources, our results are consistent with the expectation that the neutrons interact purely elastically in the chamber gas.Comment: accepted for publication in NIM

First steps in the development of a water temperature model framework for refining the ecological Reserve in South African rivers

Ecological Reserve determination for rivers in South Africa presently does not include a water temperature component, in spite of its importance in determining species distribution patterns. To achieve this requires an understanding of how lotic thermographs from South African rivers differ from northern hemisphere rivers, to avoid mismanaging rivers based on incorrect regional assumptions. Hourly water temperatures from 20 sites in four river systems, representing a range of latitudes, altitudes and stream orders, were assessed using a range of metrics. These data were analysed using principal component analyses and multiple linear regressions to understand what variables a water temperature model for use in ecoregions within South Africa should include. While temperature data are generally lacking in low- and higher-order South African rivers, data suggest that South African rivers are warmer than northern hemisphere rivers. Water temperatures could be grouped into cool, warm and intermediate types. Based on temperature time series analyses, this paper argues that a suitable water-temperature model for use in ecological Reserve determinations should be dynamic, include flow and air temperature variables, and be adaptive through a heat exchange coefficient term. The inclusion of water temperature in the determination and management of river ecological Reserves would allow for more holistic application of the National Water Act’s ecological management provisions. Water temperature guidelines added to the ecological Reserve could be integrated into heuristic aquatic monitoring programmes within priority areas identified in regional conservation plans.Keywords: water temperatures, conservation planning, water temperature modelling, managemen

Time Evolution of Two-Level Systems Driven by Periodic Fields

In this paper we study the time evolution of a class of two-level systems driven by periodic fields in terms of new convergent perturbative expansions for the associated propagator U(t). The main virtue of these expansions is that they do not contain secular terms, leading to a very convenient method for quantitatively studying the long-time behaviour of that systems. We present a complete description of an algorithm to numerically compute the perturbative expansions. In particular, we applied the algorithm to study the case of an ac-dc field (monochromatic interaction), exploring various situations and showing results on (time-dependent) observable quantities, like transition probabilities. For a simple ac field, we analised particular situations where an approximate effect of dynamical localisation is exhibited by the driven system. The accuracy of our calculations was tested measuring the unitarity of the propagator U(t), resulting in very small deviations, even for very long times compared to the cycle of the driving field.Comment: 1 table, 5 figures. Version 2 contains minor correction

Quantum dynamics of crystals of molecular nanomagnets inside a resonant cavity

It is shown that crystals of molecular nanomagnets exhibit enhanced magnetic relaxation when placed inside a resonant cavity. Strong dependence of the magnetization curve on the geometry of the cavity has been observed, providing evidence of the coherent microwave radiation by the crystals. A similar dependence has been found for a crystal placed between Fabry-Perot superconducting mirrors. These observations open the possibility of building a nanomagnetic microwave laser pumped by the magnetic field

No Evidence Supporting Flare Driven High-Frequency Global Oscillations

The underlying physics that generates the excitations in the global low-frequency, < 5.3 mHz, solar acoustic power spectrum is a well known process that is attributed to solar convection; However, a definitive explanation as to what causes excitations in the high-frequency regime, > 5.3 mHz, has yet to be found. Karoff and Kjeldsen (Astrophys. J. 678, 73-76, 2008) concluded that there is a correlation between solar flares and the global high-frequency solar acoustic waves. We have used the Global Oscillations Network Group (GONG) helioseismic data in an attempt to verify Karoff and Kjeldsen (2008) results as well as compare the post-flare acoustic power spectrum to the pre-flare acoustic power spectrum for 31 solar flares. Among the 31 flares analyzed, we observe that a decrease in acoustic power after the solar flare is just as likely as an increase. Furthermore, while we do observe variations in acoustic power that are most likely associated with the usual p-modes associated with solar convection, these variations do not show any significant temporal association with flares. We find no evidence that consistently supports flare driven high-frequency waves.Comment: 20 pages, 9 figures, Accepted for publication in Solar Physic

Doping dependence of superconducting gap in YBa_2Cu_3O_y from universal heat transport

Thermal transport in the T -> 0 limit was measured as a function of doping in high-quality single crystals of the cuprate superconductor YBa_2Cu_3O_y. The residual linear term kappa_0/T is found to decrease as one moves from the overdoped regime towards the Mott insulator region of the phase diagram. The doping dependence of the low-energy quasiparticle gap extracted from kappa_0/T is seen to scale closely with that of the pseudogap, arguing against a non-superconducting origin for the pseudogap. The presence of a linear term for all dopings is evidence against the existence of a quantum phase transition to an order parameter with a complex (ix) component.Comment: 2 pages, 2 figures, submitted to M2S-Rio 2003 Proceeding

Asymmetric Lineshape due to Inhomogeneous Broadening of the Crystal-Field Transitions in Mn12ac Single Crystals

The lineshape of crystal-field transitions in single crystals of Mn12ac molecular magnets is determined by the magnetic history. The absorption lines are symmetric and Gaussian for the non-magnetized state obtained by zero-field cooling (zfc). In the magnetized state which is reached when the sample is cooled in a magnetic field (fc), however, they are asymmetric even in the absence of an external magnetic field. These observations are quantitatively explained by inhomogeneous symmetrical (Gaussian) broadening of the crystal-field transitions combined with a contribution of off-diagonal components of the magnetic susceptibility to the effective magnetic permeability.Comment: 4 pages, 3 figure