CO2 and steam electrolysis using a microtubular solid oxide cell

Nickel-yttria stabilized zirconia (Ni-YSZ) supported tubes were fabricated by plastic extrusion molding (PEM). YSZ was used as the electrolyte and LSM-YSZ (lanthanum-strontium doped manganite) as the oxygen electrode. Both layers were deposited by dip coating and were then sintered at 1500 degrees C and 1150 degrees C, respectively. Coelectrolysis experiments were performed in these cells at 850 degrees C, using different fuel gas conditions varying the amount of steam, carbon dioxide, nitrogen and hydrogen. Area specific resistance (ASR) values ranged from 0.47 Omega cm(2), when rich steam and CO2 flows are used, to 1.74 Omega cm(2), when a diluted composition is used. Gas chromatography was used to examine the amount of H-2 and CO in the output gas. The obtained results are consistent with the equilibrium of the water gas shift reaction. For all the different analysed conditions, faradaic efficiency was found to be close to 100%. This experiment confirmed that there is no electronic conduction taking place through the YSZ electrolyte. The threshold for electronic conduction in the diluted feeding conditions (Poor H2O and CO2) for these particular YSZ-based cell was found at voltages of about 1.65 V

The H=xp model revisited and the Riemann zeros

Berry and Keating conjectured that the classical Hamiltonian H = xp is related to the Riemann zeros. A regularization of this model yields semiclassical energies that behave, in average, as the non trivial zeros of the Riemann zeta function. However, the classical trajectories are not closed, rendering the model incomplete. In this paper, we show that the Hamiltonian H = x (p + l_p^2/p) contains closed periodic orbits, and that its spectrum coincides with the average Riemann zeros. This result is generalized to Dirichlet L-functions using different self-adjoint extensions of H. We discuss the relation of our work to Polya's fake zeta function and suggest an experimental realization in terms of the Landau model.Comment: 5 pages, 3 figure

Numerical stability of a new conformal-traceless 3+1 formulation of the Einstein equation

There is strong evidence indicating that the particular form used to recast the Einstein equation as a 3+1 set of evolution equations has a fundamental impact on the stability properties of numerical evolutions involving black holes and/or neutron stars. Presently, the longest lived evolutions have been obtained using a parametrized hyperbolic system developed by Kidder, Scheel and Teukolsky or a conformal-traceless system introduced by Baumgarte, Shapiro, Shibata and Nakamura. We present a new conformal-traceless system. While this new system has some elements in common with the Baumgarte-Shapiro-Shibata-Nakamura system, it differs in both the type of conformal transformations and how the non-linear terms involving the extrinsic curvature are handled. We show results from 3D numerical evolutions of a single, non-rotating black hole in which we demonstrate that this new system yields a significant improvement in the life-time of the simulations.Comment: 7 pages, 2 figure

Static Pairwise Annihilation in Complex Networks

We study static annihilation on complex networks, in which pairs of connected particles annihilate at a constant rate during time. Through a mean-field formalism, we compute the temporal evolution of the distribution of surviving sites with an arbitrary number of connections. This general formalism, which is exact for disordered networks, is applied to Kronecker, Erd\"os-R\'enyi (i.e. Poisson) and scale-free networks. We compare our theoretical results with extensive numerical simulations obtaining excellent agreement. Although the mean-field approach applies in an exact way neither to ordered lattices nor to small-world networks, it qualitatively describes the annihilation dynamics in such structures. Our results indicate that the higher the connectivity of a given network element, the faster it annihilates. This fact has dramatic consequences in scale-free networks, for which, once the ``hubs'' have been annihilated, the network disintegrates and only isolated sites are left.Comment: 7 Figures, 10 page

Defect formation and local gauge invariance

We propose a new mechanism for formation of topological defects in a U(1) model with a local gauge symmetry. This mechanism leads to definite predictions, which are qualitatively different from those of the Kibble-Zurek mechanism of global theories. We confirm these predictions in numerical simulations, and they can also be tested in superconductor experiments. We believe that the mechanism generalizes to more complicated theories.Comment: REVTeX, 4 pages, 2 figures. The explicit form of the Hamiltonian and the equations of motion added. To appear in PRL (http://prl.aps.org/

Cytotoxic gold(I) complexes with amidophosphine ligands containing thiophene moieties

A new phosphine ligand bearing a thiophene moiety, C 4 H 3 SNHCOCH 2 CH 2 PPh 2 (L), has been prepared by reaction of the aminophosphine Ph 2 PCH 2 CH 2 NH 2 with thiophenecarbonylchloride in the presence of triethylamine. The coordination behavior towards gold(I), gold(III) and silver(I) species has been studied and several metal compounds of different stoichiometry have been achieved, such as [AuL 2 ]OTf, [AuXL] (X = Cl, C 6 F 5 ), [Au(C 6 F 5 ) 3 L], [AgL 2 ]OTf or [Ag(OTf)L]. Additionally, the reactivity of the chloride gold(I) species with biologically relevant thiolates was explored, thus obtaining the neutral thiolate compounds [AuL(SR)] (SR = 2-thiocitosine, 2-thiolpyridine, 2-thiouracil, 2-thionicotinic acid, 2, 3, 4, 6-tetra-6-acetyl-1-thiol-ß-D-glucopyranosato or thiopurine). The antitumor activity of the compounds was measured by the MTT method in several cancer cells and the complexes exhibit excellent cytotoxic activity

Winding up by a quench: vortices in the wake of rapid Bose-Einstein condensation

A second order phase transition induced by a rapid quench can lock out topological defects with densities far exceeding their equilibrium expectation values. We use quantum kinetic theory to show that this mechanism, originally postulated in the cosmological context, and analysed so far only on the mean field classical level, should allow spontaneous generation of vortex lines in trapped Bose-Einstein condensates of simple topology, or of winding number in toroidal condensates.Comment: 4 pages, 2 figures; misprint correcte

Low temperature CO oxidation

Catalytic low-temperature abatement of carbon monoxide becomes essential in environmental pollution control. CO Oxidation, CO Preferential Oxidation (PROX) and Water Gas Shift (WGS) reaction are the conventional technologies used to remove carbon monoxide at low temperature. Perovskite-type oxides have been extensively studied in the last years as catalysts for these reactions due to their high activity and catalytic stability. This chapter describes the state-of-the-art of using perovskite-based catalysts of general formula ABO3 in these reactions. Key factors such as the type and nature of A and B ions or the formation of oxygen vacancies or interstitials by doping are discussed in the light of the reaction mechanism in each casePeer reviewe

Vector opinion dynamics in a model for social influence

We present numerical simulations of a model of social influence, where the opinion of each agent is represented by a binary vector. Agents adjust their opinions as a result of random encounters, whenever the difference between opinions is below a given threshold. Evolution leads to a steady state, which highly depends on the threshold and a convergence parameter of the model. We analyze the transition between clustered and homogeneous steady states. Results of the cases of complete mixing and small-world networks are compared.Comment: Latex file, 14 pages and 11 figures, Accepted in Physica

System model development and numerical simulation of low-head pumped hydro storage

To tackle the growing demand for grid-scale energy storage, the ALPHEUS project proposes a novel low-head pumped hydro storage system aimed for coastal application in countries where the topography does not allow for traditional high-head storage. This system consists of a reversible pump-turbine technology with two contra-rotating runners coupled to their respective axial-flux motor-generators as well as a dedicated control, optimising for energy balancing and the provision of ancillary services. To better understand the integration and dynamic interaction of the individual components of the plant and to allow for the simulation of a wide variety of operating conditions and scenarios, this research aims at developing a system model coupling the hydraulic, mechanical and electrical components. Numerical results are compared and verified based on CFD simulations. While some inaccuracies have to be expected, the comparison shows an overall good match with only minor deviations in dynamic behaviour and steady state results