Momentum Transfer to an Atom in a Molecule: Internal Excitation and Bond Dissociation

An atom will dissociate from a compound if the atom receives a recoil momentum greater than some average value Q0. Considering a polyatomic molecule as composed of point‐mass atoms, there is derived an equation which relates Q0 to the bond energy, bond angles and distances, and masses of the atoms in the molecule. The minimum net recoil energy required for bond rupture, the kinetic energy of the recoiling radicals, and the internal energy of the radical originally bonded to the activated atom are calculated for a series of simple alkyl halides.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70523/2/JCPSA6-36-4-947-1.pd

Effect of the Pin Geometry on the Wear Behavior of Weld-Deposited Hardfacing

AbstractHarfacing welding is a widely used method on severe worn, corroded or oxidized surfaces to regain its functionality. For metal-to-metal sliding or rolling contact applications, in which oxidative wear, subsurface fatigue and adhesive wear are the main wear mechanisms, the materials usually selected are steels with a carbon contents between 0,1 and 0,7% and up to 20% of alloy content, such as martensitic tool steels. Among them, H13 tool steel has a great number of applications. Variables such as sliding speed, load, or contact stress may have decisive influence on wear rates. Laboratory tests like Pin-On-Disk (POD) are frequently used to evaluate the tribologic behaviour of different pairs of material. The objective of this work was to study the influence of the pin geometry (flat and spherical) in a POD test on the wear resistance of a weld-deposited hardfacing of H13 modified steel against low carbon steel AISI 1020 under different load and sliding speed conditions. It was observed an influence of the pin geometry on the wear rates, especially at high sliding speeds. Under light loads, the worn volume of the flat pin was greater, while under heavier loads it is the spherical pin the one with greater worn amount

A model for liquid phase sintering

AbstractA quantitative model for liquid phase sintering is developed based on the following ideas. During heating a liquid phase forms, which is easily mobile, wets the solid particles completely, dissolves solid atoms and provides an easy diffusion path for them. The solid density increases by particle rearrangement and by the flattening of particle contacts. Driving (or retarding) forces result from capillary stresses, from applied mechanical stresses, from the pressure of gas entrapped in closed pores and from differences in chemical potential of the dissolved and precipitated matter. At higher densities the driving force may become very small, since the liquid pressure decreases and a negative contribution from the solid-liquid interface energy increases. At this stage grain coarsening plays an important role for the continued filling of larger and larger pores. The model is applied to describe nonisothermal densification curves measured on Si3N4 for various hold temperatures, axial stresses and green densities. Adjusting a moderate number of parameters all having a physical meaning leads to good agreement between theory and experiment

The problem of resonance in technology usage

Various information system tools and techniques are analyzed. A case study is presented which draws together the issues raised in three distinct cases. This case study shows a typical progression from the selection of an analysis methodology, to the adoption of an automated tool for specification and documentation, and the difficulty of fitting these into an existing life cycle development methodology

Efecto del calor aportado y de la cantidad de capas en depósitos de aceros inoxidables súper dúplex

Los aceros inoxidables súper dúplex poseen una estructura dual con un 50% de ferrita y austenita donde se obtienen las mejores propiedades mecánicas y de resistencia a la corrosión. Gracias a estas características su utilización se encuentra en crecimiento, fundamentalmente, en las industrias del papel, químicas, del gas y del petróleo. La soldadura de recargue, o cladding es utilizada para la fabricación y/o reparación de partes y equipos. Las propiedades superficiales del recubrimiento dependen de la composición química y la microestructura en esa zona, las que a su vez quedan definidas por la dilución y el procedimiento de soldadura. Por lo tanto, en soldadura de recargue de aceros inoxidables súper dúplex, el control de las fases presentes en la microestructura es esencial para garantizar las propiedades requeridas. El objetivo de este trabajo fue el de estudiar el efecto del calor aportado (alto, medio y bajo) y de la cantidad de capas (una y dos) del depósito de soldadura de acero inoxidable súper dúplex sobre la composición química, la microestructura y la dureza. Para tal fin se soldaron cupones de recargue mediante el proceso de soldadura semiautomático con protección gaseosa, empleando un alambre macizo de 1,2 mm de diámetro con Ar + 20% CO2 como gas de protección. Se obtuvieron seis cupones: 1 y 2 capas soldados con bajo, medio y alto calor aportado (modificando únicamente la velocidad de soldadura). Sobre los mismos se caracterizó la macro y microestructura, se determinó la dilución geométrica y química mediante la técnica de espectrometría dispersiva en energías y se observó la microestructura mediante microscopía óptica, se cuantificó el contenido de ferrita y se determinó la microdureza Vickers

Experimental Study on Thermomechanical Properties of New-Generation ODS Alloys

By using a combination of new technologies together with an unconventional use of different types of materials, specific mechanical properties and structures of the material can be achieved. Some possibilities are enabled by a combination of powder metallurgy in the preparation of a metal matrix with dispersed stable particles achieved by mechanical alloying and hot consolidation. This paper explains the thermomechanical properties of new generation of Oxide Dispersion Strengthened alloys (ODS) within three ranges of temperature with specified deformation profiles. The results show that the mechanical properties of new ODS alloys are significantly affected by the thermomechanical treatment

Characterization and subcellular targeting of GCaMP-type genetically-encoded calcium indicators

Genetically-encoded calcium indicators (GECIs) hold the promise of monitoring [Ca(2+)] in selected populations of neurons and in specific cellular compartments. Relating GECI fluorescence to neuronal activity requires quantitative characterization. We have characterized a promising new genetically-encoded calcium indicator-GCaMP2-in mammalian pyramidal neurons. Fluorescence changes in response to single action potentials (17+/-10% DeltaF/F [mean+/-SD]) could be detected in some, but not all, neurons. Trains of high-frequency action potentials yielded robust responses (302+/-50% for trains of 40 action potentials at 83 Hz). Responses were similar in acute brain slices from in utero electroporated mice, indicating that long-term expression did not interfere with GCaMP2 function. Membrane-targeted versions of GCaMP2 did not yield larger signals than their non-targeted counterparts. We further targeted GCaMP2 to dendritic spines to monitor Ca(2+) accumulations evoked by activation of synaptic NMDA receptors. We observed robust DeltaF/F responses (range: 37%-264%) to single spine uncaging stimuli that were correlated with NMDA receptor currents measured through a somatic patch pipette. One major drawback of GCaMP2 was its low baseline fluorescence. Our results show that GCaMP2 is improved from the previous versions of GCaMP and may be suited to detect bursts of high-frequency action potentials and synaptic currents in vivo

Disorder promotes ferromagnetism: Rounding of the quantum phase transition in Sr_{1-x}Ca_xRuO_3

The subtle interplay of randomness and quantum fluctuations at low temperatures gives rise to a plethora of unconventional phenomena in systems ranging from quantum magnets and correlated electron materials to ultracold atomic gases. Particularly strong disorder effects have been predicted to occur at zero-temperature quantum phase transitions. Here, we demonstrate that the composition-driven ferromagnetic-to-paramagnetic quantum phase transition in Sr1-xCaxRuO3 is completely destroyed by the disorder introduced via the different ionic radii of the randomly distributed Sr and Ca ions. Using a magneto-optical technique, we map the magnetic phase diagram in the composition-temperature space. We find that the ferromagnetic phase is significantly extended by the disorder and develops a pronounced tail over a broad range of the composition x. These findings are explained by a microscopic model of smeared quantum phase transitions in itinerant magnets. Moreover, our theoretical study implies that correlated disorder is even more powerful in promoting ferromagnetism than random disorder.Comment: 15 pages, 4 figures, submitted to Phys. Rev. Let