964 research outputs found
Dielectric susceptibility of the Coulomb-glass
We derive a microscopic expression for the dielectric susceptibility
of a Coulomb glass, which corresponds to the definition used in classical
electrodynamics, the derivative of the polarization with respect to the
electric field. The fluctuation-dissipation theorem tells us that is a
function of the thermal fluctuations of the dipole moment of the system. We
calculate numerically for three-dimensional Coulomb glasses as a
function of temperature and frequency
Intruders in the Dust: Air-Driven Granular Size Separation
Using MRI and high-speed video we investigate the motion of a large intruder
particle inside a vertically shaken bed of smaller particles. We find a
pronounced, non-monotonic density dependence, with both light and heavy
intruders moving faster than those whose density is approximately that of the
granular bed. For light intruders, we furthermore observe either rising or
sinking behavior, depending on intruder starting height, boundary condition and
interstitial gas pressure. We map out the phase boundary delineating the rising
and sinking regimes. A simple model can account for much of the observed
behavior and show how the two regimes are connected by considering pressure
gradients across the granular bed during a shaking cycle.Comment: 5 pages, 4 figure
Kinetic Accessibility of Buried DNA Sites in Nucleosomes
Using a theoretical model for spontaneous partial DNA unwrapping from
histones, we study the transient exposure of protein-binding DNA sites within
nucleosomes. We focus on the functional dependence of the rates for site
exposure and reburial on the site position, which is measurable experimentally
and pertinent to gene regulation. We find the dependence to be roughly
described by a random walker model. Close inspection reveals a surprising
physical effect of flexibility-assisted barrier crossing, which we characterize
within a toy model, the "semiflexible Brownian rotor."Comment: final version as published in Phys. Rev. Let
Corrigendum to "Fractional release factors of long-lived halogenated organic compounds in the tropical stratosphere" published in Atmos. Chem. Phys., 10, 1093–1103, 2010
We have noted a computational error in the calculation of the averaged Fractional Release Factors (FRFs) relative to the averaged FRF of CFCl3 (CFC-11). ..
Optimal flexibility for conformational transitions in macromolecules
Conformational transitions in macromolecular complexes often involve the
reorientation of lever-like structures. Using a simple theoretical model, we
show that the rate of such transitions is drastically enhanced if the lever is
bendable, e.g. at a localized "hinge''. Surprisingly, the transition is fastest
with an intermediate flexibility of the hinge. In this intermediate regime, the
transition rate is also least sensitive to the amount of "cargo'' attached to
the lever arm, which could be exploited by molecular motors. To explain this
effect, we generalize the Kramers-Langer theory for multi-dimensional barrier
crossing to configuration dependent mobility matrices.Comment: 4 pages, 4 figure
Proton endor study of the photoexcited triplet state PT in Rps. sphaeroides R-26 photosynthetic reaction centres
The photoexcited triplet state PT of Rhodopseudomonas sphaeroides R-26 has been investigated by ENDOR measurements performed on frozen photosynthetic reaction centre solutions. For the first time hyperfine data could be obtained for PT. These data indicate a delocalisation of the triplet state over two bacteriochlorophyll a molecules
ESR, ENDOR and TRIPLE resonance studies of the primary donor radical cation P960+ in the photosynthetic bacterium Rhodopseudomonas viridis
The light-induced radical cation of the primary electron donor P960+• in photosynthetic reaction centers from Rhodopseudomonas viridis has been investigated by ESR, ENDOR and TRIPLE techniques. Both the comparison with the cation radical of monomeric bacteriochlorophyll b (BChl b) and with molecular-orbital calculations performed on P960+• using the results of an X-ray structure analysis, consistently show an asymmetric distribution of the unpaired electron over the two BChl b molecules which constitute P960+•. The possible relevance of this result for the primary electron transfer step in the reaction center is briefly discussed
Optimization by thermal cycling
Thermal cycling is an heuristic optimization algorithm which consists of
cyclically heating and quenching by Metropolis and local search procedures,
respectively, where the amplitude slowly decreases. In recent years, it has
been successfully applied to two combinatorial optimization tasks, the
traveling salesman problem and the search for low-energy states of the Coulomb
glass. In these cases, the algorithm is far more efficient than usual simulated
annealing. In its original form the algorithm was designed only for the case of
discrete variables. Its basic ideas are applicable also to a problem with
continuous variables, the search for low-energy states of Lennard-Jones
clusters.Comment: Submitted to Proceedings of the Workshop "Complexity, Metastability
and Nonextensivity", held in Erice 20-26 July 2004. Latex, 7 pages, 3 figure
The radical cation of bacteriochlorophyll b. A liquid-phase endor and triple resonance study
The previous termradical cationnext term of bacterioehlorophyll b (BChl b) is investigated by ENDOR and TRIPLE resonance in liquid solution. The experimental hyperfine coupling constants, ten proton and three nitrogen couplings, are compared with the predictions from advanced molecular-orbital calculations (RHF INDO/SP). The detailed picture obtained of the spin density distribution is a prerequisite for the investigation of the primary electron donor previous termradical cationnext term in BChl b containing photosynthetic bacteria
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