66 research outputs found
Einstein-Podolsky-Rosen-like correlation on a coherent-state basis and inseparability of two-mode Gaussian states
The strange property of the Einstein-Podolsky-Rosen (EPR) correlation between
two remote physical systems is a primitive object on the study of quantum
entanglement. In order to understand the entanglement in canonical
continuous-variable systems, a pair of the EPR-like uncertainties is an
essential tool. Here, we consider a normalized pair of the EPR-like
uncertainties and introduce a state-overlap to a classically correlated mixture
of coherent states. The separable condition associated with this state-overlap
determines the strength of the EPR-like correlation on a coherent-state basis
in order that the state is entangled. We show that the coherent-state-based
condition is capable of detecting the class of two-mode Gaussian entangled
states. We also present an experimental measurement scheme for estimation of
the state-overlap by a heterodyne measurement and a photon detection with a
feedforward operation.Comment: 9 pages, 5 figures. A part of the materials in Sec. VI B of previous
versions was moved into another paper: Journal of Atomic, Molecular, and
Optical Physics, 2012, 854693 (2012).
http://www.hindawi.com/journals/jamop/2012/854693
Missing OH source in a suburban environment near Beijing: observed and modelled OH an HO2 concentrations in summer 2006
Measurements of ambient OH and HO<sub>2</sub> radicals were performed by laser induced fluorescence (LIF) during CAREBeijing2006 (Campaigns of Air Quality Research in Beijing and Surrounding Region 2006) at the suburban site Yufa in the south of Beijing in summer 2006. On most days, local air chemistry was influenced by aged air pollution that was advected by a slow, almost stagnant wind from southern regions. Observed daily maxima of OH and HO<sub>2</sub><sup>*</sup> were in the range of (4–17) × 10<sup>6</sup> cm<sup>−3</sup> and (2–24) × 10<sup>8</sup> cm<sup>−3</sup>, respectively. During daytime, OH reactivities were generally high (10–30 s<sup>−1</sup>) and mainly contributed by VOCs and their oxidation products. The comparison of modelled and measured HO<sub>x</sub> concentrations reveals a systematic underprediction of OH as a function of NO. A large discrepancy of a factor 2.6 is found at the lowest NO concentration encountered (0.1 ppb), whereas the discrepancy becomes insignificant above 1 ppb NO. This study extends similar observations from the Pearl-River Delta (PRD) in South China to a more urban environment. The OH discrepancy at Yufa can be resolved, if NO-independent additional OH recycling is assumed in the model. The postulated Leuven Isoprene Mechanism (LIM) has the potential to explain the gap between modelled and measured OH at Beijing taking into account conservative error estimates, but still lacks experimental confirmation. This and the hereby unresolved discrepancy at PRD suggest that other VOCs besides isoprene might be involved in the required, additional OH recycling. Fast primary production of RO<sub>x</sub> radicals up to 7 ppb h<sup>−1</sup> was determined at Beijing which was dominated by the photolysis of O<sub>3</sub>, HONO, HCHO, and dicarbonyls. For a special case, 20 August, when the plume of Beijing city was encountered, a missing primary HO<sub>x</sub> source (≈ 3 ppb h<sup>−1</sup>) was determined under high NO<sub>x</sub> conditions similar to other urban areas like Mexico city. CAREBeijing2006 emphasizes the important role of OVOCs as a radical source and sink, and the need for further investigation of the chemical degradation of VOCs in order to better understand radical chemistry in VOC-rich air
Technical Note: Formal blind intercomparison of HO<sub>2</sub> measurements in the atmosphere simulation chamber SAPHIR during the HOxComp campaign
Hydroperoxy radical (HO<sub>2</sub>) concentrations were measured during the formal blind intercomparison campaign HOxComp carried out in Jülich, Germany, in 2005. Three instruments detected HO<sub>2</sub> via chemical conversion to hydroxyl radicals (OH) and subsequent detection of the sum of OH and HO<sub>2</sub> by laser induced fluorescence (LIF). All instruments were based on the same detection and calibration scheme. Because measurements by a MIESR instrument failed during the campaign, no absolute reference measurement was available, so that the accuracy of individual instruments could not be addressed. Instruments sampled ambient air for three days and were attached to the atmosphere simulation chamber SAPHIR during the second part of the campaign. Six experiments of one day each were conducted in SAPHIR, where air masses are homogeneously mixed, in order to investigate the performance of instruments and to determine potential interferences of measurements under well-controlled conditions. Linear correlation coefficients (<i>R</i><sup>2</sup>) between measurements of the LIF instruments are generally high and range from 0.82 to 0.98. However, the agreement between measurements is variable. The regression analysis of the entire data set of measurements in SAPHIR yields slopes between 0.69 to 1.26 and intercepts are smaller than typical atmospheric daytime concentrations (less than 1 pptv). The quality of fit parameters improves significantly, when data are grouped into data subsets of similar water vapor concentrations. Because measurements of LIF instruments were corrected for a well-characterized water dependence of their sensitivities, this indicates that an unknown factor related to water vapor affected measurements in SAPHIR. Measurements in ambient air are also well-correlated, but regression parameters differ from results obtained from SAPHIR experiments. This could have been caused by differences in HO<sub>2</sub> concentrations in the sampled air at the slightly different locations of instruments
Missing OH source in a suburban environment near Beijing: observed and modelled OH and HO2 concentrations in summer 2006
Measurements of ambient OH and HO2 radicals were performed by laser induced fluorescence (LIF) during CAREBeijing2006 (Campaigns of Air Quality Research in Beijing and Surrounding Region 2006) at the suburban site Yufa in the south of Beijing in summer 2006. On most days, local air chemistry was influenced by aged air pollution that was advected by a slow, almost stagnant wind from southern regions. Observed daily concentration maxima were in the range of (4–17) × 106 cm−3 for OH and (2–24) × 108 cm−3 for HO2 (including an estimated interference of 25% from RO2). During daytime, OH reactivities were generally high (10–30 s−1) and mainly contributed by observed VOCs and their calculated oxidation products. The comparison of modelled and measured HOx concentrations reveals a systematic underprediction of OH as a function of NO. A large discrepancy of a factor 2.6 is found at the lowest NO concentration encountered (0.1 ppb), whereas the discrepancy becomes insignificant above 1 ppb NO. This study extends similar observations from the Pearl-River Delta (PRD) in South China to a more urban environment. The OH discrepancy at Yufa can be resolved, if NO-independent additional OH recycling is assumed in the model. The postulated Leuven Isoprene Mechanism (LIM) has the potential to explain the gap between modelled and measured OH at Beijing taking into account conservative error estimates, but lacks experimental confirmation. This and the hereby unresolved discrepancy at PRD suggest that other VOCs besides isoprene might be involved in the required, additional OH recycling. Fast primary production of ROx radicals up to 7 ppb h−1 was determined at Beijing which was dominated by the photolysis of O3, HONO, HCHO, and dicarbonyls. For a special case, 20 August, when the plume of Beijing city was encountered, a missing primary HOx source (about 3 ppb h−1) was determined under high NOx conditions similar to other urban areas like Mexico City. CAREBeijing2006 emphasizes the important role of OVOCs as a radical source and sink, and the need for further investigation of the chemical degradation of VOCs in order to better understand radical chemistry in VOC-rich air
Exploring the atmospheric chemistry of nitrous acid (HONO) at a rural site in Southern China
We performed measurements of nitrous acid (HONO) during the PRIDE-PRD2006 campaign in the Pearl River Delta region 60 km north of Guangzhou, China, for 4 weeks in June 2006. HONO was measured by a LOPAP in-situ instrument which was setup in one of the campaign supersites along with a variety of instruments measuring hydroxyl radicals, trace gases, aerosols, and meteorological parameters. Maximum diurnal HONO mixing ratios of 1–5 ppb were observed during the nights. We found that the nighttime build-up of HONO can be attributed to the heterogeneous NO2 to HONO conversion on ground surfaces and the OH + NO reaction. In addition to elevated nighttime mixing ratios, measured noontime values of ≈200 ppt indicate the existence of a daytime source higher than the OH + NO→HONO reaction. Using the simultaneously recorded OH, NO, and HONO photolysis frequency, a daytime additional source strength of HONO (PM) was calculated to be 0.77 ppb h−1 on average. This value compares well to previous measurements in other environments. Our analysis of PM provides evidence that the photolysis of HNO3 adsorbed on ground surfaces contributes to the HONO formation
Intercomparison of NO₃ radical detection instruments in the atmosphere simulation chamber SAPHIR
OH reactivity at a rural site (Wangdu) in the North China Plain: contributions from OH reactants and experimental OH budget
In 2014, a large, comprehensive field campaign was conducted in the densely populated North China Plain. The measurement site was located in a botanic garden close to the small town Wangdu, without major industry but influenced by regional transportation of air pollution. The loss rate coefficient of atmospheric hydroxyl radicals (OH) was quantified by direct measurements of the OH reactivity. Values ranged between 10 and 20 s−1 for most of the daytime. Highest values were reached in the late night with maximum values of around 40 s−1. OH reactants mainly originated from anthropogenic activities as indicated (1) by a good correlation between measured OH reactivity and carbon monoxide (linear correlation coefficient R2 = 0.33) and (2) by a high contribution of nitrogen oxide species to the OH reactivity (up to 30 % in the morning). Total OH reactivity was measured by a laser flash photolysis–laser-induced fluorescence instrument (LP-LIF). Measured values can be explained well by measured trace gas concentrations including organic compounds, oxygenated organic compounds, CO and nitrogen oxides. Significant, unexplained OH reactivity was only observed during nights, when biomass burning of agricultural waste occurred on surrounding fields. OH reactivity measurements also allow investigating the chemical OH budget. During this campaign, the OH destruction rate calculated from measured OH reactivity and measured OH concentration was balanced by the sum of OH production from ozone and nitrous acid photolysis and OH regeneration from hydroperoxy radicals within the uncertainty of measurements. However, a tendency for higher OH destruction compared to OH production at lower concentrations of nitric oxide is also observed, consistent with previous findings in field campaigns in China
Entwicklung und Realisierung einer elektromechanischen Laserstrahlnachführung unter Verwendung positionsempfindlicher Photodioden
Development and application of a new mobile LOPAP instrument for the measurement of HONO altitude profiles in the planetary boundary layer
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