3,545 research outputs found
Synthesis, physicochemical and photophysical characterization of 4-(1-Pyrenyl)-Butyl-α-d-mannopyranoside
Indexación: Web of Science; Scopus; Scielo.Glycolipids are biomolecules composed of a lipid chain (lipophilic) and a monosaccharide or oligosaccharide as hydrophilic group. Their chemical structure and biological role make them undoubtedly good candidates for a large and continuously growing number of biotechnological applications. Mannose is a carbohydrate present on membrane glycolipids of a wide number of pathogenic microorganisms (bacteria, fungi, protozoa, and viruses) and specifically recognized by several lectins. We synthesized a mannose derivative linked through a short methylene chain to a pyrene moiety which behaves as a surfactant, able to aggregate, and retains the photophysical properties of pyrene: showing comparable absorption and emission spectra, having lower fluorescence quantum yield and the ability to form excimer, and finally the ability to produce O-2((1)Delta(g)) with high quantum yields. Thus, this novel molecule would open future applications for detection (fluorescence) or inactivation (singlet oxygen) of bacterial pathogens, viruses, tumor cells, or particular cells.http://ref.scielo.org/pcn4d
Anisotropic Inflation and the Origin of Four Large Dimensions
In the context of (4+d)-dimensional general relativity, we propose an
inflationary scenario wherein 3 spatial dimensions grow large, while d extra
dimensions remain small. Our model requires that a self-interacting d-form
acquire a vacuum expectation value along the extra dimensions. This causes 3
spatial dimensions to inflate, whilst keeping the size of the extra dimensions
nearly constant. We do not require an additional stabilization mechanism for
the radion, as stable solutions exist for flat, and for negatively curved
compact extra dimensions. From a four-dimensional perspective, the radion does
not couple to the inflaton; and, the small amplitude of the CMB temperature
anisotropies arises from an exponential suppression of fluctuations, due to the
higher-dimensional origin of the inflaton. The mechanism triggering the end of
inflation is responsible, both, for heating the universe, and for avoiding
violations of the equivalence principle due to coupling between the radion and
matter.Comment: 24 pages, 2 figures; uses RevTeX4. v2: Minor changes and added
references. v3: Improved discussion of slow-rol
Study of structural features of porous TiNi-based materials produced by SHS and sintering
Structural properties of porous TiNi-based materials produced by SHS method and sintering have been investigated. The material having different pore wall surface topography, porosity and pore size distribution was shown to be produced depending on the powder metallurgy method for porous TiNi-based alloy. All the materials having porosity of 55-70%, mean pore size 90-150 μm, as well as normal pore size distribution are most preferable. Ultimate strength and breaking point were determined to depend on porosity, pore size distribution, pore intersections and phase chemical composition of the material. Strength properties of the sintered alloy are twice as much compared to the SHS-produced ones due to homogeneity of its macrostructure, low chemical heterogeneity and TiNi3 precipitations strengthening the TiNi matrix.</jats:p
Quantum Noise Randomized Ciphers
We review the notion of a classical random cipher and its advantages. We
sharpen the usual description of random ciphers to a particular mathematical
characterization suggested by the salient feature responsible for their
increased security. We describe a concrete system known as AlphaEta and show
that it is equivalent to a random cipher in which the required randomization is
effected by coherent-state quantum noise. We describe the currently known
security features of AlphaEta and similar systems, including lower bounds on
the unicity distances against ciphertext-only and known-plaintext attacks. We
show how AlphaEta used in conjunction with any standard stream cipher such as
AES (Advanced Encryption Standard) provides an additional, qualitatively
different layer of security from physical encryption against known-plaintext
attacks on the key. We refute some claims in the literature that AlphaEta is
equivalent to a non-random stream cipher.Comment: Accepted for publication in Phys. Rev. A; Discussion augmented and
re-organized; Section 5 contains a detailed response to 'T. Nishioka, T.
Hasegawa, H. Ishizuka, K. Imafuku, H. Imai: Phys. Lett. A 327 (2004) 28-32
/quant-ph/0310168' & 'T. Nishioka, T. Hasegawa, H. Ishizuka, K. Imafuku, H.
Imai: Phys. Lett. A 346 (2005) 7
On the Application of a Monolithic Array for Detecting Intensity-Correlated Photons Emitted by Different Source Types
It is not widely appreciated that many subtleties are involved in the
accurate measurement of intensity-correlated photons; even for the original
experiments of Hanbury Brown and Twiss (HBT). Using a monolithic 4x4 array of
single-photon avalanche diodes (SPADs), together with an off-chip algorithm for
processing streaming data, we investigate the difficulties of measuring
second-order photon correlations g2 in a wide variety of light fields that
exhibit dramatically different correlation statistics: a multimode He-Ne laser,
an incoherent intensity-modulated lamp-light source and a thermal light source.
Our off-chip algorithm treats multiple photon-arrivals at pixel-array pairs, in
any observation interval, with photon fluxes limited by detector saturation, in
such a way that a correctly normalized g2 function is guaranteed. The impact of
detector background correlations between SPAD pixels and afterpulsing effects
on second-order coherence measurements is discussed. These results demonstrate
that our monolithic SPAD array enables access to effects that are otherwise
impossible to measure with stand-alone detectors.Comment: 17 pages, 6 figure
Investigation of the effect of copper addition on physical and mechanical properties of TiNi-Cu porous alloy
This work is devoted to the physical and mechanical properties of porous alloys based on TiNi alloyed with different amounts of Cu additive. We show that by doping a porous TiNi alloy with copper instead of nickel, it is possible to obtain characteristics acceptable for use in implantology and superior to those of known porous TiNi alloys. Cu addition in the range from 1 to 10 at.% is shown to optimize the properties of tested alloys. There is a decrease in the minimal martensitic transformation stress τminMs from 37 to 17 MPa when compared to initial unalloyed TiNi. Alloys with 3 and 6 at.% of Cu are found to be optimal for use in medical practice. Along with a wide temperature range of reversible deformations that cover the range of operating temperatures (273–313 K), such alloys demonstrate their martensitic transformation stress values below 28 MPs. This permits to model implantable structures of complex configuration from such materials under a certain temperature regime
A bimodal spacecraft bus based on a cermet fueled heat pipe reactor
Bimodal space reactor systems provide both thermal propulsion for the spacecraft orbital transfer and electrical power to the spacecraft bus once it is on station. These systems have the potential to increase both the available payload in high energy orbits and the available power to that payload. These increased mass and power capabilities can be used to either reduce mission cost by permitting the use of smaller launch vehicles or to provide increased mission performance from the current launch vehicle. A major barrier to the deployment of these bimodal systems has been the cost associated with their development. This paper describes a bimodal spacecraft bus with performance potential to permit more than 70% of the instrumented payload of the Titan IV/Centaur to be launched from the Atlas IIAS. The development cost is minimized by basing the design on existing component technologies
Nonexponential Relaxation of Magnetization at the Resonant Tunneling Point under a Fluctuating Random Noise
Nonexponential relaxation of magnetization at resonant tunneling points of
nanoscale molecular magnets is interpreted to be an effect of fluctuating
random field around the applied field. We demonstrate such relaxation in
Langevin equation analysis and clarify how the initial relaxation (square-root
time) changes to the exponential decay. The scaling properties of the
relaxation are also discussed.Comment: 4 pages, 4 fgiure
Use of a porous membrane for gas bubble removal in microfluidic channels: physical mechanisms and design criteria
We demonstrate and explain a simple and efficient way to remove gas bubbles
from liquid-filled microchannels, by integrating a hydrophobic porous membrane
on top of the microchannel. A prototype chip is manufactured in hard,
transparent polymer with the ability to completely filter gas plugs out of a
segmented flow at rates up to 7.4 microliter/s per mm2 of membrane area. The
device involves a bubble generation section and a gas removal section. In the
bubble generation section, a T-junction is used to generate a train of gas
plugs into a water stream. These gas plugs are then transported towards the gas
removal section, where they slide along a hydrophobic membrane until complete
removal. The system has been successfully modeled and four necessary operating
criteria have been determined to achieve a complete separation of the gas from
the liquid. The first criterion is that the bubble length needs to be larger
than the channel diameter. The second criterion is that the gas plug should
stay on the membrane for a time sufficient to transport all the gas through the
membrane. The third criterion is that the gas plug travel speed should be lower
than a critical value: otherwise a stable liquid film between the bubble and
the membrane prevents mass transfer. The fourth criterion is that the pressure
difference across the membrane should not be larger than the Laplace pressure
to prevent water from leaking through the membrane
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