Sustainable earth walls to meet the building regulations

The thermal conductivity and diffusivity of un-fired clay bricks, a straw clay mixture and straw bales have been measured using a thermal probe technique, with an iterative method for data analysis. The steady-state air-to-air thermal transmittance, or U-value, and the time-dependent thermal properties of some proposed sustainable earth wall constructions are presented. Sustainable cavity walls of un-fired clay bricks with paper, straw or wool cavity insulation have thermal transmittances less than 0.35 W/m2 K, and therefore meet the current United Kingdom Building Regulations. A review of possible methods for thermally up-grading existing earth walls, by adding an internal insulated timber frame construction, again demonstrates possible compliance with the current UK thermal regulations

Investigation into the variations of moisture content of two buildings constructed with light earth walls

This paper briefly describes the background to light earth buildings and details a series of moisture measurements undertaken upon the clay and straw, (light earth) constructed walls of two UK based buildings. The methodology of measurement that was based upon previous studies undertaken on walls made from straw bales is described. A novel ‘in-wall’ wet heating system used in one of the two buildings allows the investigation of the effects of direct wall heating upon the distribution of moisture in the walls. The influence of exterior and interior temperature and humidity are described as are the variations in moisture migration introduced by the in-wall heating system. It was concluded that both buildings have exterior wall moisture content readings that indicate little risk of degradation due to interior wall moisture levels (although the Studio walls do exhibit higher and if suffered over long time periods, dangerous moisture readings for part of the measurement period)

Wireless Accelerometer for Neonatal MRI Motion Artifact Correction

A wireless accelerometer has been used in conjunction with a dedicated 3T neonatal MRI system installed on a Neonatal Intensive Care Unit to measure in-plane rotation which is a common problem with neonatal MRI. Rotational data has been acquired in real-time from phantoms simultaneously with MR images which shows that the wireless accelerometer can be used in close proximity to the MR system. No artifacts were observed on the MR images from the accelerometer or from the MR system on the accelerometer output. Initial attempts to correct the raw data using the measured rotational angles have been performed, but further work will be required to make a robust correction algorithm

Rethinking the future low-carbon city: carbon neutrality, green design, and sustainability tensions in the making of Masdar City

As the global trend toward urbanization continues, new models for the design and governance of sustainable cities are being developed. The Abu Dhabi government announced in 2006 its intent to spend $22 billion to build one such city, Masdar City, as a carbon-neutral, zero-waste city that would demonstrate the state-of-the-art in sustainable city design. As initially planned, Masdar City was a bold experiment: an incubator of clean-technologies that was to be powered exclusively by renewable energy while exhibiting the highest levels of energy efficiency. Partly due to the 2008 global financial crisis and partly due to lessons learned from continued assessments of the original concept, planners at Masdar both scaled back initial ambitions for the city’s carbon and waste targets and significantly altered both the city’s development approach and timeline for completion. This, however, may turn out to be the best outcome for Masdar City if it is truly to become a model for “eco-cities” of the future. Masdar now seeks a more commercial city model that nonetheless retains a focus on sustainable urban design. This Perspective reviews the history of Masdar City from its inception to the present day and highlights the major changes that have occurred in the city planning. In consideration of the facts presented, Masdar City may yet emerge as a true eco-city. But it certainly constitutes an omen with incredibly important empirical lessons for other cities around the world seeking to become more sustainable

Bulk Group-III Nitride Crystal Growth in Supercritical Ammonia-Sodium Solutions

Gallium nitride (GaN) and its alloys with indium nitride (InGaN) and aluminum nitride (AlGaN), collectively referred to as Group-III Nitride semiconductors, have enabled white solid-state lighting (SSL) sources and power electronic devices. While these technologies have already made a lasting, positive impact on society, improvements in design and efficiency are anticipated by shifting from heteroepitaxial growth on foreign substrates (such as sapphire, Si, SiC, etc.) to homoepitaxial growth on native, bulk GaN substrates. Bulk GaN has not supplanted foreign substrate materials due to the extreme conditions required to achieve a stoichiometric GaN melt (temperatures and pressures in excess of 2200°C and 6 GPa, respectively). The only method used to produce bulk GaN on an industrial scale is hydride vapor phase epitaxy (HVPE), but the high cost of gaseous precursors and relatively poor crystal quality have limited the adoption of this technology. A solution growth technique known as the ammonothermal method has attracted interest from academia and industry alike for its ability to produce bulk GaN boules of exceedingly high crystal quality. The ammonothermal method employs supercritical ammonia (NH3) solutions to dissolve, transport, and crystallize GaN. However, ammonothermal growth pressures are still relatively high (~200 MPa), which has thus far prevented the acquisition of fundamental crystal growth knowledge needed to efficiently (i.e. through data-driven approaches) advance the field. This dissertation focused on addressing the gaps in the literature through two studies employing in situ fluid temperature analysis. The first study focused on identifying the solubility of GaN in supercritical NH3-Na solutions. The design and utilization of in situ and ex situ monitoring equipment enabled the first reports of the two-phase nature of supercritical NH3-Na solutions, and of Ga-alloying of Ni-containing autoclave components. The effects of these error sources on the gravimetric determination of GaN solubility were explored in detail. The second study was aimed at correlating autoclave dissolution and growth zone fluid temperatures with bulk GaN crystal growth kinetics, crystal quality, and impurity incorporation. The insights resulting from this analysis include the identification of the barrier between mass transport and surface integration-limited GaN growth regimes, GaN crystal shape evolution with fluid temperature, the sensitivity of (0001)-orientation crystal quality with fluid temperature, and impurity-specific incorporation activated from the dissolution and growth zones of the autoclave. The results of the aforementioned studies motivated a paradigm-shift in ammonothermal growth. To address this need, a fundamentally different crystal growth approach involving isothermal solutions and tailor-made Group-III alloy source materials was developed/demonstrated. This growth method enabled impurity incorporation reduction compared to traditional ammonothermal GaN growth, and the realization of bulk, ternary Group-III Nitride crystals

The impact of engagement in sport on graduate employability: implications for higher education policy and practice

This paper analyses the impact of engagement in sport on graduate employability using a triangulation of views from three key stakeholder groups. Primary research was conducted with 5,838 graduates, 112 employers and 13 university senior executives as part of a mixed methods approach. The research found that engagement in sport was viewed as a sound investment from the perspectives of all three groups, with examples highlighting how sport provided 'added value' beyond subject-specific qualifications. This finding was particularly prominent where graduates demonstrated experience of voluntary roles through the leadership and management of sport, and could articulate how this had a positive impact on the development of additional employability attributes. We argue that there are important implications for Higher Education policy, sports policy, universities, employers and students. For students, employability can be enhanced through participation and volunteering in sport, which is shown to be a good investment in terms of both skill development and future earnings. For employers, when recruiting graduates, a history of sport participation (inclusive of voluntary experience) may be a good indicator of candidates with desirable traits for employment. For universities, meeting their customers' demand for sport with sufficient supply through strategic investment is an important consideration of their offer

Gesturing Meaning: Non-action Words Activate the Motor System

Across cultures, speakers produce iconic gestures, which add – through the movement of the speakers’ hands – a pictorial dimension to the speakers’ message. These gestures capture not only the motor content but also the visuospatial content of the message. Here, we provide first evidence for a direct link between the representation of perceptual information and the motor system that can account for these observations. Across four experiments, participants’ hand movements captured both shapes that were directly perceived, and shapes that were only implicitly activated by unrelated semantic judgments of object words. These results were obtained even though the objects were not associated with any motor behaviors that would match the gestures the participants had to produce. Moreover, implied shape affected not only gesture selection processes but also their actual execution – as measured by the shape of hand motion through space – revealing intimate links between implied shape representation and motor output. The results are discussed in terms of ideomotor theories of action and perception, and provide one avenue for explaining the ubiquitous phenomenon of iconic gestures

"Coseismic foliations" in gouge and cataclasite: experimental observations and consequences for interpreting the fault rock record

Foliated gouges and cataclasites are commonly interpreted as the product of distributed (aseismic) fault creep. However, foliated fault rocks are often associated with localized slip surfaces, the latter indicating potentially unstable (seismic) behavior. One possibility is that such fault zones preserve the effects of both seismic slip and slower aseismic creep. An alternative possibility explored here is that some foliated fault rocks and localized slip surfaces develop contemporaneously during seismic slip. We studied the microstructural evolution of calcite- dolomite gouges deformed experimentally at slip velocities <1.13 m/s and for total displacements of 0.03 - 1 m, in the range expected for the average coseismic slip during earthquakes of Mw 3-7. As strain progressively localized in the gouge layers at the onset of high-velocity shearing, an initial mixed assemblage of calcite and dolomite grains evolved quickly to an organized, foliated fabric. The foliation was defined mainly by compositional layering and grain size variations that formed by cataclasis and shearing of individual foliation domains. Quantitative image analysis (e.g. grain size, strain) showed that the most significant microstructural changes in the bulk gouge occurred before and during dynamic weakening (<0.08 m displacement). Strain was localized to a bounding slip surface by the end of dynamic weakening and thus microstructural evolution in the bulk gouge ceased. Our experiments suggest that certain types of foliated gouge and cataclasite can form by distributed brittle \u201cflow\u201d as strain localizes to a bounding slip surface during coseismic shearing. We will also present preliminary observations of natural calcite-dolomite foliated cataclasites from the Campo Imperatore normal fault, central Italy, which bear striking resemblance to our well-characterized experimental examples

Is the electrostatic force between a point charge and a neutral metallic object always attractive?

We give an example of a geometry in which the electrostatic force between a point charge and a neutral metallic object is repulsive. The example consists of a point charge centered above a thin metallic hemisphere, positioned concave up. We show that this geometry has a repulsive regime using both a simple analytical argument and an exact calculation for an analogous two-dimensional geometry. Analogues of this geometry-induced repulsion can appear in many other contexts, including Casimir systems.Comment: 7 pages, 7 figure

Differentiation Potential of CD14+ Monocytes into Myofibroblasts in Patients with Systemic Sclerosis

BACKGROUND: Circulating monocytes are a highly plastic and functionally heterogeneic cell type with an activated phenotype in patients with systemic sclerosis (SSc). CD14(+) monocytes have the potential to differentiate into extra-cellular matrix (ECM) producing cells, possibly participating in fibrogenesis. AIM: To study the effect of GM-CSF, IL-4 and endothelin -1 (ET-1) alone or in combination on monocyte differentiation into myofibroblasts. METHODS: CD14(+) cells were isolated from peripheral blood from 14 SSc patients and healthy controls by positive selection and incubated with different combinations of GM-CSF, IL-4 and ET-1 for 14 days. Type-1 collagen and α-SMA were detected by Western blot, qPCR and confocal microscopy. HLA-DR, CD11c and CD14 expression was analysed by flow cytometry. A collagen gel contraction assay was performed for functional myofibroblast assessment. RESULTS: GM-CSF both induced collagen and α-SMA expression after 14 days. ET-1 further increased GM-CSF-induced collagen expression in a dose dependent manner up to 30-fold. IL-4/GM-CSF combination leads to a more DC-like phenotype of monocytes associated with reduced collagen and α-SMA expression compared to GM-CSF alone. Collagen and α-SMA expression was higher in monocytes from SSc patients and monocytes were more prone to obtain a spindle form. In contrast to controls, ET-1 and IL-4 alone were sufficient to induce α-SMA expression in monocytes from SSc patients. Despite the induction of α-SMA expression, monocyte-derived myofibroblasts only had a moderate capability of contraction in functional analyses. CONCLUSION: SSc monocytes display increased maturation towards myofibroblasts demonstrated by their phenotype and α-SMA expression when compared to monocytes from healthy controls, however only with minor functional contraction properties