7,392 research outputs found
Hydroprocessing and Blending of a Biomass-Based DTG-Gasoline
The number of annually registered internal-combustion vehicles still exceeds electric-driven ones in most regions,
e.g., Germany. Ambitious goals are disclosed with the European Green Deal, which calls for new technical
approaches and greenhouse gas neutral transition technologies. Such bridging technologies are synthetic fuels for
the transportation sector, e.g., using the bioliq® process for a CO2-neutral gasoline supply. Fuels must meet the
applicable national standards to be used in existing engines. Petrochemical parameters can be variably adapted
to their requirements by hydroprocessing. In this work, we considered the upgrading of aromatic-rich DTG
gasoline from the bioliq® process. The heavy gasoline was therefore separated from the light one by rectification.
We investigated how to selectively modify the petrochemical parameters of the heavy gasoline, especially the
boiling characteristics, to make the product suitable as a high-quality blending component. Three commercially
available Pt/zeolite catalysts were tested over a wide range of temperature and space velocity. We achieved high
gasoline yields, while the content of light end compounds up to a boiling temperature of 150°C could be increased
significantly. In contrast to the high naphthenic content of the gasoline, the obtained octane numbers were
satisfactory. Especially the Motor Octane Number turned out unexpectedly high and showed a dependency on
the isomerization of the naphthenic rings. By blending the upgraded heavy gasoline with the previously separated
light gasoline, we could finally show that hydroprocessing is suitable for adjusting petrochemical parameters. The
aromatic concentration was 37.5% lower than that in the original raw gasoline, while the boiling characteristics
improved significantly. Additionally, the final boiling point was 82°C lower, which is beneficial for the emission
behavior
Phase-field-crystal model for liquid crystals
Based on static and dynamical density functional theory, a
phase-field-crystal model is derived which involves both the translational
density and the orientational degree of ordering as well as a local director
field. The model exhibits stable isotropic, nematic, smectic A, columnar,
plastic crystalline and orientationally ordered crystalline phases. As far as
the dynamics is concerned, the translational density is a conserved order
parameter while the orientational ordering is non-conserved. The derived
phase-field-crystal model can serve for efficient numerical investigations of
various nonequilibrium situations in liquid crystals
Socio-psychological airplane noise investigation in the districts of three Swiss airports: Zurich, Geneva and Basel
The results of noise measurements and calculations are available in the form of noise maps for each of the three areas. To measure the stress due to airplane noise the Noise and Number Index (NNI) was applied. In the vicinities of the airports, 400 households were randomly selected in each of the three noise zones (of 10 NNI intervals each). A total of 3939 questionnaires could be evaluated, one quarter of which came from areas without airplane noise. Concurrently, traffic noise was measured in areas of Basel and expressed in sum total levels L sub 50 and the reaction of 944 persons was elicited by interrogation
Role of serotonin in the hepato-gastroIntestinal tract: an old molecule for new perspectives
Abstract.: Beside its role as a neurotransmitter in the central nervous system, serotonin appears to be a central physiologic mediator of many gastrointestinal (GI) functions and a mediator of the brain-gut connection. By acting directly and via modulation of the enteric nervous system, serotonin has numerous effects on the GI tract. The main gut disturbances in which serotonin is involved are acute chemotherapy-induced nausea and vomiting, carcinoid syndrome and irritable bowel syndrome. Serotonin also has mitogenic properties. Platelet-derived serotonin is involved in liver regeneration after partial hepatectomy. In diseased liver, serotonin may play a crucial role in the progression of hepatic fibrosis and the pathogenesis of steatohepatitis. Better understanding of the role of the serotonin receptor subtypes and serotonin mechanisms of action in the liver and gut may open new therapeutic strategies in hepato-gastrointestinal disease
On the Geometry of Supersymmetric Quantum Mechanical Systems
We consider some simple examples of supersymmetric quantum mechanical systems
and explore their possible geometric interpretation with the help of geometric
aspects of real Clifford algebras. This leads to natural extensions of the
considered systems to higher dimensions and more complicated potentials.Comment: 18 page
Strong correlation effects and optical conductivity in electron doped cuprates
We demonstrate that most features ascribed to strong correlation effects in
various spectroscopies of the cuprates are captured by a calculation of the
self-energy incorporating effects of spin and charge fluctuations. The self
energy is calculated over the full doping range of electron-doped cuprates from
half filling to the overdoped system. The spectral function reveals four
subbands, two widely split incoherent bands representing the remnant of the
split Hubbard bands, and two additional coherent, spin- and charge-dressed
in-gap bands split by a spin-density wave, which collapses in the overdoped
regime. The incoherent features persist to high doping, producing a remnant
Mott gap in the optical spectra, while transitions between the in-gap states
lead to pseudogap features in the mid-infrared.Comment: 5 pages, 4 figure
Multiband effects on beta-FeSe single crystals
We present the upper critical fields Hc2(T) and Hall effect in beta-FeSe
single crystals. The Hc2(T) increases as the temperature is lowered for field
applied parallel and perpendicular to (101), the natural growth facet of the
crystal. The Hc2(T) for both field directions and the anisotropy at low
temperature increase under pressure. Hole carriers are dominant at high
magnetic fields. However, the contribution of electron-type carriers is
significant at low fields and low temperature. Our results show that multiband
effects dominate Hc2(T) and electronic transport in the normal state
Identification of the Orbital Pairing Symmetry in UPt_3
This paper summarizes the results of a comprehensive analysis of the
thermodynamic and transport data for the superconducting phases of UPt_3.
Calculations of the transverse sound attenuation as a function of temperature,
frequency, polarization, and disorder are presented for the leading models of
the superconducting order parameter. Measurements of the specific heat, thermal
conductivity, and transverse sound attenuation place strong constraints on the
orbital symmetry of the superconducting order parameter. We show that the
superconducting A and B phases are in excellent agreement with pairing states
belonging to the odd-parity E_{2u} orbital representation.Comment: 11 pages with 7 figure
Sulphur-bearing molecules in diffuse molecular clouds: new results from SOFIA/GREAT and the IRAM 30 m telescope
We have observed five sulphur-bearing molecules in foreground diffuse
molecular clouds lying along the sight-lines to five bright continuum sources.
We have used the GREAT instrument on SOFIA to observe the 1383 GHz transitions of SH towards the star-forming regions W31C,
G29.96-0.02, G34.3+0.1, W49N and W51, detecting foreground absorption towards
all five sources; and the EMIR receivers on the IRAM 30m telescope at Pico
Veleta to detect the HS 1(10)-1(01), CS J=2-1 and SO 3(2)-2(1) transitions.
In nine foreground absorption components detected towards these sources, the
inferred column densities of the four detected molecules showed relatively
constant ratios, with N(SH)/N(HS) in the range 1.1 - 3.0, N(CS)/N(HS)
in the range 0.32 - 0.61, and N(SO)/N(HS) in the range 0.08 - 0.30. The
observed SH/H ratios - in the range (0.5-2.6) - indicate
that SH (and other sulphur-bearing molecules) account for << 1% of the
gas-phase sulphur nuclei. The observed abundances of sulphur-bearing molecules,
however, greatly exceed those predicted by standard models of cold diffuse
molecular clouds, providing further evidence for the enhancement of endothermic
reaction rates by elevated temperatures or ion-neutral drift. We have
considered the observed abundance ratios in the context of shock and turbulent
dissipation region (TDR) models. Using the TDR model, we find that the
turbulent energy available at large scale in the diffuse ISM is sufficient to
explain the observed column densities of SH and CS. Standard shock and TDR
models, however, fail to reproduce the column densities of HS and SO by a
factor of about 10; more elaborate shock models - in which account is taken of
the velocity drift, relative to H, of SH molecules produced by the
dissociative recombination of HS - reduce this discrepancy to a factor
~ 3.Comment: 30 pages, accepted for publication in A&
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