9 research outputs found
Crystallographic insights into (CH3NH3)3(Bi2I9): A new lead-free hybrid organic-inorganic material as a potential absorber for photovoltaics
The crystal structure of a new bismuth-based light-absorbing material for the application in solar cells was determined by single crystal X-ray diffraction for the first time. (CH3NH3)3(Bi2I9) (MBI) is a promising alternative to recently rapidly progressing hybrid organic–inorganic perovskites due to the higher tolerance against water and low toxicity. Single crystal X-ray diffraction provides detailed structural information as an essential prerequisite to gain a fundamental understanding of structure property relationships, while powder diffraction studies demonstrate a high degree of crystallinity in thin films
On the role of history-dependent adsorbate distribution and metastable states in switchable mesoporous metal-organic frameworks
Abstract A unique feature of metal-organic frameworks (MOFs) in contrast to rigid nanoporous materials is their structural switchabilty offering a wide range of functionality for sustainable energy storage, separation and sensing applications. This has initiated a series of experimental and theoretical studies predominantly aiming at understanding the thermodynamic conditions to transform and release gas, but the nature of sorption-induced switching transitions remains poorly understood. Here we report experimental evidence for fluid metastability and history-dependent states during sorption triggering the structural change of the framework and leading to the counterintuitive phenomenon of negative gas adsorption (NGA) in flexible MOFs. Preparation of two isoreticular MOFs differing by structural flexibility and performing direct in situ diffusion studies aided by in situ X-ray diffraction, scanning electron microscopy and computational modelling, allowed assessment of n-butane molecular dynamics, phase state, and the framework response to obtain a microscopic picture for each step of the sorption process
Crystallographic Information File from The modulator driven polymorphism of Zr(IV) based metal-organic frameworks
Crystallographic data for DUT-12
Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
International audienceSwitchable metal-organic frameworks (MOFs) have been proposed for various energy-related storage and separation applications, but the mechanistic understanding of adsorption-induced switching transitions is still at an early stage. Here we report critical design criteria for negative gas adsorption (NGA), a counterintuitive feature of pressure amplifying materials, hitherto uniquely observed in a highly porous framework compound (DUT-49). These criteria are derived by analysing the physical effects of micromechanics, pore size, interpenetration, adsorption enthalpies, and the pore filling mechanism using advanced in situ X-ray and neutron diffraction, NMR spectroscopy, and calorimetric techniques parallelised to adsorption for a series of six isoreticular networks. Aided by computational modelling, we identify DUT-50 as a new pressure amplifying material featuring distinct NGA transitions upon methane and argon adsorption. In situ neutron diffraction analysis of the methane (CD4) adsorption sites at 111 K supported by grand canonical Monte Carlo simulations reveals a sudden population of the largest mesopore to be the critical filling step initiating structural contraction and NGA. In contrast, interpenetration leads to framework stiffening and specific pore volume reduction, both factors effectively suppressing NGA transitions
Towards General Network Architecture Design Criteria for Negative Gas Adsorption Transitions in Ultraporous Frameworks
Critical design criteria for negative gas
adsorption (NGA), a counterintuitive feature of pressure amplifying materials,
hitherto uniquely observed in a highly porous framework compound (DUT-49), are
derived by analysing the physical effects of micromechanics, pore size,
interpenetration, adsorption enthalpies, and the pore filling mechanism using
advanced in situ X-ray and neutron diffraction, NMR spectroscopy, and
calorimetric techniques parallelized to adsorption for a series of six
isoreticular networks. Aided by computational
modelling, we identify DUT-50 as a new pressure amplifying material featuring
distinct NGA transitions upon methane and argon adsorption. In situ neutron
diffraction analysis of the methane (CD4) adsorption sites at 111 K supported
by grand canonical Monte Carlo simulations reveals a sudden population of the
largest mesopore to be the critical filling step initiating structural contraction
and NGA. In contrast, interpenetration leads to framework stiffening and
specific pore volume reduction, both factors effectively suppressing NGA
transitions.</p