Reactive mercury in the troposphere: Model formation and results for Florida, the northeastern United States, and the Atlantic Ocean

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/95402/1/jgrd13669.pd

The dissolution of olivine added to soil: Implications for enhanced weathering

Chemical weathering of silicate minerals consumes atmospheric CO2 and is a fundamental component of geochemical cycles and of the climate system on long timescales. Artificial acceleration of such weathering (“enhanced weathering”) has recently been proposed as a method of mitigating anthropogenic climate change, by adding fine-grained silicate materials to continental surfaces. The efficacy of such intervention in the carbon cycle strongly depends on the mineral dissolution rates that occur, but these rates remain uncertain. Dissolution rates determined from catchment scale investigations are generally several orders of magnitude slower than those predicted from kinetic information derived from laboratory studies. Here we present results from laboratory flow-through dissolution experiments which seek to bridge this observational discrepancy by using columns of soil returned to the laboratory from a field site. We constrain the dissolution rate of olivine added to the top of one of these columns, while maintaining much of the complexity inherent in the soil environment. Continual addition of water to the top of the soil columns, and analysis of elemental composition of waters exiting at the base was conducted for a period of five months, and the solid and leachable composition of the soils was also assessed before and after the experiments. Chemical results indicate clear release of Mg2+ from the dissolution of olivine and, by comparison with a control case, allow the rate of olivine dissolution to be estimated between 10−16.4 and 10−15.5 moles(Mg) cm−2 s−1. Measurements also allow secondary mineral formation in the soil to be assessed, and suggest that no significant secondary uptake of Mg2+ has occurred. The olivine dissolution rates are intermediate between those of pure laboratory and field studies and provide a useful constraint on weathering processes in natural environments, such as during soil profile deepening or the addition of mineral dust or volcanic ash to soils surfaces. The dissolution rates also provide critical information for the assessment of enhanced weathering including the expected surface-area and energy requirements

[Etudes des relations contractuelles dans la filière vin hongroise]

International audienceLa communication présente et analyse les relations contractuelles et leur structure, dans la filière vitivinicole hongroise, en considérant ses progrès qualitatifs au sein d'une économie en transition. Les auteurs examinent les partenariats entre les viticulteurs et les entreprises de négoce qui élaborent le vin. Ils analysent la performance financière de ces entreprises en vue d'évaluer leur politique contractuelle en relation avec la création de valeur. L'étude souligne la diversité des situations, l'absence générale de mécanismes incitatifs de prix et d'indexation, la faible différenciation des prix au regard de la qualité, de même que la faiblesse de l'organisation des producteurs dans les négociations, l'absence de confiance, l'asymétrie d'information entraînant l'existence de comportements opportunistes. Toutefois cet avantage des entreprises de négoce ne se retrouve pas au niveau de leurs résultats financiers ce qui renvoie l'analyse du rapport de force au niveau suivant de la filière à savoir la grande distribution

Data-dependent margin-based generalization bounds for classification

We derive new margin-based inequalities for the probability of error of classifiers. The main feature of these bounds is that they can be calculated using the training data and therefore may be effectively used for model selection purposes. In particular, the bounds involve empirical complexities measured on the training data (such as the empirical fat-shattering dimension) as opposed to their worst-case counterparts traditionally used in such analyses. Also, our bounds appear to be sharper and more general than recent results involving empirical complexity measures. In addition, we develop an alternative data-based bound for the generalization error of classes of convex combinations of classifiers involving an empirical complexity measure that is easier to compute than the empirical covering number or fat-shattering dimension. We also show examples of efficient computation of the new bounds

Chelating NHC ruthenium(II) complexes as robust homogeneous hydrogenation catalysts

A series of ruthenium(II) complexes have been prepared by using bidentate chelating N-heterocyclic carbene (NHC) ligands that feature different donor groups E (E = olefin, thioether, carboxylate, and NHC). Rigid coordination of all donor sites was concluded from NMR spectroscopy, and the electronic impact of the donor group was evaluated by electrochemical analyses. The chelating donor group had a strong influence on the activity of the metal center in catalyzing direct hydrogenation of styrene. A thioether group or a second NHC donor site essentially deactivates the metal center. Complexes comprising a NHC tethered with an olefin or a carboxylate group showed appreciable activity, though only the carboxylate-functionalized system proved to be a precursor for homogeneous hydrogenation. According to in situ high-pressure NMR analyses, complexes featuring a carboxylate chelating group are remarkably resistant toward reductive elimination even under strongly reducing conditions and may, therefore, be used repeatedly