Solid flux in travelling fluidized bed operating in square-nosed slugging regime

The performance of gas-fluidized bed reactors depends significantly on their hydrodynamics. Among the important properties that dictate the characteristics of a gas-fluidized bed, local solid flux plays a significant role, influencing vital parameters such as bed-to-surface heat exchange and solid circulation rate. Developing techniques that can provide accurate measurements of solid flux is extremely important for: 1) assessing the accuracy of other measurement techniques applicable to industrial units, and 2) validation of CFD models. Comparison of different measurement techniques that provide similar hydrodynamic information is helpful in assessing the errors associated with each methodology. Most measurement techniques for obtaining solid flux in gas-fluidized beds are based on intrusive probes that can simultaneously measure solid velocity and voidage. Previously (1), the novel travelling fluidized bed (TFB) was operated to determine particle velocity from radioactive particle tracking (RPT), positron emission particle tracking (PEPT) and borescopy with silica sand particles of mean diameter 292 μm at superficial gas velocities from 0.4 to 0.6 m/s. In this study, the TFB, operated under identical conditions, was deployed to compare RPT and PEPT for the investigation of solid flux in square-nosed slugging. Both techniques provided solid flux data of the same order, but there were significant quantitative differences. Differing physical properties of tracer particles and the bed material, and differences in the tracer localization techniques are among the factors that contributed to the observed discrepancies. The results provide useful insights on the merits and challenges associated with advanced techniques for measuring solids flux in gas-fluidized beds. REFERENCES S. Tebianian, K. Dubrawski, N. Ellis, R. A. Cocco, R. Hays, S.B.R. Karri, T. W. Leadbeater, D.J. Parker, J. Chaouki, R. Jafari, P. Garcia-Trinanes, J.P.K. Seville, J.R. Grace. Comparison of Particle Velocity Measurement Techniques in a Fluidized Bed Operating in the Square-Nosed Slugging Flow Regime. Powder Technol., 2015. doi:http://dx.doi.org/10.1016/j.powtec.2015.08.040

New chemical engineering provision: Quality in diversity

Recent growth in chemical engineering student numbers has driven an increase in the number of UK universities offering the subject. The implications of this growth are described, along with the different challenges facing new providers in the UK compared with established departments. The approaches taken by the various new entrants are reviewed, with reference to recruitment strategies, infrastructure, the use of external facilities, and the particular flavours of chemical engineering being offered by the new providers. Information about the differentiating features of the large number of chemical engineering degree courses now available is somewhat indistinct: this should be rectified in the interests both of prospective students and of employers. Dilemmas facing new providers include the need to address the fundamentals of the subject as well as moving into more novel research-led areas; enabling students to develop the competencies to sustain them for a whole career as well as meeting immediate employer needs; and providing sufficient industry understanding when academics may lack substantial industrial experience. The central importance of practical provision and of the design project, and the approaches taken by new providers to deliver these components, are reviewed, together with the role of software tools in chemical engineering education, and measures to facilitate industry input into courses. As long as it is not used prescriptively or to inhibit innovation, the accreditation process provides constructive guidance and leverage for universities developing new chemical engineering programmes

Particle progress

Particle technology principles are ubiquitous in the world of material processing, yet there are still many common problems associated with issues such as hopper flow, filtration, segregation, agglomeration, slurry processing, and grinding. While many companies do apply particle technology in manufacturing their products, in my experience few actually realize the impact that it can have, mostly due to a lack of knowledge in the field. As a result of this lack of knowledge there is often a detrimental effect on process development and design, startup and shutdown time, or performance often associated with materials handling and chemistry-related difficulties

Dense gas-particle suspension upward flow used as heat transfer fluid in solar receiver: PEPT experiments and 3D numerical simulations

A dense particle suspension, also called an upflow bubbling fluidized bed, is an innovative alternative to the heat transfer fluids commonly used in concentrated solar power plants. An additional advantage of this technology is that it allows for direct thermal storage due to the large heat capacity and maximum temperature of the particle suspension. The key to the proposed process is the effective heat transfer from the solar heated surfaces to the heat transfer fluid, i.e. the circulating solid suspension. In order to better understand the process and to optimise the design of the solar receiver, it is of paramount importance to know how particles behave inside the bundle of small tubes. To access to the particle motion in the solar receiver, two different techniques are carried out: experimental using positron emission particle tracking (PEPT) and 3D numerical simulation via an Eulerian n-fluid approach with NEPTUNE_CFD code. Both numerical predictions and PEPT measurements describe an upward flow at the centre of the transport tube with a back-mixing flow near the wall which influences the heat transfer mechanism. Comparisons between experiment and computation were carried out for the radial profiles of the solid volume fraction, and vertical and radial time-averaged and variance velocities of solid, and demonstrating the capability of NEPTUNE_CFD code to simulate this peculiar upflow bubbling fluidized bed

Enhancing the activation of silicon carbide tracer particles for PEPT applications using gas-phase deposition of alumina at room temperature and atmospheric pressure

We have enhanced the radio-activation efficiency of SiC (silicon carbide) particles, which by nature have a poor affinity towards 18F ions, to be employed as tracers in studies using PEPT (Positron Emission Particle Tracking). The resulting SiC-Al2O3 core-shell structure shows a good labelling efficiency, comparable to γ-Al2O3 tracer particles, which are commonly used in PEPT. The coating of the SiC particles was carried at 27 ± 3 °C and 1 bar in a fluidized bed reactor, using trimethyl aluminium and water as precursors, by a gas phase technique similar to atomic layer deposition. The thickness of the alumina films, which ranged from 5 to 500 nm, was measured by elemental analysis and confirmed with FIB-TEM (focus ion beam – transmission electron microscope), obtaining consistent results from both techniques. By depositing such a thin film of alumina, properties that influence the hydrodynamic behaviour of the SiC particles, such as size, shape and density, are hardly altered, ensuring that the tracer particle shows the same flow behaviour as the other particles. The paper describes a general method to improve the activation efficiency of materials, which can be applied for the production of tracer particles for many other applications too

Enhancing the activation of silicon carbide tracer particles for PEPT applications using gas-phase deposition of alumina at room temperature and atmospheric pressure

We have enhanced the radio-activation efficiency of SiC (silicon carbide) particles, which by nature have a poor affinity towards 18F ions, to be employed as tracers in studies using PEPT (Positron Emission Particle Tracking). The resulting SiC-Al2O3 core-shell structure shows a good labelling efficiency, comparable to γ-Al2O3 tracer particles, which are commonly used in PEPT. The coating of the SiC particles was carried at 27 ± 3 °C and 1 bar in a fluidized bed reactor, using trimethyl aluminium and water as precursors, by a gas phase technique similar to atomic layer deposition. The thickness of the alumina films, which ranged from 5 to 500 nm, was measured by elemental analysis and confirmed with FIB-TEM (focus ion beam – transmission electron microscope), obtaining consistent results from both techniques. By depositing such a thin film of alumina, properties that influence the hydrodynamic behaviour of the SiC particles, such as size, shape and density, are hardly altered, ensuring that the tracer particle shows the same flow behaviour as the other particles. The paper describes a general method to improve the activation efficiency of materials, which can be applied for the production of tracer particles for many other applications too